Water pollution

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Raw sewage and industrial waste flows across international borders New River passes from Mexicali toCalexico,

California.

Water pollution is the contamination of water bodies (e.g. lakes, rivers, oceans,groundwater).

Water pollution affects plants and organisms living in these bodies of water; and, in almost all
cases the effect is damaging not only to individual species and populations, but also to the
natural biological communities.

Water pollution occurs when pollutants are discharged directly or indirectly into water bodies
without adequate treatment to remove harmful compounds.

Contents
 [hide]

1 Introduction
2 Water pollution categories
o 2.1 Point source pollution
o 2.2 Non-point source pollution

3 Groundwater pollution
4 Causes of water pollution
o 4.1 Pathogens
o 4.2 Chemical and other contaminants
o 4.3 Thermal pollution

5 Transport and chemical reactions of water

 pollutants
6 Measurement of water pollution
o 6.1 Sampling
o 6.2 Physical testing
o 6.3 Chemical testing
o 6.4 Biological testing

7 Control of water pollution

o 7.1 Domestic sewage
o 7.2 Industrial wastewater
o 7.3 Agricultural wastewater
o 7.4 Construction site stormwater
o 7.5 Urban runoff (stormwater)

8 See also
9 References
10 External links

[edit]Introduction

Millions depend on the polluted Ganges river.

Water pollution is a major problem in the global context. It has been suggested that it is the
leading worldwide cause of deaths and diseases,[1][2] and that it accounts for the deaths of more
than 14,000 people daily.[2] An estimated 700 million Indians have no access to a proper toilet,
and 1,000 Indian children die of diarrheal sickness every day.[3] Some 90% of China's cities
suffer from some degree of water pollution, [4] and nearly 500 million people lack access to safe
drinking water.[5] In addition to the acute problems of water pollution in developing
countries, industrialized countries continue to struggle with pollution problems as well. In the
most recent national report onwater quality in the United States, 45 percent of
assessed stream miles, 47 percent of assessed lake acres, and 32 percent of
assessed bay and estuarine square miles were classified as polluted.[6]

Water is typically referred to as polluted when it is impaired by anthropogenic contaminants and

either does not support a human use, like serving as drinking water, and/or undergoes a marked
shift in its ability to support its constituent biotic communities, such as fish. Natural phenomena
such as volcanoes, algae blooms, storms, and earthquakes also cause major changes in water
quality and the ecological status of water.

[edit]Water pollution categories

Surface water and groundwater have often been studied and managed as separate resources,
although they are interrelated.[7] Sources of surface water pollution are generally grouped into
two categories based on their origin.

[edit]Point source pollution

Point source pollution - Shipyard - Rio de Janeiro.

Point source pollution refers to contaminants that enter a waterway through a discrete

conveyance, such as a pipe or ditch. Examples of sources in this category include discharges
from a sewage treatment plant, a factory, or a city storm drain. The U.S. Clean Water
Act (CWA) defines point source for regulatory enforcement purposes.[8] The CWA definition of
point source was amended in 1987 to include municipal storm sewer systems, as well as
industrial stormwater, such as from construction sites.[9]

[edit]Non-point source pollution

Non-point source (NPS) pollution refers to diffuse contamination that does not originate from a
single discrete source. NPS pollution is often the cumulative effect of small amounts of
contaminants gathered from a large area. The leaching out of nitrogen compounds from
agricultural land which has been fertilized is a typical example.
Nutrient runoff in stormwater from "sheet flow" over an agricultural field or a forest are also cited
as examples of NPS pollution.

Contaminated storm water washed off of parking lots, roads and highways, called urban runoff,

is sometimes included under the category of NPS pollution. However, this runoff is typically
channeled into storm drain systems and discharged through pipes to local surface waters, and
is a point source. However where such water is not channeled and drains directly to ground it is
a non-point source.

[edit]Groundwater pollution
See also: Hydrogeology

Interactions between groundwater and surface water are complex. Consequently, groundwater

pollution, sometimes referred to asgroundwater contamination, is not as easily classified as
surface water pollution.[7] By its very nature, groundwater aquifers are susceptible to
contamination from sources that may not directly affect surface water bodies, and the distinction
of point vs. non-point source may be irrelevant. A spill or ongoing releases of chemical
or radionuclide contaminants into soil (located away from a surface water body) may not create
point source or non-point source pollution, but can contaminate the aquifer below, defined as a
toxin plume. The movement of the plume, a plume front, can be part of a Hydrological transport
model or Groundwater model. Analysis of groundwater contamination may focus on
the soil characteristics and site geology, hydrogeology, hydrology, and the nature of the
contaminants.

[edit]Causes of water pollution

The specific contaminants leading to pollution in water include a wide spectrum
of chemicals, pathogens, and physical or sensory changes such as elevated temperature and
discoloration. While many of the chemicals and substances that are regulated may be naturally
occurring (calcium, sodium, iron, manganese, etc.) the concentration is often the key in
determining what is a natural component of water, and what is a contaminant.

Oxygen-depleting substances may be natural materials, such as plant matter (e.g. leaves and
grass) as well as man-made chemicals. Other natural and anthropogenic substances may
cause turbidity (cloudiness) which blocks light and disrupts plant growth, and clogs the gills of
some fish species.[10]

Many of the chemical substances are toxic. Pathogens can produce waterborne diseases in

either human or animal hosts.[11] Alteration of water's physical chemistry includes acidity
(change in pH), electrical conductivity, temperature, and eutrophication. Eutrophication is an
increase in the concentration of chemical nutrients in an ecosystem to an extent that increases
in the primary productivity of the ecosystem. Depending on the degree of eutrophication,
subsequent negative environmental effects such as anoxia (oxygen depletion) and severe
reductions in water quality may occur, affecting fish and other animal populations.

[edit]Pathogens

A manhole cover unable to contain a sanitary sewer overflow.

Coliform bacteria are a commonly used bacterial indicator of water pollution, although not an

actual cause of disease. Other microorganisms sometimes found in surface waters which have
caused human health problems include:

 Burkholderia pseudomallei
 Cryptosporidium parvum
 Giardia lamblia
 Salmonella
 Novovirus and other viruses
 Parasitic worms (helminths).[12][13]

High levels of pathogens may result from inadequately treated sewage discharges.[14] This can

be caused by a sewage plant designed with less than secondary treatment (more typical in less-
developed countries). In developed countries, older cities with aging infrastructure may have
leaky sewage collection systems (pipes, pumps, valves), which can cause sanitary sewer
overflows. Some cities also have combined sewers, which may discharge untreated sewage
during rain storms.[15]

Pathogen discharges may also be caused by poorly managed livestock operations.

[edit]Chemical and other contaminants

Muddy river polluted by sediment. Photo courtesy of United States Geological Survey.

Contaminants may include organic and inorganic substances.

Organic water pollutants include:

 Detergents
 Disinfection by-products found in chemically disinfected drinking water, such
as chloroform
 Food processing waste, which can include oxygen-demanding substances, fats and
grease
 Insecticides and herbicides, a huge range of organohalides and other chemical
compounds
 Petroleum hydrocarbons, including fuels (gasoline, diesel fuel, jet fuels, and fuel oil) and
lubricants (motor oil), and fuel combustion byproducts, from stormwater runoff[16]
 Tree and bush debris from logging operations
 Volatile organic compounds (VOCs), such as industrial solvents, from improper
storage.Chlorinated solvents, which are dense non-aqueous phase liquids (DNAPLs), may
fall to the bottom of reservoirs, since they don't mix well with water and are denser.
 Various chemical compounds found in personal hygiene and cosmetic products

Inorganic water pollutants include:

 Acidity caused by industrial discharges (especially sulfur dioxide from power plants)

 Ammonia from food processing waste
 Chemical waste as industrial by-products
 Fertilizers containing nutrients--nitrates and phosphates--which are found in stormwater
runoff from agriculture, as well as commercial and residential use[16]
 Heavy metals from motor vehicles (via urban stormwater runoff)[16][17] and acid mine
drainage
 Silt (sediment) in runoff from construction sites, logging, slash and burn practices or land
clearing sites

Macroscopic pollution—large visible items polluting the water—may be termed "floatables" in

an urban stormwater context, or marine debriswhen found on the open seas, and can include
such items as:

 Trash (e.g. paper, plastic, or food waste) discarded by people on the ground, and that
are washed by rainfall into storm drains and eventually discharged into surface waters
 Nurdles, small ubiquitous waterborne plastic pellets
 Shipwrecks, large derelict ships

Potrero Generating Station discharges heated water into San Francisco Bay.[18]

[edit]Thermal pollution
Main article: Thermal pollution

Thermal pollution is the rise or fall in the temperature of a natural body of water caused by
human influence. A common cause of thermal pollution is the use of water as
a coolant by power plantsand industrial manufacturers. Elevated water temperatures decreases
oxygen levels (which can kill fish) and affects ecosystem composition, such as invasion by
new thermophilic species. Urban runoff may also elevate temperature in surface waters.

Thermal pollution can also be caused by the release of very cold water from the base
of reservoirsinto warmer rivers.

[edit]Transport and chemical reactions of water pollutants

See also: Marine pollution

Most water pollutants are eventually carried by rivers into the oceans. In some areas of the
world the influence can be traced hundred miles from the mouth by studies using hydrology
transport models. Advanced computer models such as SWMM or the DSSAM Model have been
used in many locations worldwide to examine the fate of pollutants in aquatic systems.
Indicator filter feeding species such as copepods have also been used to study pollutant fates in
the New York Bight, for example. The highest toxin loads are not directly at the mouth of
the Hudson River, but 100 kilometers south, since several days are required for incorporation
into planktonictissue. The Hudson discharge flows south along the coast due to coriolis force.
Further south then are areas of oxygen depletion, caused by chemicals using up oxygen and
by algae blooms, caused by excess nutrients from algal cell death and decomposition. Fish
and shellfishkills have been reported, because toxins climb the food chain after small fish
consume copepods, then large fish eat smaller fish, etc. Each successive step up the food chain
causes a stepwise concentration of pollutants such as heavy metals (e.g. mercury)
and persistent organic pollutants such as DDT. This is known as biomagnification, which is
occasionally used interchangeably with bioaccumulation.

A polluted river draining an abandonedcopper mine on Anglesey

Large gyres (vortexes) in the oceans trap floating plastic debris. The North Pacific Gyre for

example has collected the so-called "Great Pacific Garbage Patch" that is now estimated at 100
times the size of Texas. Many of these long-lasting pieces wind up in the stomachs of marine
birds and animals. This results in obstruction of digestive pathways which leads to reduced
appetite or even starvation.

Many chemicals undergo reactive decay or chemically change especially over long periods of
time in groundwaterreservoirs. A noteworthy class of such chemicals is the chlorinated
hydrocarbons such as trichloroethylene (used in industrial metal degreasing and electronics
manufacturing) and tetrachloroethylene used in the dry cleaning industry (note latest advances
in liquid carbon dioxide in dry cleaning that avoids all use of chemicals). Both of these
chemicals, which are carcinogens themselves, undergo partial decomposition reactions, leading
to new hazardous chemicals (including dichloroethylene and vinyl chloride).

Groundwater pollution is much more difficult to abate than surface pollution because
groundwater can move great distances through unseen aquifers. Non-porous aquifers such
as clays partially purify water of bacteria by simple filtration (adsorption and absorption), dilution,
and, in some cases, chemical reactions and biological activity: however, in some cases, the
pollutants merely transform to soil contaminants. Groundwater that moves through cracks
and caverns is not filtered and can be transported as easily as surface water. In fact, this can be
aggravated by the human tendency to use natural sinkholes as dumps in areas
of Karst topography.

There are a variety of secondary effects stemming not from the original pollutant, but a
derivative condition. An example is silt-bearing surface runoff, which can inhibit the penetration
of sunlight through the water column, hampering photosynthesis in aquatic plants.

[edit]Measurement of water pollution

Environmental Scientists preparing water autosamplers.

Water pollution may be analyzed through several broad categories of methods: physical,
chemical and biological. Most involve collection of samples, followed by specialized analytical
tests. Some methods may be conducted in situ, without sampling, such as temperature.
Government agencies and research organizations have published standardized, validated
analytical test methods to facilitate the comparability of results from disparate testing events.[19]

[edit]Sampling

Sampling of water for physical or chemical testing can be done by several methods, depending
on the accuracy needed and the characteristics of the contaminant. Many contamination events
are sharply restricted in time, most commonly in association with rain events. For this reason
"grab" samples are often inadequate for fully quantifying contaminant levels. Scientists
gathering this type of data often employ auto-sampler devices that pump increments of water at
either time or discharge intervals.

Sampling for biological testing involves collection of plants and/or animals from the surface
water body. Depending on the type of assessment, the organisms may be identified
for biosurveys (population counts) and returned to the water body, or they may be dissected
forbioassays to determine toxicity.

[edit]Physical testing
Common physical tests of water include temperature, solids concentration like total suspended
solids (TSS) and turbidity.

[edit]Chemical testing
See also: water chemistry analysis and environmental chemistry

Water samples may be examined using the principles of analytical chemistry. Many published
test methods are available for both organic and inorganic compounds. Frequently used methods
include pH, biochemical oxygen demand (BOD), chemical oxygen demand (COD), nutrients
(nitrate and phosphorus compounds), metals
(including copper, zinc, cadmium, lead and mercury), oil and grease, total petroleum
hydrocarbons (TPH), and pesticides.

[edit]Biological testing
Main article: Bioindicator

Biological testing involves the use of plant, animal, and/or microbial indicators to monitor the
health of an aquatic ecosystem.

For microbial testing of drinking water, see Bacteriological water analysis.

[edit]Control of water pollution
[edit]Domestic sewage
Main article: Sewage treatment
 Deer Island Waste Water Treatment Plantserving Boston, Massachusetts and vicinity.

Domestic sewage is 99.9% pure water, the other 0.1% are pollutants. While found in low
concentrations, these pollutants pose risk on a large scale.[20] In urban areas, domestic
sewage is typically treated by centralized sewage treatment plants. In the U.S., most of
these plants are operated by local government agencies, frequently referred to as publicly
owned treatment works(POTW). Municipal treatment plants are designed to
control conventional pollutants: BOD and suspended solids. Well-designed and operated
systems (i.e., secondary treatment or better) can remove 90 percent or more of these
pollutants. Some plants have additional sub-systems to treat nutrients and pathogens.
Most municipal plants are not designed to treat toxic pollutants found in industrial
wastewater.[21]

Cities with sanitary sewer overflows or combined sewer overflows employ one or
more engineeringapproaches to reduce discharges of untreated sewage, including:

 utilizing a green infrastructure approach to improve stormwater management capacity

throughout the system, and reduce the hydraulicoverloading of the treatment plant[22]
 repair and replacement of leaking and malfunctioning equipment[15]
 increasing overall hydraulic capacity of the sewage collection system (often a very
expensive option).

A household or business not served by a municipal treatment plant may have an

individual septic tank, which treats the wastewater on site and discharges into the soil.
Alternatively, domestic wastewater may be sent to a nearby privately owned treatment
system (e.g. in a rural community).

[edit]Industrial wastewater
Main article: Industrial wastewater treatment
 Dissolved air flotation system for treating industrial wastewater.

Some industrial facilities generate ordinary domestic sewage that can be treated by
municipal facilities. Industries that generate wastewater with high concentrations of
conventional pollutants (e.g. oil and grease), toxic pollutants (e.g. heavy metals, volatile
organic compounds) or other nonconventional pollutants such as ammonia, need
specialized treatment systems. Some of these facilities can install a pre-treatment system
to remove the toxic components, and then send the partially treated wastewater to the
municipal system. Industries generating large volumes of wastewater typically operate their
own complete on-site treatment systems.

Some industries have been successful at redesigning their manufacturing processes to

reduce or eliminate pollutants, through a process called pollution prevention.

Heated water generated by power plants or manufacturing plants may be controlled with:

 cooling ponds, man-made bodies of water designed for cooling

by evaporation, convection, and radiation
 cooling towers, which transfer waste heat to
the atmosphere through evaporation and/or heat transfer
 cogeneration, a process where waste heat is recycled for domestic and/or industrial
heating purposes.[23]
[edit]Agricultural wastewater
Main article: Agricultural wastewater treatment
 Riparian buffer lining a creek in Iowa

Nonpoint source controls

Sediment (loose soil) washed off fields is the largest source of agricultural pollution in
the United States.[10]Farmers may utilize erosion controls to reduce runoff flows and retain
soil on their fields. Common techniques include contour plowing, crop mulching, crop
rotation, planting perennial crops and installing riparian buffers.[24][25]:pp. 4-95–4-96

Nutrients (nitrogen and phosphorus) are typically applied to farmland as

commercial fertilizer; animal manure; or spraying of municipal or industrial wastewater
(effluent) or sludge. Nutrients may also enter runoff from crop
residues, irrigation water, wildlife, and atmospheric deposition.[25]:p. 2-9 Farmers can develop
and implementnutrient management plans to reduce excess application of nutrients.[24][25]:pp.
4-37–4-38

To minimize pesticide impacts, farmers may use Integrated Pest Management (IPM)

techniques (which can include biological pest control) to maintain control over pests,
reduce reliance on chemical pesticides, and protect water quality.[26]

Confined Animal Feeding Operation in theUnited States

Point source wastewater treatment
Farms with large livestock and poultry operations, such as factory farms, are
called concentrated animal feeding operations or confined animal feeding operations in the
U.S. and are being subject to increasing government regulation.[27][28] Animal slurries are
usually treated by containment in lagoons before disposal by spray or trickle application to
grassland. Constructed wetlands are sometimes used to facilitate treatment of animal
wastes, as are anaerobic lagoons. Some animal slurries are treated by mixing
with straw and composted at high temperature to produce a bacteriologically sterile and
friable manure for soil improvement.

[edit]Construction site stormwater

Silt fence installed on a construction site.

Sediment from construction sites is managed by installation of:

 erosion controls, such as mulching and hydroseeding, and

 sediment controls, such as sediment basins and silt fences.[29]

Discharge of toxic chemicals such as motor fuels and concrete washout is prevented by
use of:

 spill prevention and control plans, and

 specially designed containers (e.g. for concrete washout) and structures such as
overflow controls and diversion berms.[30]
[edit]Urban runoff (stormwater)
Main article: Urban runoff
 Retention basin for controlling urban runoff

Effective control of urban runoff involves reducing the velocity and flow of stormwater, as
well as reducing pollutant discharges. Local governments use a variety of stormwater
management techniques to reduce the effects of urban runoff. These techniques,
called best management practices (BMPs) in the U.S., may focus on water quantity control,
while others focus on improving water quality, and some perform both functions.[31]

Pollution prevention practices include low impact development techniques, installation

of green roofs and improved chemical handling (e.g. management of motor fuels & oil,
fertilizers and pesticides).[32] Runoff mitigation systems include infiltration
basins, bioretention systems, constructed wetlands, retention basins and similar devices.[33]
[34]

Thermal pollution from runoff can be controlled by stormwater management facilities that
absorb the runoff or direct it into groundwater, such as bioretention systems and infiltration
basins. Retention basins tend to be less effective at reducing temperature, as the water
may be heated by the sun before being discharged to a receiving stream.[31]:p. 5-58