Reverse Osmosis: Sudhakar M Rao

GENERAL ¨ ARTICLE
Reverse Osmosis
Sudhakar M Rao
Osmosis is a phenomenon which regulates many biological

functions in plants and animals. That the plants stand upright,
or the water reaches the tip of every leaf of a plant is due to
osmotic pressure. The fact that we cannot survive by drinking
seawater is also linked to this same phenomenon. J H van ’t
Hoff showed in 1886 that osmotic pressure is related to
concentration and temperature of the solution by a law that is Sudhakar M Rao is a
Professor in the Depart-
similar to the gas law. An understanding of this phenomenon
ment of Civil Engineering
paved the way not only in explaining the biological functions and is an Associate Faculty
which depend on osmosis, but also in creating conditions for at Center for Sustainable
reversing it known as ‘reverse osmosis’. Reverse osmosis has Technologies, Indian
Institute of Science,
many applications, one of which is desalination of seawater.
Bangalore. His research
The inaugural Nobel Prize in Chemistry was awarded in 1901 areas include, unsaturated
to van ’t Hoff for his seminal work in this area. The present soil behaviour, hazardous
article explains the principle of osmosis and reverse osmosis. waste management, water
quality and remediation of
contaminated water.
Osmosis and Reverse Osmosis
As the name suggests, reverse osmosis is the opposite phenom-

enon of osmosis. Osmosis describes the spontaneous flow of
water from a dilute to a more concentrated solution, when sepa-
rated from each other by a suitable membrane. These membranes
allow the free passage of water but not of dissolved substances
and van’t Hoff suggested the adjective ‘semi-permeable’ to de-
scribe this property. During osmosis, when water moves away
from low concentration areas, it causes these areas to become
more concentrated. On the other side, when water moves into
areas of high concentration, solute concentration in these areas
decreases. The tendency for water to flow through the membrane
Keywords
can be expressed as ‘osmotic pressure (symbol, S)’, since it is
Osmosis, reverse osmosis,
similar to water flow caused by a pressure differential. desalinatiion, seawater, water
purification.
RESONANCE ¨ May 2007 37

GENERAL ¨ ARTICLE
Calculation of Osmotic Pressure

Solution Osmotic
Concentration pressure*
Osmotic pressure of a solution is related to its dissolved solute
(NaCl) (kPa)
concentration and is calculated from van ’t Hoff equation:
0.05 M 248 S = iMR, (1)

0.1 M 496
0.4 M 1983 where S is the osmotic pressure (kPa) of the solution, R is
1.0 M 4959 universal gas constant, T is absolute temperature (K), M is
4.0 M 19835 molarity of the dissolved salts in the solution and i is the van’t
*from equation (1) at 25OC Hoff factor. The van ’t Hoff factor is introduced to cover
deviations from ideal solution behaviour that include finite
Table 1. Osmotic pressures
volume occupied by solute molecules and their mutual attraction
of sodium chloride solu-
as in van der Waals attraction. Equation (1) is sometimes known
tions.
as Morse’s equation as it was proposed empirically by H N Morse
as a modification of van ’t Hoff equation. It allows calculation of
osmotic pressures of salt solutions. The van ’t Hoff factor (i) for
sodium chloride salt is two. Inserting the other values in (1) gives
us the osmotic pressures of sodium chloride solutions of varying
concentrations as illustrated in Table 1.
Development of Osmotic Pressure Differentials
Figure 1 illustrates the development of osmotic pressure differ-

ential across a semi- permeable membrane.Here dilute salt solu-
tion with an osmotic pressure of S1 is in contact with concentrated
salt solution of osmotic pressure S2 through a semi-permeable
ho
Figure 1. Development of
an osmotic pressure gradi-
ent across a semi-perme-
able membrane; h0 is the Semi-permeable
membrane
pressure differential gen-
erated between two cham-
Con. Salt Dil. Salt
bers because of chemical
solution solution
concentration gradients.
38 RESONANCE ¨ May 2007

GENERAL ¨ ARTICLE
membrane, which allows water molecules but not the dissolved The osmotic pressure
salt molecules to flow through. difference between
the two chambers is
This induces an osmotic pressure difference ('S = S2 – S1) dissipated by the flow
between the two chambers. The osmotic pressure difference of water (termed
between the two chambers is dissipated by the flow of water osmotic flow) from the
(termed osmotic flow) from the dilute side to the concentrated dilute side to the
solution chamber till the dissolved salt concentration in both concentrated solution
chambers becomes equal. The ability of the semi-permeable chamber till the
membrane to allow only passage of water and not dissolved salt dissolved salt
molecules is defined by the term osmotic efficiency, Z and is concentration in both
given by a number between zero and one. If Z = 0, then the chambers becomes
membrane does not interfere with the movement of dissolved salt equal.
molecules at all. In this case there is no osmotic flow. If Z = 1 then
the semi-permeable membrane is perfect and dissolved salts
cannot flow through the membrane, that is, the membrane totally
prevents the flow of solute down its chemical potential gradient.
Referring to Figure 1, assume that the concentrated salt solution

chamber contains seawater having a salinity of 35,000 mg/l and
the dilute salt solution chamber contains distilled water. To
simplify calculations, it is assumed that the seawater is essentially
composed of sodium chloride salt. The dissolved sodium chloride
concentration of 35,000 mg/l represents a molar concentration of
0.6 M and such a salt solution is characterized by osmotic
pressure of approximately 2975 kPa according to equation (1).
Since distilled water has osmotic pressure of zero (as dissolved
salt concentration = 0), it means that an osmotic pressure differ-
ential of 2975 kPa is generated when 35,000 mg/l salt water is
separated from distilled water by a perfect (Z =1) semi-permeable
membrane.
How Reverse Osmosis Works
Instead of water flowing from distilled water chamber to concen-

trated salt solution chamber, if water is forced from a region of
hiher salt concentration (concentrated salt solution chamber)
through a semi-permeable membrane to a region of low solute
RESONANCE ¨ May 2007 39

GENERAL ¨ ARTICLE
concentration (dilute solution chamber) by applying a pressure in

excess of the osmotic pressure differential, the process is reverse
of the nor-mal osmosis process and is therefore termed as reverse
osmosis.
The membranes used for reverse osmosis have a dense barrier

layer in the polymer matrix where most separation occurs. In most
cases the membrane is designed to allow only water to pass
through this dense layer while preventing the passage of solutes
(such as salt ions). This process requires that a high pressure be
applied on the high concentration side of the membrane, usually
2–17 bar for fresh and brackish water, and 40–70 bar for seawa-
ter, which has around 30 bar natural osmotic pressure which must
be overcome.
Some Applications of Reverse Osmosis
As may be evident by now, the reverse osmosis process is best

known for its use in desalination (removing the salt from sea
water to get fresh water), but also to get purified naturally
occurring water for medical, industrial process and other rinsing
applications. In the production of bottled mineral water, the water
passes through a reverse osmosis water processor to remove
pollutants and microorganisms. Rain water collected from sewer
drains is purified with reverse osmosis water processors and used
as tap water in Los Angeles and other cities, in case of water
shortages. In industry, reverse osmosis is used to remove minerals
from boiler water. It also finds application in cleaning effluent
and brackish groundwater.
Suggested Reading
Address for Correspondence
Sudhakar M Rao
[1] S Glasstone, Textbook of Physical Chemistry, Macmillan India, New Delhi,
Department of Civil
1974.
Engineering
[2] http://en.wikipedia.org/wiki/Seawater
Indian Institute of Science
[3] http://en.wikipedia.org/wiki/Osmotic_pressure
Bangalore 560012, India.
Email:
msrao@civil.iisc.ernet.in
40 RESONANCE ¨ May 2007

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GENERAL ¨ ARTICLE

Osmosis is a phenomenon which regulates many biological

As the name suggests, reverse osmosis is the opposite phenom-

RESONANCE ¨ May 2007 37

Calculation of Osmotic Pressure

0.05 M 248 S = iMR, (1)

Development of Osmotic Pressure Differentials

Figure 1 illustrates the development of osmotic pressure differ-

38 RESONANCE ¨ May 2007

Referring to Figure 1, assume that the concentrated salt solution

How Reverse Osmosis Works

Instead of water flowing from distilled water chamber to concen-

RESONANCE ¨ May 2007 39

concentration (dilute solution chamber) by applying a pressure in

The membranes used for reverse osmosis have a dense barrier

Some Applications of Reverse Osmosis

As may be evident by now, the reverse osmosis process is best

40 RESONANCE ¨ May 2007

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