Chemistry:

The Study of Change

Chapter 1
Chemistry is the study of matter and the changes it undergoes

1. Matter is anything that occupies space and has mass.

2. Matter is broadly classified into Substance and Mixture

3. A substance is a form of matter that has a definite

composition and distinct properties ; element and compound
water, ammonia, sucrose, gold, oxygen.
A mixture is a combination of two or more substances in which
the substances retain their distinct identities.

1. Homogenous mixture – composition of the mixture is the

same throughout.
soft drink, milk, solder

2. Heterogeneous mixture – composition is not uniform

throughout.
cement, iron filings in sand

Physical means can be used to separate a mixture into its

pure components.
An element is a substance that cannot be separated into simpler
substances by chemical means.

• 113 elements have been identified

• 82 elements occur naturally on Earth

Gold, aluminum, lead, oxygen, carbon

• 31 elements have been created by scientists

Technetium, americium, seaborgium
A compound is a substance composed of atoms of two or more
elements chemically united in fixed proportions.

Compounds can only be separated into their pure components

(elements) by chemical means.

Water (H2O) Glucose (C6H12O6)

Ammonia (NH3)
Classification of Matter

Separation by
physical methods

Separation by
chemical methods
Three states of Matter
 Physical or Chemical?

A physical change does not alter the composition or identity of a

substance.
ice melting sugar dissolving in water

A chemical change alter the composition or identity of the

substance(s) involved.

H burns in air to
form water
 Extensive and Intensive Properties
An extensive property of a material depends upon how much
matter is being considered.
• Mass
• Length
• Volume

An intensive property of a material does not depend upon how

much matter is being considered.
• Density
• Temperature
• Color
Measurements

1.7
(Multiple factor)

1.7
Volume – SI derived unit for volume is cubic meter (m3)
1 cm3 = (1 x 10-2 m)3 = 1 x 10-6 m3
1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3
1 L = 1000 mL = 1000 cm3 = 1 dm3
1 mL = 1 cm3

1.7
 Density – SI derived unit for density is kg/m3
1 g/cm3 = 1 g/mL = 1000 kg/m3

mass m
density = volume d= V

A piece of platinum metal with a density of 21.5

g/cm3 has a volume of 4.49 cm3. What is its mass?
m
d= V

m = d x V = 21.5 g/cm3 x 4.49 cm3 = 96.5 g

1.7
 Scientific Notation
The number of atoms in 12 g of carbon:
602,200,000,000,000,000,000,000
6.022 x 1023
The mass of a single carbon atom in grams:
0.0000000000000000000000199
1.99 x 10-23
N x 10n
N is a number n is a positive or
between 1 and 10 negative integer

1.8
 Scientific Notation
568.762 0.00000772
move decimal left move decimal right
n>0 n<0
568.762 = 5.68762 x 102 0.00000772 = 7.72 x 10-6

Addition or Subtraction
1. Write each quantity with 4.31 x 104 + 3.9 x 103
the same exponent n
2. Combine N1 and N2 = (4.31 x 104)+ (0.39 x 104)
3. The exponent, n, remains
the same = (4.31+ 0.39) x 104
* If different n, change to = 4.70 x 104
same n, then continue
with 2 1.8
 Scientific Notation

Multiplication
1. Multiply N1 and N2 (4.0 x 10-5) x (7.0 x 103)
= (4.0 x 7.0) x (10-5+3)
2. Add exponents n1 and n2
= 28 x 10-2
3. (N1 x N2)(n1+n2) =2.8 x 10-1

Division 8.5 x 104 ÷ 5.0 x 109

1. Divide N1 and N2 = (8.5 ÷ 5.0) x 104-9
= 1.7 x 10-5
2. Subtract exponents n1 and n2
3. (N1 / N2)(n1-n2)

1.8
 Significant Figures
•Any digit that is not zero is significant
1.234 kg 4 significant figures
•Zeros between nonzero digits are significant
606 m 3 significant figures
•Zeros to the left of the first nonzero digit are not significant
0.08 L 1 significant figure
•If a number is greater than 1, then all zeros to the right of the
decimal point are significant
2.0 mg 2 significant figures
•If a number is less than 1, then only the zeros that are at the
end and in the middle of the number are significant
0.00420 g 3 significant figures
•Trailing zero may or may not be significant 1.8
 How many significant figures are in
each of the following measurements?
24 mL 2 significant figures

3001 g 4 significant figures

0.0320 m3 3 significant figures

6.4 x 104 molecules 2 significant figures

560 kg 2 or 3 significant figures

1.8
 Significant Figures
Addition or Subtraction
The number of significant figure is determined by the smallest
No fo S.F. to the right of the decimal point.
89.332
+1.1 one significant figure after decimal point
90.432 round off to 90.4

3.70 two significant figures after decimal point

-2.9133
0.7867 round off to 0.79

1.8
 Significant Figures
Multiplication or Division
The number of significant figures in the result is set by the original
number that has the smallest number of significant figures
4.51 x 3.6666 = 16.536366 = 16.5

3 sig figs round to

3 sig figs

6.8 ÷ 112.04 = 0.0606926 = 0.061

2 sig figs round to

2 sig figs
1.8
 Significant Figures
Exact Numbers
Numbers from definitions or numbers of objects are considered
to have an infinite number of significant figures

The average of three measured lengths; 6.64, 6.68 and 6.70?

6.64 + 6.68 + 6.70

= 6.67333 = 6.67 = 7
3

Because 3 is an exact number

1.8
K = 0C + 273.15
273 K = 0 0C
373 K = 100 0C

F=
0 9 x 0C + 32
5
32 0F = 0 0C
212 0F = 100 0C

1.7
Convert 172.9 0F to degrees Celsius.
0
F= 9 x 0C + 32
5
0
F – 32 = 9 x 0C
5
5 x (0F – 32) = 0C
9

0
C = 5 x (0F – 32)
9
0
C = 5 x (172.9 – 32) = 78.3
9

1.7
Accuracy – how close a measurement is to the true value
Precision – how close a set of measurements are to each other

accurate precise not accurate

& but &
precise not accurate not precise

1.8