Q1) At what

temperature , average speed

molecule will be double that
of gas
at 270C .

A) 27°C B) 327°C C) 527°C 927°C .

U2) At 400k , root mean square speed

CMw=uo) to most
of gas X is equal

probable speed at 60k

of gas y
.

Find MW
of Gas y .

( Ans :
by

43) The atomic masses He and Ne are

of
and The
Hamm 20 amu
respectively .
value

of De-

broglie wavelength of the

gas at

-
730C is M times that
of De -

Broglie
Ne at 7270C Find
wavelength of
.

Value M ( Ans 5)
of . :
Sen .

① ( Vang ) =
2
(Vang ) ,
,

fIma=zF¥y
Fiz = 2ft,

Tz z UXTI

24×300
Tz z 1200 K

1- ( K ) = ECC ) -1-273

t.CC ) = T CK ) -

273
= 1200 -

273
= 927 °C
-
 400K ← Ts 607C
,

② Vrms ex ) =
Umps ly)

E¥=f÷
sXff→ =

2rmXy
My =
II
30

My =
y

#
vrms

③ Xue = M -
1)
we

( Erm ): .
"

Ernst .

¥+1 .
-
-
m
- =
M '

p¥o . ooo

# 1000
¥wq
a M

M = Ft

M z 5

=
 |M0lFWlARspEE
IMAXWELLDISTRIBUMONOFT

main fraction of
molecules
.

T - - - - - -
t .
.
- - - -

i
-

# ,

Is
'
'
DN '
'
i
p
I

High
,

speech →
i
,

low speed
O u at du Umps Varg Vrms .

UC speed) →

DN =
no >

of molecules having speed in between u

and Utd'u ,
in terms of total no -

of molecules
' '

present in
N
gas .

And = Fraction
between
of
u and
molecules

UT du
having
.
speed in
Izu ( DNI ) having
=
Fraction of molecules speed
between u and at du
per unit
interval of speed .

dN=N( ,,m a
"
-
u
? eT¥t ! du
-
"
-7¥
HI) "
tf ; we
.

= -

da { Tu CF ) }
For most
probable speed ,
-

- O

.ie?e-mIEJ=o
"
da { ( a7 )
'
"
hit
,
↳
ad-acu.us
u
Fat V
day
-
-
-

[ "'
TIE
,

utf¥ e- .
run -

may;)
- o
 Z
- mu
Tier U A

}
=0 =D =
this
e neglecting
vanes
O =p U = 0 (as it is least
2h
speed
=

probable

I -

MI
2kt
=o
U =

JET M
most

probable
speed

Vmpsz ¥4 m

Umps =

¥1 M

From Graph
-

i) Fraction mummies having low speed

of
and high speed is very less .

ii) Maximum fraction molecules having

of
most
probable speed at a
given
temperature .

iii) At a given temperature ,

molecular speed
varies from o to es .
 iii) Area under curve total
represents no -

of molecules consists all speed

of
present in sample .

Area under curve remains constant

at all temperatures .

( as molecules will be constant

no
of
.

at
different temperatures )

same Gas temperature

at
different
^

T :

÷
ammonia: ¥:
'" "
: :

Imps
:*¥¥
o vmpse, , is, High speed
speed speed CU) →
 Vmpscz > Umps ( Fhm hnrph )
, ep

C ::
"

>
Tz
'

. .
> T,

fraction of molecules having low speed

is
greater at
temp T, writ temp Tz

Ns temp .
Mses ,

Fraction of molecules
having high
speed is more at
temp Tz w -
rt

temp T
,
.
 Gas at Same
Different Temp .

Gas '

÷÷÷÷
r M'
- - - - -
-
-
i
ans -
2-
Gas-3
-

i - - -

:( Md
Cms,
-
- - - -

DN '
i

1 I
,

l l

I
l '

°
Vmpse , , VMPSC's Vmpscz,
speed cu ) →

Vmpscz > Vmpscz, > Vmpsc , ) ( lGmpb )

,

=
FRI Umps Atm
(#
-

>
Mz Mz C
'
. . C MI