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    Experiment 20

    Uploaded by

    Beenu Singh
    This document describes an experiment to detect the presence of acidic and basic radicals in a given compound. Tests were conducted to identify the radicals nitric acid (NO3-) and lead (Pb2+). Nitric acid was confirmed through the production of reddish-brown gas when conc. H2SO4 was added, as well as the formation of dark brown fumes and a ring when copper chips and ferrous sulfate solution were added respectively. Lead was identified by the formation of a white precipitate with dilute HCl and yellow precipitates with potassium iodide and potassium chromate, confirming the presence of lead ions.

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    Experiment 20

    Uploaded by

    Beenu Singh
    40 views4 pages
    This document describes an experiment to detect the presence of acidic and basic radicals in a given compound. Tests were conducted to identify the radicals nitric acid (NO3-) and lead (Pb2+). Nitric acid was confirmed through the production of reddish-brown gas when conc. H2SO4 was added, as well as the formation of dark brown fumes and a ring when copper chips and ferrous sulfate solution were added respectively. Lead was identified by the formation of a white precipitate with dilute HCl and yellow precipitates with potassium iodide and potassium chromate, confirming the presence of lead ions.

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    This document describes an experiment to detect the presence of acidic and basic radicals in a given compound. Tests were conducted to identify the radicals nitric acid (NO3-) and lead (Pb2+). Nitric acid was confirmed through the production of reddish-brown gas when conc. H2SO4 was added, as well as the formation of dark brown fumes and a ring when copper chips and ferrous sulfate solution were added respectively. Lead was identified by the formation of a white precipitate with dilute HCl and yellow precipitates with potassium iodide and potassium chromate, confirming the presence of lead ions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    40 views4 pages

    Experiment 20

    Uploaded by

    Beenu Singh
    This document describes an experiment to detect the presence of acidic and basic radicals in a given compound. Tests were conducted to identify the radicals nitric acid (NO3-) and lead (Pb2+). Nitric acid was confirmed through the production of reddish-brown gas when conc. H2SO4 was added, as well as the formation of dark brown fumes and a ring when copper chips and ferrous sulfate solution were added respectively. Lead was identified by the formation of a white precipitate with dilute HCl and yellow precipitates with potassium iodide and potassium chromate, confirming the presence of lead ions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    EXPERIMENT-20

     AIM: To detect the presence of acidic and basic


    radical in the given compound.
     MATERIALS REQUIRED: Test tubes, test tube
    stands, burner, glass rod, test tube holder, dil. H2SO4,conc.H2SO4,
    copper chips , ferrous sulphate , ammonium acetate , potassium iodide ,
    potassium chromate.

     PROCEDURE:

    Test for acidic radical:


    EXPERIMENT OBSERVATION INFERENCE

    To the original No observation Dilute group is


    solution add dil. absent.
    H2SO4.

    To the salt add Reddish brown gas NO3- [nitrate] may be


    conc. H2SO4 and a small with pungent smell present.
    paper ball and heat. comes out.

    Copper Chips test: To the Dark brown fumes NO3- [nitrate] is confirmed.
    salt add of nitrogen dioxide
    conc. H2SO4 and few copper are formed.
    chips, heat the test tube.

    Ring test: Add a Dark brown ring is formed at NO3- [nitrate] is confirmed.
    small quantity of the junction of the layers of
    freshly prepared the acid and the solution.
    solution of ferrous
    sulphate to a part
    of the aqueous
    solution of a salt
    and add conc. H2SO4 slowly
    along the sides of
    the testube.
    Test for basic radical:

    EXPERIMENT OBSERVATION INFERENCE


    To the salt add NaOH No pungent ammoniacal 0 group is absent.
    solution and warm. smell.

    To the original solution of White ppt is formed. Pb2+ may be present.


    salt, add dil. HCl.

    Boil the white ppt with


    5-10ml of water and
    divide the solution in 2
    parts..
    Potassium Iodide Yellow ppt. Lead is confirmed.
    test: To the first part of
    ppt add KI solution.

    Potassium Yellow ppt. Lead is confirmed.


    chromate: dissolve
    the ppt in hot
    ammonium acetate
    and KCrO4 solution to it.

     RESULT:
    Acidic Radical: Nitrate (NO3-)
    Basic Radical: Lead (Pb2+)

     PRECAUTIONS:
     Handle reagents carefully.
     Wash the test tube after chemical reaction.
     Don’t use broken glass ware.

    WITH PENCIL ON FIRST BLANK PAGE:


    Copper chips test:
    2KNO3 + H2SO4 → K2SO4 + 2HNO3

    4HNO3 + Cu → Cu(NO3)2 + 2NO2 + 2H2O


    (Reddish Brown)

    Ring test:
    KNO3 + H2SO4 → KHSO4 + HNO3

    6FeSO4 + 3H2SO4+ 2HNO3 → 3Fe2(SO4)3 + 4H2O + 2NO

    FeSO4 + NO + 5H2O → [Fe(NO)(H2O)5]SO4


    (Brown Ring)
    WITH PENCIL ON SECOND BLANK PAGE:
    Reactions involved in group 1 analysis:

    Pb(NO3)2 + 2HCl → PbCl2 + 2HNO3

    (white ppt)

    Potassium Iodide test:

    PbCl2 + 2KI → PbI2 + 2KCl

    (yellow ppt)

    Potassium Chromate test:

    PbCl2 + K2CrO4 → PbCrO4 + 2KCl

    (yellow ppt)

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