Fire Fight Part 2

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FIRE BEHAVIOR

AND
CHEMISTRY

Effective fire control


and extinguishment

requires a basic
understanding of
the
chemical
and
physical nature
of fire.

This includes
information
describing sources
of
heat energy,

environmental
conditions
necessary to
sustain the
combustion
process.

When paper burns in a fire,


the reactants are mostly

carbon(the main substance


in the paper)
andoxygen(from the air).

Fireis the
rapidoxidationof a
material in the
exothermic
chemical process
of combustion,

releasing
heat,

light,

and various
reaction
products.

A temperature @
which a material
oxide quickly &
starts to
burn
is
called
combustion

Slower
oxidative
processes
like
rusting

ordigestion
are not included
by this definition.

Theflame is the
visible portion of
the fire.
If hot

enough,

the gases may become


ionized to
produceplasma.

(a highly ionized
gas contain
approximately
equal number of
positive ions and
electrons)

Oxidation is a
process that
occurs when an
object is exposed
to oxygen for a

Burning something
is a rapid oxidation

rusting is the perfect


example of slow
oxidation

This will cause the


substances in the
object to
start
breaking
down.

Oxygen has to be
present for oxidation to
take place.

The addition of
oxygen to any
element is what
caused oxidation.
Slow oxidation of wood,

as in rotten of
wood

Foxingis a term
describing the agerelated spots and
browning seen on vintage
paperdocumentssuch
asbooks,postage
stamps,certificates, and
so forth.

theory is that
foxing is caused
by the effect on
certainpapersof
theoxidation

fast oxidation,
such as
detonations

and explosions.

16% fire point

14% flash point


12% no fire

For many years,


the fire triangle
(oxygen, fuel, and
heat) was used
to teach the
components of
fire.

While this
simple example
is useful,
it is not
technically
correct.

The fire
tetrahedron
represents the

addition

of a

the chemical chain


reaction,
to the three already
present in the fire
triangle.

Remove any one of


the four components
and combustion will
not occur.

If ignition has already


occurred,
the fire is
extinguished
when one of the
components is
removed from
the reaction.

Extinguishment Considering
the Fire Tetrahedron

A fire can be
extinguished
by
removing
its oxygen.

Starvation is
achieved by
removal of the
fuel burning in
the
fire.

Sometimes
combustible
material can
be
removed by
shutting off
gas
valves or
fuel flows.

The removal of heat


or the cooling
of a fire is the
most common
form of
suppression.

In most cases water


is used to
essentially
soak up
the heat
generated by the

This heat turns the


water in to steam,
thereby robbing the
fire of the heat
used.

Fat
If we Quality
look

atSmoke
fuel Point
types
and
vapor
Extra
Coconut
Virgin
350F 177C
production,
we
find
oil
(Unrefined)
that solid fuels and
Coconut
Refined
450F high
232C
liquid
fuels
with
oil
flash
Corn
oil points
Unrefined can
352F be
178C
Corn
oil Refined
450F
extinguished
by 232C
cooling

Low

flashpoint liquids
and flammable gases
cannot be
extinguished by
cooling with water as
vapor production
cannot be sufficiently
reduced.

Interference is the
process of
applying
extinguishing agents
to the fire
that inhibit
chemical
chain
reaction
at the
molecular level

STOP CHAIN REACTION


Stopping or interrupting the
chain reaction between the
fuel, heat, and oxygen will
extinguish the fire. Specific
methods of extinguishing fires
often involve a combination of
more than one of the four
principles.

Most fires involve a fuel


that is chemically
combined with the oxygen
normally found in
atmospheric air.
Atmospheric air contains
21 percent oxygen, 78
percent nitrogen and 1
percent of other gases.

A rapid oxidation
where burning
substances combines
with Oxygen then
energy is given off in
the form of heat and
light. fire

Most common
fuels contain
carbon along
with
combinations of
hydrogen and
oxygen.

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