15-06-2025

1902CJA101001250008 JA

PART-1 : PHYSICS

SECTION-I (i)

1) In the figure, the man is moving on the track and rain appeared to him as shown by arrows.
Find the actual speed of the rain in meter per second.

(A)

(B)

(C)

(D)

2) There are two particles P and Q separated by distance 10 km and moving with velocities 10
kmph as shown on a smooth horizontal surface. The time elapsed before they come at minimum

separation is :

(A) 1 hr

(B)

(C)

(D) 2 hr
3) A swimmer crosses a river with minimum possible time 10 second. And when he reaches the
other end starts swimming in the direction towards the point from where he started swimming.
Keeping the direction fixed the swimmer crosses the river in 15 sec. The ratio of speed of swimmer
with respect to water and the speed of river flow is (Assume constant speed of river & swimmer):-

(A)

(B)

(C)

(D)

4) A particle is projected from point A at an angle of 53° with horizontal. At the same time
wedge starts from rest and moves with constant acceleration a as shown. The value of a for which
the particle strikes the plane perpendicular to it at P, is

(tan53° = 4/3, g = 10 m/s2)

(A) 10 m/s2
(B) 100 m/s2

(C)

(D)

SECTION-I (ii)

1) A projectile is thrown from the ground at a speed of 40 m.s–1 at angle of elevation 60° above the
horizontal. Select the correct option(s). [ g = 10 m.s–2 ]

(A) Rate of change of speed of the projectile just after projection is +5 m. s–2.
(B) The projectile is moving away from point of projection at all instants till hitting the ground.
(C) Velocity vector of the projectile is rotating at a rate of 0.5 rad . s–1 at top most point.
(D) Maximum height reached by the projectile is 60m.

2)

A particle is projected from origin with speed u=50 m/s at an angle 30° with X-axis. Due to
wind particle acquires an extra acceleration a = 6 m/s2 in –ve x-direction. Path of particle is shown
in figure.
 x - Coordinates of point A and B are same
y- Coordinates of P and Q are same.
Point N on the X-axis, point M on the Y-axis.
Time taken by particle from O to P, O to Q, O to A and O to B are t1, t2 , t3 and t4 respectively.
(Assuming Y along vertical and their is no surface in the space) (g = 10 m/s2 and constant).
(A) The value of t1 + t2 is 5 sec.
(B) The value of t3 + t4 is 25 sec.

(C)
The length of ON is
The length of OM is
(D)

3)

Two particles, one with constant velocity 50 m/s and the other with zero initial velocity and
uniform acceleration 10 m/s2, start moving simultaneously from the same place in the same
direction. They will be at a distance of 125 m from each other after :

(A) 5 sec.

(B)

(C) 10 sec.

(D)

4)

A 600 m wide river flows towards South at 4 m/s. A small motor boat travels at 5 m/s in still water &
points in such a direction so that it will travel towards East relative to land.
(A) The speed of boat relative to land is 3 m/s.
(B) The speed of boat relative to land is .
(C) The time taken by boat to cross the river is nearly 200 second.
(D) The time taken by boat to cross the river is nearly 100 second.

SECTION-II

1)

A particle moving with constant speed turns left by an angle of 74° after traveling every 1 m
distance. If it returns back to its starting point after 18 sec, then the magnitude of average
acceleration of the particle from it’s initial position to just before it takes it’s second turn is 50 k
m/s2. Find the value of K.

2) A car starts from rest from origin an straight line with an acceleration (a) given by the relation

, where a is in m/s2 and x is in metre. The maximum velocity (in m/s) of the car will be (x
is the position of the car)

3) A board is being moved with a constant velocity v0 on a smooth horizontal plane. A small block is
projected on the rough boards. Coefficient of friction between board and block is μ = 0.3. Block is
projected with velocity v1 = 25 m/s at an angle of θ = 37° relative to ground. What is the velocity of

block (in m/s) relative to ground after time t = 10 sec.

4)

The point from where a ball is projected in x-y plane is taken as origin of the co-ordinate axis. The x
and y components (in meter) of its displacement are given by x = 6t and y = 8t – 5t2 where t is time
(in seconds). What is speed of projection (in m/s) ?

5)
Brakes are being applied in a car moving with speed 20 m/s which produces a retardation of 5 m/s2.
The distance travelled by car (in m) till it stops.

6) The angle of inclination of inclined plane is 30° horizontal velocity v0 so that particles hit the

incline plane perpendicularly, . Find a + b

7) Ram has been caught red handed doing notorious activities and is punished to run back and forth
in a 20 m long corridor from room number 109 to the other end. Ram starts running from room
number 109, touches the other end, returns & touches the door of room number 109 & so on for 65
minutes continuously after which he drops down exhausted. His speed is seen to be
m/s where x is the distance (in m) from the centre of the corridor. How many times did he touch the
other end during this time interval. (Take : π = 3.14)

8)

A cyclists uniformly accelerates along a straight path and covers a distance 50 m with an average
speed of 7 m/s. During the motion his speed changes by 6 m/s. Then instantaneous speed of cyclists
in the middle of the path during motion is (in m/s)

PART-2 : CHEMISTRY

SECTION-I (i)

1) 5 moles of hydrogen gas, 3 moles of white phosphorus P4(s) and 12 moles of Oxygen gas are taken
in a sealed flask and allowed to react as follows.
H2(g) + P4(s) + O2(g) → H3PO4.
Determine the moles of H3PO4 that can be produced considering 90% yield of reaction.

(A) 3 moles
(B) 4 moles
(C) 3.33 moles
(D) 5 moles

2) EMR of wavelength λ = 31 nm are subjected to a metal sheet having work function W = 25 eV.
Calculate minimum de–Broglie wavelength of the photo–electron emitted.

(A) 3 Å
(B) 10 Å
(C) 124 nm
(D) 3.16 Å

3) Which of the following configuration has least energy

(A)

(B)

(C)

(D)

4) Among the following elements, which has the highest ionization energy ?

(A) Nitrogen
(B) Chromium
(C) Neon
(D) Manganese

SECTION-I (ii)

1) The number of d- electrons in Mn2+ is equal to that of

(A) p-electrons in N
(B) s-electron in Na
(C) d-electrons in Fe+3
(D) p-electrons in O–2

2) One mole of H2SO4 will exactly neutralize

(A) 2 moles of an ammonia solution

(B) 1 mole of Ba(OH)2
(C) 2 moles of NaOH
(D) 0.5 mole of Ba(OH)2

3) Which of the following is / are correct statements :

 The ratio of λ of mth & nth lines in Lyman series of a H-like species is
(A)

Kinetic energies of emitted electrons during photoelectric effect is lower than the energy
(B)
incident.
(C) All Balmer lines are observed in visible region of electromagnetic spectrum for H-like species.
(D) H-spectrum is discrete spectrum

4) The wave function for 2s orbital is given as

Where ao = First Bohr's radius in H atom = 0.529 A°.

Read the given statement and pick out the correct statement(s).

(A) The number of radial nodes is equal to three

(B) The probability density is independent of direction
(C) The probability density of finding electron at nucleus is non-zero.
(D) The radial node occur at a distance 2a0 from nucleus

SECTION-II

1) The ionisation potential of a hydrogen like species is 36 volt. What is the value of excitation
energy from ground state to 1st excited state. (in eV)

2) A certain metal when illuminated alternatively by light of λ1 = 155 nm and λ2 = 310 nm emit
photoelectrons of maximum kinetic energies in the ratio 5 : 1. The work function of the metal in eV is
[Take hc = 1240 eV nm]

3) An orbital having double dumpbell shape of an unielectronic specie is represented as

0
where and a represents Bohr’s radius. Calculate sum of angular & spherical nodes.

4) The radius of the orbit in hydrogen atom is 0.8464 nm. The velocity of electron in this orbit is 547
× 10x m/sec. The value of ‘x’ will be

5) The mass of H2O produced by combining 4gm of H2 with 32g of O2 is 10.8 gm. If the percentage

yield of reaction is x %, then value of is.

6) SO2Cl2 reacts with water to give a mixture of H2SO4 and HCl. How many moles of NaOH would be
needed to neutralize the solution formed by adding 1 mole of SO2Cl2 to excess water –
7) The shape of a virus is clyindrical having length 3000 Å and radius 85 Å respectively. If specific
volume of virus is 12.5 ml/gm then what will be the molecular weight of virus.
[Express your answer in terms of 3.28 × 10x & calculate x.]

8) The successive ionization energies for an unknown element are :

IE1 = 889 KJ/mol ; IE2 = 1757 KJ/mol.
IE3 = 14,847 KJ/mol. ; IE4 = 17,948 KJ/mol.
To which group in the periodic table does the unknown element most likely belong?

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let λ = , then value of λ is equal to

(A) 1
(B) 2
(C) 3
(D) None of these

2) Let 12 + 22 + 32 + ... + 20032 = (2003)(4007)(334) and (1)(2003) + (2)(2002) + (3)(2001) + ... +

(2003)(1) = (2003)(334 )(x), then the value of x is

(A) 2005
(B) 2004
(C) 2003
(D) 2001

3) Let a, b, c are distinct positive numbers such that b + c – a, c + a – b and a + b – c are positive,
then the expression (b + c – a)(c + a – b)(a + b – c) – abc is

(A) positive
(B) negative
(C) non-positive
(D) non-negative

4) Let a1, a2, a3, .....an are first 'n' terms of an increasing A.P. with common difference equal to a2,

then equal to -

(A) 4
(B) 2
(C)

(D)

SECTION-I (ii)

1) Consider an equation 8x4 – 16x3 + 16x2 – 8x + a = 0 then the sum of all the non-real roots of
the equation can be [a ∈ R]

(A) 1
(B) 2

(C)

(D)

2) Which of the following is/are true ?

(A) 2x + x–x ≥, x ∈ R

(B)

(C)

(D) If p, q, r are in H.P. roots of px2 + qx + r = 0 are imaginary (p, q, r ∈ R+)

3) Let x1, x2, x3, x4 are four positive real numbers such that

and , then

(A) x1 = x3
(B) x2 = x4
(C) x1x2 = 1
(D) x3x4 = 1

4) a1, a2, a3 ......are distinct terms of an A.P. We call (p, q, r) an increasing triad if ap, aq, ar are in G.P.
where p, q, r ∈ N such that p < q < r. Let (5, 9, 16) be an increasing triad, then which of the
following option is/are correct

(A) let a1 is a non-zero multiple of 4 then every term of the A.P. is an integer
(B) (85, 149, 261) is an increasing triad

(C) let the common difference of the A.P. is , then its first term is

(D) ratio of the (4k + 1)th term and 4kth term can be 4
 SECTION-II

1) If x, y, z are positive then the minimum value of xlog y – log z + ylog z – log x + zlog x – log y is

2) Given sequence of numbers x1, x2, x3, ... x1005 which satisfy,

... = where x1 + x2 + ... x1005 = 2010 then is

3) Let positive numbers x, y, z are in A.P., then the minimum value of is equal to

4) Let a, b, c, > 0 and then the minimum value of

a2 b2 c2 (Consider = 1.41 and = 1.73)

5) is

6)

Let then no. of integers x satisfying the inequality is :

7) The number of integer values of k in the closed interval [–500, 500] for which the equation log
(kx) = 2log (x + 2) has exactly one real solution.

8) Let a, b, c ∈ R and a2 + b2 + c2 = 1, then the maximum value of |a–b| + |b–c| + |c–a| is ?

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B C C

SECTION-I (ii)

Q. 5 6 7 8
A. B,D A,D A,B A,C

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 1.20 2.50 8.00 10.00 40.00 7.00 621.00 7.6

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. A D A C

SECTION-I (ii)

Q. 21 22 23 24
A. B,C A,B,C A,B,D B,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 27.00 3.00 5.00 3.00 3.00 4.00 6.00 2.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. C A B D

SECTION-I (ii)

Q. 37 38 39 40
A. A,B A,C,D A,B,C,D A,B,C
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 3.00 0.50 4.00 2.82 7.00 31.00 501.00 2.83
 SOLUTIONS

PART-1 : PHYSICS

1)

2) Diagram shows relative path of Q w.r.t. P

3)
V = velocity of man w.r.t . river
u = velocity of river
4) Let height of point p above the ground be h.
ucos53°t + h = 1/2 at2 ...(1)

On solving above equations we get a = 130m/s2

5)

correct option is BD
2, 4
11111111111
222222222222
33333333333
44444444444444
6)

7)

V1 = 50
V2 = 10t
Initially 1 will be ahead & finally two will overtake 1
8)

vb = 3m/s

9)

Nθ = 2np
Where N is the side of a regular polygon and n is the number of rotations before it comes to its
inital position.\
N(74) =n(360)

10)

correct option is 2.50

11111111111111
22222222222
3333333333
444444444444

11)

a = –3
at t = so it will stop relative motion before 10 sec. So it will have same velocity as
plank.

12)

correct option is 10.00

13)

Stopping distance =

14)
In a direction along the inclined plane,
0 = V0 cos 30° – g sin 30°
In a direction perpendicular to incline,

–H cos 30° = – V sin 30° t – g cos 30° t2

Putting the value of t and solving, we get

15) v2 = 100 – x2
differentiating w.r.t. 'x', we get

a = – x | equation of S.H.M. a = – ω2x

ω = 1 rad/s

Time period,
v2 = 100 – x2 ... (1)
speed at position 'x'
v2 = ω2(A2 – x2) ... (2)
 comparing equation (1) & equation (2),
A = 10 m
He will touch 'x' no. of times

x = 621

16)

correct option is 7.6

PART-2 : CHEMISTRY

17) Correct option is A

3 moles

18)

19) Correct option is A

20) Correct option is C

21) Same number of electrons.

22) eAcid = eBase.

23) Correct option is A, B , D

24) * no of radial node = n – ℓ – 1 = 2 – 0 –1 = 1

* Probability density
* Since contain no θ or ϕ terms – probability of finding electron do not depend upon
direction

* Also since at r = 0, ;
is non zero at r = 0

* when the term vanishes putting =0

r = 2a0
 at r = 2a0 , : Corresponds to radial node.

25)

ΔE = I.P. = I.P. × = 32 eV

26)

We know

ϕ = 3 eV.

27) From Ψ(r) 3 radial nodes 7 also the orbital is d (∴ σ2)

∴ Total nodes = n – ℓ – 1 + ℓ = n – 1 = 5
ℓ = 2 & n – ℓ – 1 ∴ n = 6.

28) Radius of orbit rn = 0.529 × n2 = 0.8464 × 10

⇒n=4

Velocity of e– =
= 547×103 m/sec ⇒ x = 3

29) Theoretical yield = 36

percentage yield (x) =

So,

30) correct option is 4.00

31) Vvirus = π × 3000 × 85 × 10–24 cm3

∴ Mass of virus =

∴ Molar mass =

32) There is jump in ionization energy from second to third one. Alkaline earth metals have the
electron configuration [noble gas]ns2; third electron is to be removed from the electron
configuration [noble gas] which will require very high energy. These data are of beryllium.
PART-3 : MATHEMATICS

33) λ = =

= = =

= + +..........+

= = 4 - 1 = 3, λ = 3

34) If 12 + 22 + 32 + ... + 20032 = (2003)(4007)(334)

(1)(2003) + (2)(2002) + 3(2001) + ... + (2003)(1) = (2003)(334)(x)

= (2003)(334)(x)
2
⇒ 2004(Σr) – (Σr ) = (2003)(334)(x)

⇒ 2004
⇒ (2003)(334) ⇒ x = 2005

35) Here,

and
Multiplying, abc > (a + b – c)(b + c – a)(c + a – b)

36)

Correct answer is (D)

37) 8x (x – 1) (x2 – x + 1) + a = 0
a = 8x(1–x) (x2– x + 1)
f(x) = 8x(1–x) (x2– x + 1)
f(x) has only 2 real roots x = 0, 1 and is concave downwards
and its maximum value is at

Maximum value of f(x) =

If
All roots will be imaginary of sum = 2

If
Only two roots will be imaginary of sum = 1

38) Correct answer is (A), (C), (D)

39)

∴ to hold all the inequalities x1 = = 2,

∴ x1 = x3 = 2 & x2 = x4 =

40) Let R be the common ratio of the G.P. and D be the common difference of A.P.
a5 = a5,a9 = Ra5, a16 = a5R2
a9 – a5 = 4D ⇒ (R –1) a5 = 4D.............(1)
a16 – a9 = 7D ⇒ R(R –1) a5 = 7D.............(2)

From equation (1)/(2), we get

From equation (2) – (1), we get (R – 1)2 a5 = 3D ⇒

41)
because log{ xlog y – log z .ylog z – log x . zlog x – log y} = 0 (on simplification).

42) Above sequence is in A.P.

= ................ =k

∴k=

k=1+ =

⇒ x21 =

43) Since x, y, z are in A.P., x + z = 2y and hence

≥ 1 + 3 [A.M. ≥ G.M.]
⇒ minimum value of the given expression is 4

44) Let a2 = tan α, b2 = tan β and c2 = tan γ

Then, cos2 α + cos2 β + cos2 γ = 1 ⇒ sin2 α = cos2 β + cos2 γ
Use AM ≥ GM
sin2 α = cos2 β + cos2 γ = 2(cos2 β cos2 γ)1/2
⇒ sin2 α ≥ 2 cos β cos γ ….. (1)
Similarly, sin2 β ≥ 2 cos α cos γ ….. (2)
and sin2 γ ≥ 2 cos α cos β ….. (3)
Multiplying 1, 2, 3
sin2 α sin2 β sin2 γ ≥ 8 cos2 α cos2 β cos2 γ
⇒ tan2 α tan2 β tan2 γ ≥ 8 ⇒ tan α tan γ tan γ ≥ 2
⇒ a2 b2 c2 ≥ 2 minimum value 2 = 2.82

45) tr =

=
⇒ t1 + t29 = 2
But t15 = 1 & t30 = 1
⇒ Final sum = 31
So required answer is 7

46)
For to be defined x < 0

Since are positive & –x2 + x – 1 is always negative

x<0

⇒
⇒ No. of integers = 31

47) The equation log (kx) = 2log (x + 2) is valid for kx > 0 and x > – 2.
It is easy to seen that the all negative values of k make the equation log (kx) = 2 log (x + 2)
have 500 integer values and for positive reason of x, k has only one value.

48)

Let assume a ≥ b ≥ c; (|a–b| + |b–c| + |c–a|)2 ≤4(a–c)2 ≤ 8 ⇒ |a–b| + |b–c| + |c–a| ≤ 2