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    2.5 EXERCISE 1 - Reactions of The Halogens and Halide Ions 1

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    Tr3sS1
    As you descend group VII, boiling point decreases and electronegativity increases while oxidizing power decreases. When combined with aqueous halide ions, halogens form products through oxidation-reduction reactions. Halides are reduced in the order F- < Cl- < Br- < I- based on their ability to be oxidized. Reactions of halogens with water and sodium hydroxide involve oxidation or displacement to form acids or salts. Reactions of more reactive halogens like fluorine or astatine with less reactive halides would likely involve oxidation or substitution based on their positions on the periodic table.

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    2.5 EXERCISE 1 - Reactions of The Halogens and Halide Ions 1

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    Tr3sS1
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    As you descend group VII, boiling point decreases and electronegativity increases while oxidizing power decreases. When combined with aqueous halide ions, halogens form products through oxidation-reduction reactions. Halides are reduced in the order F- < Cl- < Br- < I- based on their ability to be oxidized. Reactions of halogens with water and sodium hydroxide involve oxidation or displacement to form acids or salts. Reactions of more reactive halogens like fluorine or astatine with less reactive halides would likely involve oxidation or substitution based on their positions on the periodic table.

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    chemistry

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    arlindi1

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    As you descend group VII, boiling point decreases and electronegativity increases while oxidizing power decreases. When combined with aqueous halide ions, halogens form products through oxidation-reduction reactions. Halides are reduced in the order F- < Cl- < Br- < I- based on their ability to be oxidized. Reactions of halogens with water and sodium hydroxide involve oxidation or displacement to form acids or salts. Reactions of more reactive halogens like fluorine or astatine with less reactive halides would likely involve oxidation or substitution based on their positions on the periodic table.

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    © All Rights Reserved
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    Download as doc, pdf, or txt
    61 views1 page

    2.5 EXERCISE 1 - Reactions of The Halogens and Halide Ions 1

    Uploaded by

    Tr3sS1
    As you descend group VII, boiling point decreases and electronegativity increases while oxidizing power decreases. When combined with aqueous halide ions, halogens form products through oxidation-reduction reactions. Halides are reduced in the order F- < Cl- < Br- < I- based on their ability to be oxidized. Reactions of halogens with water and sodium hydroxide involve oxidation or displacement to form acids or salts. Reactions of more reactive halogens like fluorine or astatine with less reactive halides would likely involve oxidation or substitution based on their positions on the periodic table.

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    © All Rights Reserved
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    of 1

    2.

    5 EXERCISE 1 reactions of the halogens and halide ions


    1.

    Describe and explain the how the following properties of the halogens change as
    you descend group VII:
    a)
    b)
    c)

    2.

    3.

    boiling point
    electronegativity
    oxidising power

    Describe what you see if you combined the following reagents, and write
    equations for any reactions that take place:
    a)
    b)
    c)
    d)
    e)
    f)

    chlorine with aqueous sodium bromide


    chlorine with aqueous sodium iodide
    bromine with aqueous sodium chloride
    bromine with aqueous sodium iodide
    iodine with aqueous sodium chloride
    iodine with aqueous sodium bromide

    a)

    Write half-equations to show the following processes:


    i)
    The reduction of H2SO4 to SO2
    ii)
    The reduction of H2SO4 to H2S
    iii)
    The oxidation of Br- to Br2
    iv)
    The oxidation of I- to I2

    b)

    Write equations to show the following processes:


    i)
    The reduction of H2SO4 to SO2 by bromide ions
    ii)
    The reduction of H2SO4 to H2S by iodide ions
    iii)
    The reaction between H2SO4 and chloride ions

    c)

    Explain what you would observe in the reactions in (b).

    d)

    Explain what these reactions tell you about the reducing power of the
    halides.

    5.

    Write equations for the reactions of chlorine with water and cold dilute sodium
    hydroxide solution. Give a use for each reaction.

    6.

    Based on their position in the Periodic Table, suggest what would happen when:
    a)
    b)
    c)
    d)
    e)

    fluorine was bubbled through sodium astatide solution


    astatine was mixed with sodium fluoride solution
    silver astatide was dissolved in concentrated ammonia
    sodium fluoride was reacted with concentrated sulphuric acid
    sodium astatide was reacted with concentrated sulphuric acid

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