9701 s10 Ms 21

UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
MARK SCHEME for the May/June 2010 question paper

for the guidance of teachers
9701 CHEMISTRY
9701/21 Paper 2 (AS Structured Questions), maximum raw mark 60
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners’ meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
• CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2010 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
www.XtremePapers.net
Page 2 Mark Scheme: Teachers’ version Syllabus Paper
GCE AS/A LEVEL – May/June 2010 9701 21
1 (a) fewer electrons in Cl 2 than in Br2 (1)

smaller van der Waals’ forces in Cl 2 or stronger van der Waals’ forces in Br2 (1) [2]
(b) CO has a permanent dipole or N2 does not (1)

permanent dipole-permanent dipole interactions are stronger than those from induced
dipoles (1) [2]
(c) (i) a co-ordinate bond (1)
(ii) a covalent bond (1)
or
(iii) a lone pair (1)
or
penalise any groups of 3 or 4 electrons that are circled [3]
(d) CO and HCN both have a dipole or N2 does not have a dipole (1) [1]
© UCLES 2010
(e) (i)
H H
 
HCCOH
 
H C≡N
C≡N must be shown (1)
(ii) nucleophilic addition (1)
(iii)
H H
δ+ δ– | 
CH3C=O CH3CO– HCN
CH3COH + CN–
 | 
H CN– CN CN
C=O dipole correctly shown or correct curly arrow on C=O (1)

attack on Cδ+ by C of CN– (1)
correct intermediate (1)
CN– regenerated (1) [5 max]
[Total: 13]
© UCLES 2010
2 (a) (i) new graph has lower maximum (1)

maximum is to the right of previous maximum (1)
(ii) H is at Ea (1) [3]
(b) the minimum amount of energy molecules must have or energy required (1)
in order for the reaction to take place (1) [2]
(c) (i) iron or iron oxide (1)

100 to 500 atm and 400–550°C
units necessary – allow other correct values and units (1)
(ii) C is placed to the left of H (1)
(iii) more molecules now have energy >Ea (1) [4]
(d) reaction 1
has greater Ea (1)
because energy is needed to break covalent bonds (1)
reaction 2
has lower Ea
or actual reaction is H+ + OH– → H2O
or reaction involves ions (1)
opposite charges attract (1) [4]
[Total: max 12]
© UCLES 2010
3 (a) Accept only symbols.
(i) S or S8 (1)
(ii) K or K+ (1)
(iii) Na – allow K or Li (1)
(iv) Cl or Br or F (1)
(v) Mg or Ca or Li
allow Ni, Cu, or Zn (1) [5]
(b) Accept only formulae.
(i) F2O (1)
(ii) SO2 and SO3

or P2O3/P4O6 and P2O5/P4O10
or any two from N2O3, NO2/N2O4, N2O5
or any two from Cl 2O, ClO2, ClO3, Cl 2O7 (1+1) [3]
(c) (i) NaF, MgF2, AlF3 – any two (1)
(ii) octahedral (1)
(iii) I atom is larger than Cl atom (1)
(iv) cannot pack 7 F atoms around Cl atom

or can pack 7 F atoms around I atom (1) [4]
[Total: 12]
© UCLES 2010
4 (a)
CH3CHBrCH2Br CH3CH(OH)CH2OH
Br2 CH3CH=CH2 KMnO4/H+
A B
cold, dilute
HBr
CH3CH2CH2CN CH3CH2CH2Br CH3CH2CH2NH2

KCN in NH3
or or or
aqueous in an
CH3CH(CN)CH3 ethanol CH3CHBrCH3 excess CH3CH(NH2)CH3
D C F
H2SO4(aq) NaOH(in ethanol)

heat under heat under
reflux reflux
CH3CH2CH2CO2H CH3CH=CH2
or
CH3CH(CO2H)CH3 G
give 1 for each correct structure (7 × 1) [7]
(b) (i) ester (1)
(ii) heat under reflux (1)

trace of conc. H2SO4 or presence of HCl (g) (1) [3]
[Total: 10]
© UCLES 2010
5 (a) (i) same molecular formula

but different structural formula/structure (1)
(ii) asymmetric C atom/chiral centre present (1)

>C=C< bond present (1) [3]
(b) NaO2CCH(OH)CH(OH)CO2Na (1) [1]
(c) no because there is no chiral carbon atom present (1) [1]
35.8 4.5 59.7

(d) (i) C : H : O = : : this mark is for correct use of Ar values (1)
12 1 16
C : H : O = 2.98 : 4.5 : 3.73
C : H : O = 1 : 1.5 : 1.25 this mark is for evidence of correct calculation (1)
gives empirical formula of W is C4H6O5
(ii) C4H6O5 = 12 × 4 + 1 × 6 + 16 × 5 = 134

molecular formula of W is C4H6O5 (1) [3]
© UCLES 2010
29.4 × 100
(e) (i) n(OH–) = = 0.0294 (1)
1000
1.97
n(W) = = 0.0147 (1)
134
no. of –CO2H groups present
0.0294
in one molecule of W = = 2 (1)
0.0147
29.4 × 1.00
or n(OH–) = = 0.0294 (1)
1000
1.97 g W ≡ 0.0294 mol NaOH
0.0294 × 134
134 g W ≡ = 1.999 ≈ 2 mol NaOH (1)
1.97
no. of –CO2H groups present in 1 molecule of W = 2 (1) [3]
(ii)
H H
H—O   O—H
C—C—C—C
O   O
H O—H or
CH3
H—O  O—H
C —C—C
O  O
O—H or
OH

H—C—H
H—O  O—H
C—C—C
O  O
H
one correct structure (1)

correctly displayed (1)
allow any correct ether [2]
[Total: 13]
© UCLES 2010

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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

GCE Advanced Subsidiary Level and GCE Advanced Level

MARK SCHEME for the May/June 2010 question paper

1 (a) fewer electrons in Cl 2 than in Br2 (1)

(b) CO has a permanent dipole or N2 does not (1)

(c) (i) a co-ordinate bond (1)

(ii) a covalent bond (1)

(iii) a lone pair (1)

penalise any groups of 3 or 4 electrons that are circled [3]

C≡N must be shown (1)

(ii) nucleophilic addition (1)

C=O dipole correctly shown or correct curly arrow on C=O (1)

2 (a) (i) new graph has lower maximum (1)

(ii) H is at Ea (1) [3]

(c) (i) iron or iron oxide (1)

(ii) C is placed to the left of H (1)

(iii) more molecules now have energy >Ea (1) [4]

[Total: max 12]

3 (a) Accept only symbols.

(iii) Na – allow K or Li (1)

(b) Accept only formulae.

(i) F2O (1)

(ii) SO2 and SO3

(c) (i) NaF, MgF2, AlF3 – any two (1)

(ii) octahedral (1)

(iii) I atom is larger than Cl atom (1)

(iv) cannot pack 7 F atoms around Cl atom

CH3CH2CH2CN CH3CH2CH2Br CH3CH2CH2NH2

H2SO4(aq) NaOH(in ethanol)

give 1 for each correct structure (7 × 1) [7]

(b) (i) ester (1)

(ii) heat under reflux (1)

5 (a) (i) same molecular formula

(ii) asymmetric C atom/chiral centre present (1)

(b) NaO2CCH(OH)CH(OH)CO2Na (1) [1]

(c) no because there is no chiral carbon atom present (1) [1]

35.8 4.5 59.7

(ii) C4H6O5 = 12 × 4 + 1 × 6 + 16 × 5 = 134

one correct structure (1)

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