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identification functional gp

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7 views

identification functional gp

Uploaded by

tamilselvi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Experiment Observations Inference

1.Given organic compound + litmus No change Alcohol or carbonyl


solution (Red and Blue) group may be present
2.Test for alcohol- Alcoholic group
a)Compound + ceric ammonium Red colour confirmed
nitrate solution
b)Compound + acetic acid + conc. Pleasant fruity Alcoholic group
H2SO4 and warm smell confirmed
Result:- The given organic compound contains:- alcoholic (-OH) group.

Experiment Observations Inference


1.Given organic compound + blue Changes to red Phenolic or carboxylic
litmus solution group may be present
2.Test for phenol-Compound + Violet colour Phenolic group
neutral FeCl3 solution confirmed
Result:- The given organic compound contains:- phenolic (-OH) group

Experiment Observations Inference


1.Given organic compound Changes to red Phenolic or carboxylic
+ blue litmus solution group may be present
2.Test for phenol- No specific colour Phenolic (-OH) group
Compound + neutral absent
FeCl3 solution
3.Test for carboxylic group- Effervescence with -COOH group confirmed
a)Compound + NaHCO3 evolution of colour less and
solution odourless gas which turns
b)Compound + ethanol + lime water milky
conc. H2SO4 and warm -COOH group confirmed
Pleasant fruity smell
Result:- The given organic compound contains:- carboxylic (-COOOH) group.

Experiment Observations Inference


1.Given organic compound + litmus No change Alcohol or carbonyl
solution (Red and Blue) group may be present
2.Test for alcohol-Compound + Red colour Alcoholic group absent
ceric ammonium nitrate solution
3.Test for carbonyl group- Orange yellow
>C=O group may be
Compound + 2,4-DNP solution colour/ ppt
present
4.Test for aldehyde group-
(a)compound + Fehling solution Red ppt -CHO group confirmed
& heat
Silver mirror on
(b) compound + Tollen’s reagent
inside wall of the -CHO group confirmed
And heat
test tube
Result:- The given organic compound contains:- aldehyde (-CHO) group.

Experiment Observations Inference


1.Given organic compound + litmus No change Alcohol or carbonyl
solution (Red and Blue) group may be present
2.Test for alcohol-Compound + Red colour Alcoholic group absent
ceric ammonium nitrate solution
3.Test for carbonyl group-
Orange yellow >C=O group may be
Compound + 2,4-DNP solution
colour/ ppt present
4.Test for aldehyde group-
(a)compound + Fehling solution No Red ppt -CHO group absent
& heat
(b) compound + Tollen’s reagent No Silver mirror -CHO group absent
And heat
5.Test for ketonic group-Compound
+ sodium nitropruside solution & Red colour Ketonic group confirmed
NaOH solution dropwise
Result:- The given organic compound contains:- Ketonic (>C=O)
group.

Experiment Observations Inference


1.Given organic compound + red Change to blue -NH2 group may be
litmus solution present
2.Test for -NH2 group -
a)Compound + CHCl3 + alcoholic Unpleasant smell -NH2 group confirmed
KOH and heat
b)Compound + NaNO2 + conc. Red colour
HCl and add β- naphthol -NH2 group confirmed
Result:- The given organic compound contains:- amino (-NH2) group.

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