2007 A

THE CANADIAN CHEMISTRY CONTEST 2007
for high school and CEGEP students

(formerly the National High School Chemistry Examination)
PART A - MULTIPLE CHOICE QUESTIONS (60 minutes)
All contestants should attempt this part of the examination before proceeding to Part B (the CIC Exam) and/or Part C (the CCO Exam).
A CIC/CCO Periodic Table is required, but no other data may be given. Answers should be marked on the Answer Grid provided.
1.
The following substances have all been used in general anaesthetics.

Which one MUST be kept away from flames?
A.
B.
C.
D.
E.
2.
Xenon, Xe
Nitrous oxide, N2O
Chloroform (trichloromethane), CHCl3
Ether (ethoxyethane), CH3CH2OCH2CH3
Isoflurane (2-chloro-2-(difluoromethoxy)-1,1,1-trifluoroethane),
CF3CHClOCHF2
B. BrF3
B. Cl
7.
E. NH4
8.
C. P
D. S
E. Se
B. B
C. C
D. N
Which one of the following responses correctly identifies the structure

of all the substances shown in the table? All the substances are pure and
in their solid state.
Substance
LiCl
HCl
CH3OCH3
C(graphite)
B. 4.0
A.
Ionic
Ionic
Molecular
B.
Ionic
Metallic
Molecular
C.
Ionic
Molecular
Molecular
D.
E.
Ionic
Molecular
Molecular
Ionic
Metallic
Ionic
Covalent
network
Covalent
network
Covalent
network
Atomic
Atomic
Atomic
A. {1.0 x 10
32
C. {1.0 x 10
Metallic
Metallic
13
14
B. 1.2 x 10
15
E. 1.2 x 10
E. {1.0 x 10
1/4
/27}
1/3
/27}
32
Atomic
Metallic
E. 10.3
C. 1.0 x 10
Aluminum hydroxide (Mr = 78.0) is used in the dyeing industry. What

mass (in kg) will be required to saturate 1000 L of water at 298 K if the
32
solubility product constant Ksp{Al(OH)3} = 1.0 x 10 at 298 K?
32
Response
D. 10. 0
14
15
9.
C. 8.0
The ionic product of water, Kw, is 1.0 x 10 at 298 K. Given that the
neutralisation of a strong acid with a strong base is an exothermic
reaction, which one of the following is likely to be the value of Kw at
273 K?
A. 1.2 x 10
14
D. 1.2 x 10
E. Si
B. OF, BeF, CF
D. BeF, CF, OF
Magnesium hydroxide, Mg(OH)2, is used in antacid tablets. It is a

strong base, which is completely dissociated in water. What is the pH of
1
o
a solution of Mg(OH)2 with a concentration of 0.0001 mol L at 25 C?
A. 3.7
Which of the following atoms has the largest first ionization energy?
A. Al
5.
D. CH4
Which of the following atoms has the smallest atomic radius?

A. Br
4.
C. H2O
Select the response below that lists the bonds in order of increasing
polarity (least polar to most polar):
A. OF, CF, BeF
C. BeF, OF, CF
E. CF, OF, BeF
Which one of the following species has only one lone pair (nonbonding pair) of electrons on the central atom?
A. NH3
3.
6.
1/4
/81}
32
x 78.0
B. {1.0 x 10
32
x 78.0
D. {1.0 x 10
1/4
78.0
1/3
78.0
/27}
/81}
x 78.0
2+
3+
10. The iodate ion (IO3 ) can oxidize Fe to Fe in acid solution. If IO3
is reduced to iodide (I ) in this reaction, then the number of moles of
2+
Fe that can be oxidized by 1 mole of IO3 is
A. 2
B. 3
C. 4
D. 5
E. 6
CCC 2007 page 2 of 4

11. Vitamin C is ascorbic acid, which is a monoprotic acid of formula
C6H8O6. When a 500-mg tablet of pure vitamin C is dissolved in 100
mL of water, the pH of the solution is measured as 2.83. The acid
dissociation constant, Ka, of ascorbic acid is therefore:
A. 1.0 x 10
14
B. 2.2 x 10
D. 1.5 x 10
E. 5.5 x 10
C. 8.1 x 10
12. A group of researchers did an experiment to determine the mass ratio of

molybdenum to oxygen in two different oxides. They combined their
results to give the graph shown below:
3.0
Oxide (1)
Mass of
molybdenum, 2.0
grams
Oxide (2)
2 Fe2O3(s) + 3 C(graphite) 4 Fe(s) + 3 CO2(g)

What is the maximum mass of iron metal can be obtained from 1235 kg
of iron(III) oxide and 154.0 kg of graphite?
A. 477.5 kg
D. 953.1 kg
B. 863.8 kg
E. 955.7 kg
C. 714.8 kg
15. Oxalic acid (ethanedioic acid, H2C2O4) has many uses in metal
cleaning, textile dyeing and photography. Suppose you dissolve a
1.034 -g sample of impure oxalic acid in some water, add an acid-base
1
indicator, and titrate with NaOH (0.485 mol L ). The sample requires
34.47 mL of the NaOH solution to reach the equivalence point. The
equation for the titration reaction is:
H2C2O4(aq) + 2 OH (aq) C2O4 (aq) + 2 H2O(l)
1.0
0.0
0.0
What is the mass of oxalic acid and what is its mass percent in the
sample?
0.5
A. 0.547 g, 52.9%
D. 0.752 g, 72.8%
1.0
1.5
Mass of oxygen, grams
From these results it can be deduced that the formulae of the two metal
oxides are:
Oxide (1)
Oxide (2)
14. An example of a highly exothermic thermite reaction is used in the

production of iron by the blast furnace process. The equation for this
reaction is:
A
MoO
Mo2O3
B
Mo2O
Mo3O
C
Mo3O
Mo2O
D
MoO2
MoO3
E
MoO3
MoO2
B. 0.654 g, 63.2%
E. 0.856 g, 82.8%
C. 0.729 g, 70.5%
16. Warfarin is an anticoagulant used to decrease the clotting ability of

blood so that thrombosis is prevented, while avoiding spontaneous
bleeding. The structural formula of Warfarin is given below:
OH
13. Flutamide (Eulexin ) is an important organic compound containing

three fluorine atoms in each molecule. It is used in the treatment of
prostate cancer. An analytical chemist extracted flutamide from a
commercial tablet weighing 203.21 mg leaving a residue (containing
non-medicinal ingredients) that weighed 128.23 mg. Elemental analysis
of the extracted flutamide revealed the presence of 15.47 mg of
1
fluorine. What is the molar mass (in g mol ) of flutamide?
A. 232.8
B. 254.5
C. 276.2
D. 286.9
E. 303.1
Four of the functional groups present in Warfarin are:

A. ether, alkene, ketone, ester
B. ether, alkene, ester, alcohol
C. ester, alkene, alcohol, ketone
D. ether, ketone, alkene, alcohol
E. ester, alcohol, alkene, aldehyde
energy
17. The following diagram shows the energy profile of a reaction:
19. The table below gives the solubilities of sodium nitrate and lithium
chloride in 100 g of water at 20oC and 60oC.
Products
reaction progress
Which one of the following correctly identifies the type of reaction

shown in the diagram, together with the correct reason for this choice?
Type of reaction
Exothermic
Exothermic
Exothermic
D.
E.
Endothermic
Endothermic
Reason
Energy is supplied to the reactants
Energy is given out by the reaction
The products have a higher potential energy
than the reactants
Energy is given out by the reaction
The products have a higher potential energy
than the reactants
I)
IV) CO(g) + 3 H2(g)
what is the enthalpy of combustion

1
A. I and II
1
A. 1256 kJ mol
1
D. +1256 kJ mol
B. 2511 kJ mol
1
E. +2511 kJ mol
mole of ethyne?
1
C. 1604 kJ mol
CH4(g) + H2O(g)
Assuming that each of these reactions has achieved equilibrium, which

two would NOT then be affected by an increase in pressure (by reducing
the volume, and with the temperature kept constant)?
Hf {C2H2(g)} = + 226.7 kJ mol , Hf {CO2(g)} = 393.5 kJ mol

o
1
and Hf {H2O(g)} = 241.8 kJ mol
o
(Hc ) per
1
C(graphite) + S2(g) CS2(g)
III) CH4(g) + 2 S2(g) CS2(g) + 2 H2S(g)
Given the following enthalpies of formation:

o
6.9 g of solid containing 36% LiCl

6.9 g of solid containing 64% LiCl
20.0 g of solid containing 22.0% LiCl
II) CO2(g) + C(graphite) 2 CO(g)
2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(g)

1
A.
B.
C.
D.
E.
20. Consider the following reactions:
18. Acetylene (ethyne) is burned in oxy-acetylene blowtorches, which

are used for cutting and welding metals. The combustion reaction is
represented by the following equation:
60oC
125 g
103 g
A 40.0-g sample of a mixture that is 50.0% by mass in each of sodium

nitrate and lithium chloride is stirred in 20.0 g of water at 60oC until all
of it dissolves. When the solution is cooled down to 20oC, white
crystals appear and the latter are carefully recovered by filtration.
Which one of the following gives the correct mass of recovered solid
and the percent by mass of lithium chloride in it?
Reactants
A.
B.
C.
20oC
87.5 g
78.0 g
Solubility in 100 g of water

Sodium nitrate
Lithium chloride
B. I and III
C. I and IV
D. II and III
E. II and IV
21. Given the following standard reduction potentials:
2 H2O(l) + 2e H2(g) + 2 OH (aq);
O2(g) + 2 H2O(l) + 4e 4 OH (aq);
E = 0.83 V
o
E = +0.40 V
What is the electromotive force of a fuel cell with the overall reaction:
2 H2(g) + O2(g) 2 H2O(l) ?
A. 1.23 V
B. 0.43 V
C. +0.43 V
D. +1.23 V
E. +2.06 V
1/time, s
22. The following graph shows the effect of initial temperature on the rate
of reaction for a series of experiments performed on the same reaction,
with the same initial concentrations of reactants. (Note that each
experiment is performed as a clock reaction, so it is only timed up to
a certain point, and you can assume that the rate is proportional to
1/time.)
0.140
0.120
0.100
0.080
0.060
0.040
0.020
0.000
Br
HO
H+ +
H3C
III
H3C
O
Vanillin
HO
H3C
C
H2
OH
HO
H3C
OH
Identify which type of reaction is taking place during steps I, II and III.
40
50
60
70
80
90
Initial temperature, in C
Which one of the following statements can be correctly deduced from

this graph:
The reaction is exothermic
The reaction is endothermic
The rate of reaction increases with initial temperature
The rate of reaction decreases with initial temperature
The time taken for the reaction to be completed increases with
initial temperature
A.
B.
C.
D.
E.
I
reduction
oxidation
reduction
reduction
oxidation
II
oxidation
reduction
oxidation
oxidation
reduction
N2(g) + 3 H2(g) 2 NH3(g)

If the equilibrium constant for this reaction is K, then which one of the
following will be the equilibrium constant when the concentration of
hydrogen gas in the mixture is doubled (at the same temperature)?
B. K/4
C. K
D. 2K
III
substitution
substitution
elimination
addition
addition
25. Treatment of the organic substance 2,3,5-trimethyl-3-hexanol (structure

below) with aqueous sulfuric acid causes a dehydration reaction.
Three alkene products are formed in unequal amounts:
2,3,5-trimethyl-2-hexene (I), 2-isopropyl-4-methyl-1-pentene (II), and
2,3,5-trimethyl-3-hexene (III).
23. The following equilibrium reaction is the basis for the production of
ammonia used in fertilizers:
A. K/8
HO
II
30
A.
B.
C.
D.
E.
24. Vanillin, the primary component of the extract of the vanilla bean,
undergoes several chemical reactions as shown below:
OH
Which of these three alkenes can exist as geometric isomers?

A. I only
B. I and II only
D. II and III only
C. I, II and III
E. III only
E. K
This is the end of Part A of the contest.

Now go back and check your work.

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THE CANADIAN CHEMISTRY CONTEST 2007

for high school and CEGEP students

The following substances have all been used in general anaesthetics.

Which one of the following responses correctly identifies the structure

Aluminum hydroxide (Mr = 78.0) is used in the dyeing industry. What

Magnesium hydroxide, Mg(OH)2, is used in antacid tablets. It is a

Which of the following atoms has the smallest atomic radius?

is reduced to iodide (I ) in this reaction, then the number of moles of

CCC 2007 page 2 of 4

12. A group of researchers did an experiment to determine the mass ratio of

2 Fe2O3(s) + 3 C(graphite) 4 Fe(s) + 3 CO2(g)

H2C2O4(aq) + 2 OH (aq) C2O4 (aq) + 2 H2O(l)

14. An example of a highly exothermic thermite reaction is used in the

16. Warfarin is an anticoagulant used to decrease the clotting ability of

13. Flutamide (Eulexin ) is an important organic compound containing

Four of the functional groups present in Warfarin are:

CCC 2007 page 3 of 4

17. The following diagram shows the energy profile of a reaction:

Which one of the following correctly identifies the type of reaction

IV) CO(g) + 3 H2(g)

what is the enthalpy of combustion

Assuming that each of these reactions has achieved equilibrium, which

Hf {C2H2(g)} = + 226.7 kJ mol , Hf {CO2(g)} = 393.5 kJ mol

C(graphite) + S2(g) CS2(g)

III) CH4(g) + 2 S2(g) CS2(g) + 2 H2S(g)

Given the following enthalpies of formation:

6.9 g of solid containing 36% LiCl

II) CO2(g) + C(graphite) 2 CO(g)

2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(g)

20. Consider the following reactions:

18. Acetylene (ethyne) is burned in oxy-acetylene blowtorches, which

A 40.0-g sample of a mixture that is 50.0% by mass in each of sodium

Solubility in 100 g of water

21. Given the following standard reduction potentials:

2 H2O(l) + 2e H2(g) + 2 OH (aq);

O2(g) + 2 H2O(l) + 4e 4 OH (aq);

CCC 2007 page 4 of 4

Which one of the following statements can be correctly deduced from

N2(g) + 3 H2(g) 2 NH3(g)

25. Treatment of the organic substance 2,3,5-trimethyl-3-hexanol (structure

Which of these three alkenes can exist as geometric isomers?

D. II and III only

This is the end of Part A of the contest.

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