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    P Electrons Using Briet's Scheme.: Dual Degree B. Sc. (Hons.) Physics-M.Sc. Physics EXAMINATION, May 2019

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    Vishal Tanwar
    The document discusses topics in atomic and molecular theory: 1) It asks to discuss the spectrum of the helium atom with an energy level diagram and construct exchange symmetric wave functions for the ground and excited states of the helium atom. 2) It asks to obtain an expression for the rotational energy levels of a diatomic molecule treated as a non-rigid rotator and discuss its spectrum and selection rules. 3) It provides the force constant of the CO molecule and asks to calculate the energy of the lowest vibrational level.

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    P Electrons Using Briet's Scheme.: Dual Degree B. Sc. (Hons.) Physics-M.Sc. Physics EXAMINATION, May 2019

    Uploaded by

    Vishal Tanwar
    42 views3 pages
    The document discusses topics in atomic and molecular theory: 1) It asks to discuss the spectrum of the helium atom with an energy level diagram and construct exchange symmetric wave functions for the ground and excited states of the helium atom. 2) It asks to obtain an expression for the rotational energy levels of a diatomic molecule treated as a non-rigid rotator and discuss its spectrum and selection rules. 3) It provides the force constant of the CO molecule and asks to calculate the energy of the lowest vibrational level.

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    DPH202

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    The document discusses topics in atomic and molecular theory: 1) It asks to discuss the spectrum of the helium atom with an energy level diagram and construct exchange symmetric wave functions for the ground and excited states of the helium atom. 2) It asks to obtain an expression for the rotational energy levels of a diatomic molecule treated as a non-rigid rotator and discuss its spectrum and selection rules. 3) It provides the force constant of the CO molecule and asks to calculate the energy of the lowest vibrational level.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    42 views3 pages

    P Electrons Using Briet's Scheme.: Dual Degree B. Sc. (Hons.) Physics-M.Sc. Physics EXAMINATION, May 2019

    Uploaded by

    Vishal Tanwar
    The document discusses topics in atomic and molecular theory: 1) It asks to discuss the spectrum of the helium atom with an energy level diagram and construct exchange symmetric wave functions for the ground and excited states of the helium atom. 2) It asks to obtain an expression for the rotational energy levels of a diatomic molecule treated as a non-rigid rotator and discuss its spectrum and selection rules. 3) It provides the force constant of the CO molecule and asks to calculate the energy of the lowest vibrational level.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    (b) Find the spectral term for two equivalent No. of Printed Pages : 6 Roll No. .......................

    p electrons using Briet’s scheme. 5


    D511
    5. (a) Discuss the spectrum of helium atom with
    Dual Degree B. Sc. (Hons.) Physics-
    appropriate energy level diagram. 10
    M.Sc. Physics EXAMINATION,
    (b) Construct the exachange symmetric wave
    May 2019
    functions (including spin) of the helium (Fourth Semester)
    atom in the ground state and in the 1s 2s (Main Only)
    excited state. 5 PHYSICS
    DPH202
    Unit III Atomic and Molecular Theory
    6. (a) Obtain an expression for the rotational
    Time : 3 Hours] [Maximum Marks : 75
    energy level of a diatomic molecule taking
    it as non-rigid rotator. Discuss its Before answering the question-paper candidates should
    spectrum and the relevant selection rule. ensure that they have been supplied to correct and

    10 complete question-paper. No complaint, in this regard,


    will be entertained after the examination.
    (b) The force constant of the bond in CO
    Note : Attempt Five questions in all, selecting at
    molecule is 1870 N/m. Find the energy
    least one question from each Unit. All
    of the lowest vibrational level. 5 questions carry equal marks.

    M-D511 4 (4-22/17) M-D511 P.T.O.


    1. (a) Explain space quantization. 3 (b) In a Stern-Gerlach experiment, a beam of
    (b) State and explain Lande interval rule for hydrogen atom moves a distance of
    Russell-Saunders’s Coupling. 3 20 cm in a homogeneous magnetic field

    (c) Discuss the condition under which the of gradient 2 × 102 T/m. If the velocity

    pure rotational spectrum of a diatomic of hydrogen atom is 2 × 105 m/s, calculate


    molecule is observable, which of the the maximum separation between the two
    following molecules H2, N2, HCl and OH traces on the collector plates. 5
    will give pure rotational spectrum and
    3. (a) What are normal and anomalous Zeernan
    which will give rotational Raman spectrum.
    effect ? Use classical ideas to explain the
    3
    normal Zeeman effect. 10
    (d) Explain the effect of isotope substitution
    (b) Evaluate the Lande g-factor for the 3P1
    on vibrational spectra of diatomic
    level in 2p3s configuration of the carbon
    molecule. 3
    atom and use the results to predict the
    (e) Explain why anistokes Raman lines are
    splitting of the level when atom is in
    less intense than stokes Raman lines. 3
    external magnetic field of 0.1 tesla. 5
    Unit I
    Unit II
    2. (a) Describe the principle, theory and 4. (a) What is L-S coupling ? Deduce the various
    significance of Stern-Gerlach experiment. interaction energy terms for L-S coupling.
    10 10
    M-D511 2 (4-22/18) M-D511 3 P.T.O.
    9. (a) Explain the construction and working of 7. (a) Discuss the spectrum of diatomic
    Raman spectrometer. 10 molecule treated as vibrating rotator.

    (b) The values of  e and  exe are 1580.36 Explain why fine structure of IR bands of
    and 12.07 cm–1 respectively for the ground diatomic molecule always degraded toward
    state of O2 molecule. Calculate the zero red. 10
    point energy and the expected vibrational (b) A Hg200Cl35 molecule emits a 4.4 cm
    displacement. 5 photon when it undergoes a transition from
    J = 1 to J = 0. Find the internuclear
    distance of this molecule. 5

    Unit IV

    8. (a) What is Raman effect ? Discuss the


    classical theory of Raman effect. 10

    (b) In the rotational Raman spectrum of HCl


    molecule, the displacement form the
    exciting lines are represented by :

    v = ± (62.4 + 4 + 41.6J) cm–1

    Calculate the moment of inertia of HCl


    molecule. 5

    M-D511 6 70 (4-22/19) M-D511 5 P.T.O.

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