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    Proposal PPT 1

    Uploaded by

    Zargul Ammara
    ethanol to ethylene

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    © All Rights Reserved
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    Proposal PPT 1

    Uploaded by

    Zargul Ammara
    91 views10 pages
    ethanol to ethylene

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    Proposal Ppt 1

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    © © All Rights Reserved

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    ethanol to ethylene

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    91 views10 pages

    Proposal PPT 1

    Uploaded by

    Zargul Ammara
    ethanol to ethylene

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    You are on page 1of 10

    GROUP 3

    Group members
    Shamaim ul Hassan 2016-CH-447
    Zargul Ammara 2016-CH-404
    Tahir Mehmood 2016-CH-416
    Muhammad Awais 2016-CH-432
    Production of 342.5 kg/hr Ethylene
    by dehydration of Ethanol using
    0.5%Lanthanum and 2%
    Phosphorous modified HZSM-5
    catalyst
    Scope of project
    ■ Ethylene is the most essential organic compound in the world
    Major industrial uses of ethylene are as follows:
    ■ Polyvinyl chloride (PVC)
    ■ Polyethylene
    ■ Polyethylene terpthalate
    ■ Ethylene glycol
    ■ Detergents and surfactants
    ■ Polystyrene
    ■ Plasticizers
    ■ Explosives
    ■ Sulfur mustard gas
    Reference:
    • Aron miller.S,(1969),``Ethylene and its industrial derivatives``,Benn
    Demand of Ethylene
    ■ Demand in Pakistan ■ Demand in world

    Company Product Capacity (tons World 134 million ton/year


    per year)
    Asia Pacific 50 million ton/year
    Novatex PET 235,000
    U.S 25 million ton/year
    Engro polymers PVC 150,000

    Pak Poly styrene 90,000 Europe 20 million ton/year


    petrochemicals
    Dynea Pakistan Packaging ,urea 34,000 Middle East 20 million ton/year
    resin

    Reference:
    • https://www.bloomberg.com/press-releases/2019-05-24/global-ethylene-market-2016-2018-emergence-of-bio-
    ethylene-to-boost-the-market-technavio
    Manufacturing processes
    Process Temperature Emissions Selectivity By-products Cost Raw material

    Catalytic
    High High pollutant Low Present High capital cost Naphtha not
    cracking of
    emissions easily available
    higher
    hydrocarbons
    (conventional)

    Catalytic
    Comparatively Bio-green plant High Not present Low capital cost Ethanol easily
    dehydration
    low available
    of Ethanol
    (selected)

    Reference:
    • S.Seifzadeh Haghighi,aM.R.Rahimpourab (2013). Investigation of ethylene production in naphtha thermal cracking plant in presence of steam and carbon
    dioxide. Rchemical engineering journal, 15 July 2013.
    • Antonio Morschbacker (2009) Bio-Ethanol Based Ethylene, Journal of Macromolecular Science®,20 April 2009.
    Catalyst selection
    Catalyst name Conversion Selectivity Reaction temp Reactor type By-products Size of
    catalyst

    Aluminum 97% 96% 500-800oC Fixed bed Acetaldehyde, lumps


    oxide reactor diethyl ether,
    propene

    HZSM-5 99.5% 99.9% 250-280oC Fluidized bed No by- 0.5496 (nm)


    reactor products

    Reference:
    • Nina Zhan, Yi Hu, Heng Li, Dinghua Yu, Yuwang Han, He Huang(2009). Lanthanum–phosphorous modified HZSM-5 catalysts in
    dehydration of ethanol to ethylene: A comparative analysis, Nanjing University of Technology, Nanjing 210009, China,15 JANURAY
    2010.
    • Denise Fan 1, Der-Jong Dai 2 and Ho-Shing Wu (2012). Ethylene Formation by Catalytic Dehydration of Ethanol with Industrial
    Considerations, Materials 2013.
    Preliminary cost analysis
    Process Cost of catalyst Cost of raw Selectivity of Total Total capital
    materials the Product operating cost(17,00,00
    cost 0 TPY)

    Cracking 20,000$/ton 0.927$/liter 88-90% 491million 2.37billion$


    $/year

    Dehydration 8000- 0.614$/liter 99.9% 465million 1.91billion$


    10000$/ton $/year

    Reference:
    • Freiling, J. G., Huson, B. L., Summerville, R. N., "Which Feedstock for Ethylene," Hydrocarbon Processing (2011) 47 (11), 145.
    • Denise Fan 1, Der-Jong Dai 2 and Ho-Shing Wu (2012). Ethylene Formation by Catalytic Dehydration of Ethanol with Industrial
    Considerations, Materials 2013.
    Capacity selection
    1.20E+08 9.00E+07

    8.00E+07
    1.00E+08
    Trade value(Dollars) Quantity(kg) 7.00E+07

    8.00E+07 6.00E+07

    QUANTITYY)KG)
    QUANTITY (KG)

    5.00E+07
    6.00E+07
    4.00E+07

    4.00E+07 3.00E+07

    2.00E+07
    2.00E+07
    1.00E+07

    0.00E+00 0.00E+00
    2002 2004 2006 2008 2010 2012 2014 2016 2018 2020
    YEAR

    • Yearly import is 6-8 million kg per year


    • Selecting 50% of total import quantity of year 2018

    Reference:
    • United nations commodity trade statistics
    Capacity selection criteria
    Process flow diagram

    250-280 o C
    C2H5OH C2H2+H2O
    HZSM-5

    Reference:
    • Antonio Morschbacker (2009) Bio-Ethanol Based Ethylene, Journal of Macromolecular Science®,20 April 2009

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