Conduction & Breakdown in Gases
Conduction & Breakdown in Gases
Conduction & Breakdown in Gases
Gases as insulating medium Simplest & most commonly found dielectrics gases Most apparatus use air but some of them use SF6 When the applied voltage is low , small currents flow between the electrodes and insulation retains its electrical properties (i.e. works as insulators) If the applied voltages are large, the current flowing through the insulation increases very sharply and electrical breakdown occurs. A strongly conducting spark formed during breakdown produces a short circuit between the electrodes. The maximum voltage applied to the insulation at the moment of breakdown is called breakdown voltage.
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Collision Process
Types of Collision An electrical discharge is normally created from unionized gas by collision process. Two types of Collisions (I) Elastic Collisions (II) Inelastic Collisions Elastic Collisions - Collisions which when occur , no change takes in
the internal energy of the particle but only their kinetic energy gets redistributed. Does not takes place in practice. When electrons collide with gas molecules, a single electron traces a zigzag path during its travel. In between the collisions , its is accelerated by electric field. Since electrons are very light in weight, they transfer only a part of their kinetic energy to the much heavier ions or gas molecules with which they collide. This results in very little loss of energy by the electrons and electrons gain very high energies and travel at a much higher speed than the ions. 4
Collision Process
Inelastic Collisions Inelastic collisions are those in which internal changes in energy take place within an atom or a molecule at the expense of the total kinetic energy of the colliding particle. The collisions often results in a change in the structure of the atom. All collisions that occur in practice are inelastic collisions. Example-ionization, attachment , excitation, recombination are in elastic collisions.
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Ionization Process
Ionization Process
Ionization by collision
Photo ionization
Ionization Process
Ionization by collision The process of liberating an electron from a gas molecule with the simultaneous production of a positive ion is called ionization. A free electron collides with a neutral gas molecules and gives to a new electron and positive ion.
Cathode UV Light Anode
Current Limiting Resistor
Considering Electric field E applied across two parallel electrodes as shown in figure, then any electron starting at the cathode will be accelerated more and more 7 between collisions with other gas molecules during its travel towards the anode.
Ionization Process
Ionization by collision (contd) If the energy ()gained during this travel between collisions exceeds the ionization potential ,Vi which is the energy required to dislodge an electron from its atomic shell , then ionization takes place. - +A >Vi e- + A+ +eA is the atom, A+ is the positive ion, e- is the electron
A few electrons are generated at the cathode by some external means (UV light), ionize neutral gas particle producing positive ions and additional electrons.
The additional electrons , then themselves make ionizing collisions and thus the process repeats itself. The positive ions also reach the cathode and on bombardment on the cathode gives rise to secondary electrons.
Ionization Process
Photo ionization Photo-ionization occurs when the amount of radiation energy absorbed by an atom or molecule exceeds the ionization potential. Process by which radiation can be absorbed by atom or molecule are a) excitation of the atom to a higher energy sate. b) continuous absorption by direct excitation of the atom or dissociation of diatomic molecule or direct ionization etc. An excited atom emits radiation when the electron returns to the lower state or to the ground state .
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Ionization Process
Photo ionization (contd) hf+A A* Ionization occurs when c.h/vi
h is the planks constant c.is the velocity of light is the wavelength of incident radiation Vi is the ionization energy of the atom Higher the ionization energy, the shorter will be the wave length of radiation capable of causing ionization It was observed experimentally that a radiation having wavelength of 1250A0 is capable of causing photo-ionization of almost all gases.
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h.c/ vi,
h. c/vi
Ionization Process
Secondary Ionization Process Secondary Ionization is process by which secondary electrons are produced which sustain a discharge after it is established due to ionization by collision and photo ionization A) Electrons emission due to positive impact B) Electron emission due to Photons C) electrons emission due to Metastable and Neutral Atoms Electrons Emission due to Positive Impact Positive ions are formed due to ionization by collision or by photoionization and being positively charged , they travel towards the cathode A positive ions approaching a metallic cathode can cause emission of electrons from the cathode by giving up its kinetic energy on impact. If the total energy of the positive ion is greater than twice the work function of the metal, then one electron will be ejected and a second electron will neutralize the ion.
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Ionization Process
Secondary Ionization Process (contd) Electron emission due to Photons To cause an electron to escape from a metal, it should be given energy to overcome the surface barrier. The energy can be supplied in the form of photon of ultraviolet light of suitable frequency Electron emission from a metal surface occurs at the critical condition hv where is the work function of the metal electrode If the incident radiation has a greater frequency than the threshold frequency, then excess energy goes partly as the kinetic energy of the emitted electron and partly to heat the surface of the electrode
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Ionization Process
Secondary Ionization Process (contd) Electron Emission due to Metastable and Neutral atoms A meta-stable atom or molecule is a particle whose lifetime is very large(10-3) compared to the lifetime of an ordinary particle. Electrons can be ejected from the metal surface by the impact of excited (meta-stable) atoms provided that their total energy is sufficient to overcome the function This process is most easily observed with meta-stable atoms , because the life time of other excited states is too short for them to reach the cathode and cause electron emission, unless they originate very near to cathode surface. Neutral atoms in the ground state also give rise to secondary electron emission if their kinetic energy is high.
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When an electron collides with a neutral particle, positive ion and an electron are formed. This is called an ionizing collision. Let = Average number of Collision made by an electron per centimeter travel in the direction of field = Collision /electron/length This depends on gas pressure p and is te function of electric field and pressure. It is written as /p= f(E/p)
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I=Ioed
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n= n0 ed / 1-(ed -1)
I= I0 ed / 1-(ed -1)
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