UTS Kfa

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Golongan Fenol (nipagin, nipasol, as galat, 1 naftol, 2 Golongan Sulfonamida ( sulfamerazin, sulfadiazine,

naftol) sulfadimidin,sulfasetamid)

a. Reaksi umum a. Reaksi gugus amin

Zat + diazo A + diazo B + NaOH -> panaskan -> Zat + HCL encer-> batang korek api-> orange, kuning
merah frambors -> + amil alkohol/alkohol ->
b. Reaksi amin aromatic primer(erlich)
merah frambors tertarik oleh amil/eter
Zat + p DAB HCl ->kuning, jingga merah
b. Reaksi spesifik fenol
1. Reaksi FeCl3 c. Reaksi cuprifil
Zat + fecl3-> merah,ungu +alkohol-> hilang Zat + 1 ml air panas + 3 tts HCl + 5 tts cuso4 2% + 10tts
Naoh -> biru muda, hijau, violet, coklat +eter-> hilang
2. Reaksi maequis

Zat + h2so4 + formaldehid encer -> cincin


warna (merah,coklat,jingga ungu, hijau) sulfosetamid,
As galat dimidin,
3. Reaksi muhleman diazin,
Nipagin
Zat + chcl3 -> 3tts aquadest + KOH/NaOH merazin
padat-> timbul warna Nipasol
(dari kiri)
(dari kiri)
Golongan karbohidrat
(amilum,laktosa,maltose,sukrosa,fruktosa,glukosa,gal
aktosa)

a. Reaksi umum Uji fenol (fecl3) Uji sulfo(erlich)

Zat + molisch + h2so4 -> cincin ungu

b. Reaksi penggolongan
1. Reaksi benedict

Zat + benedict,panaskan -> merah bata

2. Reaksi seliwanoff

Zat dlm air + HCL + resorsinol, panaskan ->merah Uji karbo (reaksi umum)

3. Reaksi barfoed Amilum,galak,sukr,lak,fruk,glu, mal

Zat dlm air + barfoed, panaskan ->merah bata

Golongan asam (asam salisilat, asam borat, asam


sitrat)

a. Reaksi esterifikasi
1. Reaksi metanol

Zat + metanol + h2so4 p, panaskan -> bau ester


Uji karbo (benedict)
2. Reaksi etanol
Galak, maltosa,amilum,fruktose,sukr,lakt, glu
Zat + etanol + h2so4 p, panaskan -> bau ester

3. Reaksi amil alkohol Uji asam (fecl3)

Zat + amil h2so4 p, panaskan -> bau ester Asam sitrat (lar kuning)

b. Reaksi fecl3 Asam salisilat (coklat kemerahan)

Zat + fecl3 -> merah, kuning, coklat, ungu Asam borat(ungu pekat)

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