2017 U.S.

NATIONAL
CHEMISTRY OLYMPIAD
NATIONAL EXAM PART I
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force

OLYMPIAD EXAMINATIONS TASK FORCE

Seth N. Brown, Chair, University of Notre Dame, Notre Dame, IN
James Ayers, Colorado Mesa University, Grand Junction, CO
Mark DeCamp, University of Michigan, Dearborn, MI (retired)
Marian DeWane, Centennial High School, Boise, ID
Xu Duan, Holton-Arms School, Bethesda, MD
Valerie Ferguson, Moore HS, Moore, OK
Julie Furstenau, Thomas B. Doherty HS, Colorado Springs, CO
Kimberly Gardner, United States Air Force Academy, CO
Paul Groves, South Pasadena HS, South Pasadena, CA
David W. Hostage, Taft School, Watertown, CT
Dennis Kliza, Kinkaid School, Houston, TX
John Kotz, State University of New York, Oneonta, NY (retired)
Jane Nagurney, Scranton Preparatory School, Scranton, PA
Sheila Nguyen, Cypress College, Cypress, CA
Ronald Ragsdale, University of Utah, Salt Lake City, UT (retired)

DIRECTIONS TO THE EXAMINER – PART I

The USNCO Subcommittee is conducting a survey in an effort to determine the impact of the Olympiad program on students.
At the end of the exam there are four questions, which should be answered on the same Scantron sheet students use for the
exam. These questions may be administered after the 90 minutes allotted for the exam, each student should be encouraged to
answer these questions.
Part I of this test is designed to be taken with a Scantron answer sheet on which the student records his or her responses. Only this
Scantron sheet is graded for a score on Part I. Testing materials, scratch paper, and the Scantron sheet should be made available to the
student only during the examination period. All testing materials including scratch paper should be turned in and kept secure until
April 26, 2017, after which tests can be returned to students and their teachers for further study.
Allow time for students to read the directions, ask questions, and fill in the requested information on the Scantron sheet. The answer
sheet must be completed using a pencil, not pen. When the student has completed Part I, or after one hour and thirty minutes has
elapsed, the student must turn in the Scantron sheet, Part I of the testing materials, and all scratch paper.
There are three parts to the National Chemistry Olympiad Examination. You have the option of administering the three parts in any
order, and you are free to schedule rest breaks between parts.
Part I 60 questions single answer, multiple-choice 1 hour, 30 minutes
Part II 8 questions problem-solving, explanations 1 hour, 45 minutes
Part III 2 lab problems laboratory practical 1 hour, 30 minutes
A periodic table and other useful information are provided on page 2 for student reference.
Students should be permitted to use non-programmable calculators. The use of a programmable calculator, cell phone, watch,
or any other device that can access the internet or make copies or photographs during the exam is grounds for disqualification.
DIRECTIONS TO THE EXAMINEE – DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO. Answers to questions in
Part I must be entered on a Scantron answer sheet to be scored. Be sure to write your name on the answer sheet, an ID number is
already entered for you. Make a record of this ID number because you will use the same number on Parts II and III. Each item in
Part I consists of a question or an incomplete statement that is followed by four possible choices. Select the single choice that best
answers the question or completes the statement. Then use a pencil to blacken the space on your answer sheet next to the same letter as
your choice. You may write on the examination, but the test booklet will not be used for grading. Scores are based on the number of
correct responses. When you complete Part I (or at the end of one hour and 30 minutes), you must turn in all testing materials, scratch
paper, and your Scantron answer sheet. Do not forget to turn in your U.S. citizenship/Green Card Holder statement before
leaving the testing site today.

Property of ACS USNCO ‒ Not for use as USNCO National Exam after April 24, 2017
Distributed by the American Chemical Society, 1155 16 th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.
 ABBREVIATIONS AND SYMBOLS CONSTANTS
amount of substance n Faraday constant F molar mass M
R = 8.314 J mol– K–
1 1
ampere A free energy G mole mol
R = 0.08314 L bar mol– K–
1 1
atmosphere atm frequency  Planck’s constant h
F = 96,500 C mol–
atomic mass unit u 1
gas constant R pressure P
Avogadro constant NA gram g rate constant k
F = 96,500 J V mol–
–1 1
Celsius temperature °C hour h reaction quotient Q
NA = 6.022  1023 mol–
1
centi– prefix c joule J second s
coulomb C kelvin K speed of light c h = 6.626  10–34 J s
density d kilo– prefix k temperature, K T
c = 2.998  108 m s–
1
electromotive force E liter L time t
energy of activation Ea measure of pressure mm Hg vapor pressure VP 0 °C = 273.15 K
enthalpy H milli– prefix m volt V 1 atm = 1.013 bar = 760 mm Hg
entropy S molal m volume V Specific heat capacity of H2O =
equilibrium constant K molar M
4.184 J g– K–
1 1

EQUATIONS

RT  H o   1  k  E  1 1 
E  Eo  ln Q ln K       constant ln  2   a   
nF  R  T   k1  R  T1 T2 

1 PERIODIC TABLE OF THE ELEMENTS 18

1A 8A
1 2
H 2 13 14 15 16 17 He
1.008 2A 3A 4A 5A 6A 7A 4.003

3 4 5 6 7 8 9 10
Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.99 24.31 3B 4B 5B 6B 7B 8B 8B 8B 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.97 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.95 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
(223) (226) (227) (261) (262) (263) (262) (265) (266) (281) (272) (285) (286) (289) (289) (293) (294) (294)

58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (145) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)

Page 2 Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017
 DIRECTIONS
 When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
 There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
 Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.

1. Lithium reacts with water to form lithium hydroxide. 7. When a solution of barium hydroxide is mixed with a
What mass of lithium is required to produce 12 g of solution of iron(III) chloride, what is observed?
lithium hydroxide?
(A) Precipitation of a colored solid
(A) 2.0 g (B) 3.5 g (C) 7.0 g (D) 12 g
(B) Precipitation of a colorless solid
2. Complete combustion of 1.00 g of the hydrocarbon (C) Evolution of a colorless gas
pagodane gives 3.38 g carbon dioxide. What is the
empirical formula of pagodane? (D) Neither precipitation nor gas evolution

8. Which element is a liquid at 25 ºC and 1 atm pressure?

(A) CH (B) CH2 (C) C2H5 (D) C3H8

3. Electrolysis of 10.00 g of a binary metal chloride deposits (A) Fluorine (B) Chlorine
6.207 g of the pure metal. What is the metal? (C) Bromine (D) Iodine

(A) Cu (Z = 29) (B) Cd (Z = 48) 9. The concentration of which approximately 0.01 M

solution could be most accurately determined by a visible
(C) Ce (Z = 58) (D) Th (Z = 90)
spectrophotometer (or colorimeter)?
4. Decomposition of 1.0 g of which of the following
compounds into its constituent elements gives the greatest (A) Mn(NO3)2 (B) Co(NO3)2
amount of N2 gas? (C) Zn(NO3)2 (D) Pb(NO3)2
(A) NO (B) NO2 (C) N2O4 (D) NH3 10. A 0.1 M solution of which salt is the most acidic?
5. Permanganate ion oxidizes hydrogen peroxide in acidic (A) Al(NO3)3 (B) MgBr2
solution according to the following equation:
(C) NaHCO3 (D) NaHCO2
2 MnO4–(aq) + 5 H2O2(aq) + 6 H+(aq) 
2 Mn2+(aq) + 5 O2(g) + 8 H2O(l) 11. A gas with P = 615 mm Hg is contained in the U-tube as
shown. If h = 65 mm, what is the atmospheric pressure
If 35.0 mL of an acidic 0.150 M KMnO4 solution is Patm?
required to consume all the H2O2 in 50.0 mL of a
disinfectant solution, what is the concentration of H2O2 in
the disinfectant?

(A) 0.0420 M (B) 0.105 M

(C) 0.263 M (D) 0.368 M

6. A solution containing 10 g of which substance dissolved

in 100 g of water will show the greatest freezing point
depression compared to pure water?

(A) Anhydrous magnesium sulfate, MgSO4

(B) Magnesium sulfate heptahydrate, MgSO4•7 H2O
(C) Anhydrous sodium thiosulfate, Na2S2O3
(A) 550 mm Hg (B) 615 mm Hg
(D) Sodium thiosulfate pentahydrate, Na2S2O3•5 H2O
(C) 680 mm Hg (D) 760 mm Hg

Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017 Page 3
 12. What is the reading of the buret shown? 16. What is the principal energetic factor in the lack of
miscibility between C6H14(l) and H2O(l)?

(A) The strength of intermolecular forces of attraction

between C6H14(l) molecules
(B) The strength of intermolecular forces of attraction
between H2O(l) molecules
(C) The difference between the molecular weights of the
molecules
(D) The difference in electronegativity between carbon
and hydrogen

(A) 30.20 mL (B) 30.25 mL 17. The melting point of silicon dioxide (1713 ºC) is higher
than the melting point of silicon (1414 ºC). What is the
(C) 30.30 mL (D) 31.75 mL best explanation for this difference?
13. A beaker containing 25 mL of liquid 1-aminopentane, (A) Silicon-oxygen bonds are stronger than silicon-
CH3(CH2)4NH2, is placed on a hotplate and brought to a silicon bonds.
boil. As the 1-aminopentane boils,
(B) Silicon dioxide is an ionic solid while silicon is a
(A) the total energy of the system stays constant. metallic solid.
(B) the hydrogen bonding between the 1-aminopentane (C) Silicon dioxide is polar while silicon is nonpolar.
molecules is disrupted. (D) Silicon dioxide forms tetragonal crystals while
(C) the ion-dipole forces between the 1-aminopentane silicon forms cubic crystals.
molecules are disrupted.
18. A unit cell of the cubic form of ZnS is shown below
(D) pentane and ammonia gas are formed. (large spheres = Zn, small spheres = S). How many of
each type of atom are present in one unit cell?
14. Into both ends of a meter-long glass tube samples of
gases are introduced simultaneously. One end receives
hydrogen chloride gas (HCl) while the other end receives
ammonia gas (NH3). When the gases meet in the tube,
they react to form solid ammonium chloride (NH4Cl).
Where in the tube does the NH4Cl form?

(A) At the center of the tube

(B) Closer to the end where the hydrogen chloride is
inserted
(C) Closer to the end where the ammonia is inserted
(D) Uniformly at all positions in the tube

15. At its normal boiling point of –1.0 ºC, a sample of

gaseous butane at 1.0 atm occupies a volume of 1.0 L.
What is the pressure if the volume is decreased to 0.70 L
while maintaining the temperature at –1.0 ºC?
(A) 1 Zn, 1 S (B) 2 Zn, 4 S
(A) 0.70 atm (B) 1.0 atm (C) 4 Zn, 4 S (D) 4 Zn, 14 S
(C) 1.4 atm (D) 2.0 atm

Page 4 Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017
 19. What is ∆Hº for the reaction shown? 23. What is ∆Gºf of CH4(g) at 298 K? (All data are given at
298 K.)
2 H2S(g) + 3 O2(g)  2 H2O(l) + 2 SO2(g)
–1 – –1 –1
Substance ∆Hºf, kJ mol Sº, J mol 1 K ∆Gºf, kJ mol
Compound ∆Hºf, kJ mol–1 CH4(g) –74.8 186.3
H2S(g) –20.15 H2(g) 0.0 130.7 0.0
H2O(l) –285.8 CO2(g) –393.5 213.7 –394.4
SO2(g) –296.4 H2O(g) –241.8 188.8 –228.6
–1 –1
(A) –19.4 kJ mol (B) –374.7 kJ mol (A) –50.7 kJ mol–1 (B) –75.7 kJ mol–1
(C) –562.1 kJ mol–1 (D) –1124.1 kJ mol–1 (C) –98.0 kJ mol–1 (D) –130.3 kJ mol–1
20. Upon which factors can the Gibbs free energy change for 24. A solution containing 0.060 mol NaOH dissolved in 200 g
a reaction (∆Grxn) depend? water was treated with successive aliquots of 6.0 M aqueous
I. Temperature HCl in a well-insulated flask, and the temperature was
II. Concentration of species in solution measured after each aliquot to give the following data:

(A) I only (B) II only

(C) Both I and II (D) Neither I nor II

21. The natural logarithm of the vapor pressure (in bar) of

HCN(s) as a function of the reciprocal of the absolute
temperature is plotted below.

The same experiment was repeated, again using 0.060 mol

NaOH and 6.0 M aqueous HCl, but this time the NaOH was
initially dissolved in 400 g water. Which graph represents
the data obtained in this experiment?

(A) (B)

What is the heat of sublimation of HCN?

(A) 4.54 kJ mol–1 (B) 15.9 kJ mol–1

(C) 37.8 kJ mol–1 (D) 132 kJ mol–1

22. Which has the greatest entropy at 0 ºC? (C) (D)

(A) 1.0 mol H2O(s)

(B) 1.0 mol H2O(l)
(C) 1.0 mol H2O(g)
(D) 1.0 mol H2(g) + 0.5 mol O2(g)

Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017 Page 5
25. For the reaction A + B  products, the rate law is rate = 29. Hydrogen peroxide disproportionates to water and
k[A]2[B]. Which change will cause the greatest decrease molecular oxygen in the presence of iodide in neutral
in reaction rate? solution according to a mechanism consisting of two
elementary steps:
(A) Decreasing [A] by a factor of 2
H2O2(aq) + I –(aq)  IO–(aq) + H2O(l) reaction 1
(B) Decreasing [B] by a factor of 2
H2O2(aq) + IO–(aq)  I –(aq) + O2(g) + H2O(l) reaction 2
(C) Decreasing both [A] and [B] by a factor of 2
The rate constant for reaction 1 is much larger than the
(D) Decreasing [B] by a factor of 4 rate constant for reaction 2. Which statement is correct?

26. For a reaction with an activation energy of 65 kJ mol–1, (A) As the reaction proceeds, the predominant form of
by what percentage is the rate constant decreased if the iodine in solution is IO–(aq).
temperature is decreased from 37 °C to 22 °C?
(B) Adding more iodide to the reaction will not increase
(A) 13% (B) 27% (C) 51% (D) 72% the rate of production of O2.
(C) The reaction is zeroth-order in H2O2.
27. A plot of ln[A] as a function of time in an irreversible
reaction A → products is linear, with a slope of (D) The reaction will go more slowly at higher O2
–0.0175 s–1. What conclusions may be drawn from these pressures.
observations?
30. Which of the following are true about the overall reaction
I. The reaction is first-order in A. A + B  D illustrated in the diagram?
II. The rate constant for the reaction is 0.0175 s–1.

(A) I only (B) II only

(C) Both I and II (D) Neither I nor II

28. A sample containing only the isotope 99Mo undergoes

radioactive decay as shown:

β γ
99Mo 99mTc 99Tc
t1/2 = 65 h t1/2 = 6 h

Which of the following statements about the relative

activity of 99Mo and 99mTc in the sample is correct?
I. The reaction displays second-order kinetics.
99m 99 II. The reaction has two intermediates.
(A) The activity of Tc exceeds that of the Mo after
about 20 h.
(A) I only (B) II only
(B) The activity of 99mTc exceeds that of the 99Mo after
(C) Both I and II (D) Neither I nor II
about 120 h.
(C) The activity of 99mTc becomes roughly equal to that 31. What is the pH of a 0.25 M solution of NaCN? (The pKa
of the 99Mo after about 20 h. of HCN is 9.21.)
(D) The activity of 99mTc becomes roughly equal to that
(A) 4.91 (B) 8.61 (C) 11.30 (D) 13.40
of the 99Mo after about 120 h.
32. The autoionization constant of water at 60 ºC is
Kw = 1.0  10–13. Which of the following statements are
correct?
I. Autoionization of water is exothermic.
II. A sample of pure water at 60 ºC is slightly acidic.

(A) I only (B) II only

(C) Both I and II (D) Neither I nor II

Page 6 Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017
 33. Barium carbonate, BaCO3, is stable at ambient 38. When the following skeleton equation is balanced with
temperatures, but decomposes to barium oxide and smallest whole number coefficients, what is the
carbon dioxide at higher temperatures. coefficient and location of H2O(l)? The reaction takes
place in basic solution.
BaCO3(s) BaO(s) + CO2(g)
At a certain temperature, this system is in equilibrium in a Cu(s) + MnO4–(aq)  Cu(OH)2(s) + MnO2(s)
closed system and contains appreciable amounts of all
three compounds. Which changes will lead to an increase (A) 2, on reactant side (B) 4, on reactant side
in the pressure of CO2 present at equilibrium? (C) 2, on product side (D) 4, on product side
I. Adding more BaCO3(s)
II. Increasing the volume of the container 39. Which of the following species contains the element in
the highest oxidation state?
(A) I only (B) II only
(A) OsO4 (B) Mn2(CO)10
(C) Both I and II (D) Neither I nor II
(C) N5+ (D) XeF82–
34. If 0.10 mol solid NaOH is added to 1.00 L of a saturated
40. What is the standard reduction potential of Hg2+(aq) to
solution of Ca(OH)2 (Ksp = 8.0  10–6), what percentage
Hg(l)?
of the calcium hydroxide will precipitate at equilibrium?
Half Reaction Eº, V
(A) Roughly 50% (B) Roughly 75%
2 Hg2+(aq) + 2e–  Hg22+(aq) +0.90
(C) Roughly 95% (D) Over 99%
Hg22+(aq) + 2e–  2 Hg(l) +0.80
35. The concentration of formic acid (pKa = 3.75) is being
determined by titration with sodium hydroxide solution. (A) +1.70 V (B) +0.85 V
Which indicators are suitable for this titration? (C) +0.10 V (D) –0.10 V
I. Bromophenol blue (pH transition range 3.0 – 4.6)
II. Neutral red (pH transition range 6.8 – 8.0) 41. The lead-acid storage battery consists of the following
two half-cells:
(A) I only (B) II only PbO2(s) + 4 H+(aq) + SO42-(aq) + 2 e–  PbSO4(s) + 2 H2O(l)
(C) Both I and II (D) Neither I nor II Pb(s) + SO42-(aq)  PbSO4(s) + 2 e–
Which of the following concentrations decrease as the
36. The ionization of ammonium ion is endothermic: battery is discharged?
NH4+(aq) + H2O(l)  NH3(aq) + H3O+(aq) I. [H+] II. [Pb2+]
∆Hº > 0
(A) I only (B) II only
Which changes will result in the increase in [H3O+] of a
0.100 M solution of NH4Cl? (C) Both I and II (D) Neither I nor II

I. Diluting the solution from 1.00 L to 2.00 L 42. Which graph represents the reduction potential of O2 (at 1
II. Raising the temperature from 25 ºC to 35 ºC bar pressure and 25 ºC) as a function of pH?

(A) I only (B) II only O2(g) + 4 H+(aq) + 4 e–  2 H2O(l) Eº = 1.23 V

(C) Both I and II (D) Neither I nor II (A) (B)

37. Which changes to this galvanic cell increase the measured

potential?
Cu(s) | Cu2+(aq), 0.10 M || Ag+(aq), 1.0 M | Ag(s)

I. Increasing [Cu2+] in the Cu/Cu2+ half-cell to 0.50 M

II. Adding Cl– to the Ag+/Ag half-cell until [Cl–] = 0.01 M (C) (D)

(A) I only (B) II only

(C) Both I and II (D) Neither I nor II

Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017 Page 7
 43. In a ground-state P atom in the gas phase, how many 51. How many distinct C–O bond lengths are present in the
electrons have quantum numbers n = 3, l = 1, ml = –1? oxalate ion, C2O42–?

(A) 0 (B) 1 (C) 2 (D) 3 (A) 1 (B) 2 (C) 3 (D) 4

44. Rank the elements Si, P, Ge, and As in increasing order 52. Which statement about the molecular orbitals in a
of their first ionization energies. molecule is correct?

(A) Si < P < Ge < As (B) As < Ge < P < Si (A) No molecular orbital may have a net overlap with
any other molecular orbital.
(C) Ge < Si < As < P (D) Ge < As < Si < P
(B) Each molecular orbital must have a different number
45. Which gas-phase atom or ion has the following ground of nodes than every other molecular orbital.
state?
(C) The number of molecular orbitals is equal to half the
[Ar] number of atomic orbitals of the atoms that make up
3d 4s the molecule.

(A) Mn (B) Co (C) Fe+ (D) Cu2+ (D) The lowest-energy molecular orbitals are the most
antibonding in character and the highest-energy
46. Which change in principal quantum number for an molecular orbitals are the most bonding in character.
electron in a hydrogen atom would correspond to
emission of the longest-wavelength photon? 53. NF3 has a bond angle of 102.5º, while PF3 has a bond
angle of 96.3º. What is the best explanation for the larger
(A) n = 4  n = 1 (B) n = 5  n = 2 bond angle in NF3?

(C) n = 1  n = 5 (D) n = 2  n = 4 (A) The nitrogen 2s orbital participates more in bonding

than does the phosphorus 3s orbital.
47. Which pair of elements has the most similar
(B) Nitrogen is more electronegative than phosphorus.
electronegativities?
(C) NF3 has no unpaired electrons while PF3 has two
(A) B and C (B) B and Al unpaired electrons.
(C) B and Si (D) Al and C (D) NF3 is an ionic compound while PF3 forms covalent
bonds.
48. The permanganate ion, MnO4–, is purple while the
pertechnetate ion, TcO4–, is colorless. This difference is 54. Allene has the structure H2C=C=CH2. What is the best
most closely related to which difference between description of the geometry of allene?
manganese and technetium?
Geometry at central carbon Positions of hydrogen atoms
(A) Manganese(VII) is a stronger oxidant than (A) Linear All in the same plane
technetium(VII).
(B) Linear In two perpendicular planes
(B) Manganese consists of a stable isotope while all
(C) Bent All in the same plane
isotopes of technetium are radioactive.
(D) Bent In two perpendicular planes
(C) The Mn–O bond in permanganate is shorter than the
Tc–O bond in pertechnetate.
55. Which of the following molecules is chiral?
(D) Elemental manganese is less dense than elemental
technetium. (A) (B)

49. Which ion has the longest N–O bond?

(A) NO3– (B) NO2– (C) NO2+ (D) NO+

50. Which pair of species has the same shape? (C) (D)
(A) CO2 and SO2 (B) CCl4 and TiCl4
(C) C2H6 and B2H6 (D) NO3– and PO33–

Page 8 Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017
 56. A chemist wishes to separate benzoic acid from 4- 59. The isoelectric point of a protein is the pH at which it is
hydroxybenzaldehyde. Which is the best method to electrically neutral. Which mutation of an amino acid
achieve this separation? NH2CHRCOOH in the protein would have the greatest
effect on its isoelectric point, assuming that the mutation
does not significantly affect the protein’s overall structure?

(A) Serine (R = CH2OH)  Lysine

(R = CH2CH2CH2CH2NH2)
(B) Glutamine (R = CH2CH2CONH2)  Methionine
(A) Partitioning the mixture between diethyl ether and (R = CH2CH2SCH3)
water (C) Isoleucine (R = CH[CH3]CH2CH3)  Valine
(B) Partitioning the mixture between diethyl ether and 1 (R = CH[CH3]2)
M aqueous NaHCO3
(D) Alanine (R = CH3)  Glycine (R = H)
(C) Partitioning the mixture between diethyl ether and 1
M aqueous NaOH 60. Hydrolysis of which disaccharide with dilute acid gives
only a single type of monosaccharide as a product?
(D) Partitioning the mixture between diethyl ether and 1
M aqueous HCl
(A) Lactose,
57. (E)-2-butene and (Z)-2-butene (shown below) each react
with bromine to form compounds with the formula
C4H8Br2. What is the relationship between the products?

(B) Melibiose,

(A) Structural isomers (B) Enantiomers

(C) Diastereomers (D) Identical

58. What is the role of the acid catalyst in the Fischer

esterification reaction below?
H+
CH3CH2OH + CH3CH2CO2H CH3CH2CO2CH2CH3 + H2O
(C) Rutinose,

(A) Shifts the equilibrium in the right-hand direction

(B) Neutralizes the base formed as a side product in the
reaction
(C) Converts ethanol to a more reactive nucleophile
(D) Converts propanoic acid to a more reactive
electrophile

(D) Sophorose,

END OF TEST

Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017 Page 9
 PLEASE ANSWER THE FOLLOWING
FOUR QUESTIONS

THANK YOU!
When you have finished answering this examination or time has
been called by the Examiner, please provide responses to the
following 4 items. Your answers will not affect your score on
the exam but will help with a study being conducted by the U.S.
National Chemistry Olympiad (USNCO) Subcommittee.

61. The amount of time I spend doing experiments in the

laboratory per week on average during my chemistry course
was/is?
(A) less than ½ hour
(B) between ½ and 1 hour
(C) between 1 and 2 hours
(D) more than 2 hours

The following questions should be answered using the scale

(A) Strongly agree
(B) Agree
(C) Disagree
(D) Strongly disagree

62. As a result of my participation in the USNCO program,

I plan to study more chemistry.

63. As a result of my participation in the USNCO program,

I plan to major in chemistry in college.

64. As a result of my participation in the USNCO program,

I have a more positive view of chemistry than I did before
participating.

Page 10 Property of ACS USNCO – Not for use as USNCO National Exam after April 24, 2017
 Olympiad 2017
USNCO National Exam Part I
KEY

Number Answer Number Answer

1. B 31. C
2. A 32. D
3. D 33. D
4. D 34. C
5. C 35. B
6. C 36. B
7. A 37. D
8. C 38. B
9. B 39. A
10. A 40. B
11. C 41. A
12. C 42. A
13. B 43. B
14. B 44. C
15. B 45. B
16. B 46. B
17. A 47. C
18. C 48. A
19. D 49. A
20. C 50. B
21. C 51. A
22. D 52. A
23. A 53. A
24. B 54. B
25. C 55. B
26. D 56. B
27. C 57. C
28. C 58. D
29. A 59. A
30. D 60. D