FIBROHAS 5%

SC

宁波汇力进出口有限公司

NINGBO HUILI IMPORT & EXPORT CO., LTD.

1403 AUX CENTRAL BUILDING, 757 RILI ZHONGLU, YINZHOU, NINGBO, 315100, CHINA
 MATERIAL SAFETY DATA SHEET

SECTION 1. PRODUCT AND COMPANY

IDENTIFICATION
• Product Name: FIPROHAS 5% SC (FIPRONIL 5% SC)

• Use Catalogue: Hygienic Insecticide

• Chemical Name:

• (±)-5-amino-1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-4-
trifluoromethylsulfinylpyrazole-3-carbonitrile

• CAS Number: 120068-37-3

SECTION 2. COMPOSITION/INFORMATION ON
INGREDIENTS

Ingredients CAS Number Concentration (% w/w)

Fipronil 120068-37-3 5.0

Inert ingredients - Up to 100.0

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 SECTION 3. HAZARDS IDENTIFICATION
• Potential Health Effects & Symptoms

• Eyes: May cause redness and tearing of eyes.

• Skin: May cause irritation, redness and tearing of skin.

• Ingestion: Harmful if swallowed.

• Inhalation: Harmful if inhaled.

• Chronic exposure: May cause chronic respiratory problems

like asthma, emphysema, or bronchitis.

SECTION 4. FIRST AID MEASURES

If swallowed Call a poison control center or doctor immediately for treatment

advice

Have person sip a glass of water if able to swallow

Do not induce vomiting unless told to do so by the poison control

center or doctor.

Do not give anything by mouth to an unconscious person

If on skin or Take off contaminated clothing.

clothing
Rinse skin immediately with plenty of water for 15-20 minutes

Call a poison control center or doctor for treatment advice

If inhaled: Move person to fresh air

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 If person is not breathing, call an ambulance, then give artificial
respiration, preferably by mouth-to-mouth if possible.

Call a poison control center of doctor for further treatment

advice

If in eyes Hold eye open and rinse slowly and gently with water 15-20
minutes

Remove contact lenses, if present, after the first 5 minutes, then

continuing rinsing eye.

Call a poison control center or doctor for treatment advice

Note to There is no specific antidote. All treatment should be based on

Physician observed signs and symptoms of distress in the patient.
Overexposure to materials other than this product may have
occurred. In severe cases of overexposure by oral ingestion
lethargy muscle tremors and in extreme cases possibly
convulsions may occur.

Have the product container or label with you when calling a

poison control center or doctor, or going for treatment.

SECTION 5. FIRE FIGHTING MEASURES

• FLASH POINT: Not applicable

• FLAMMABLE LIMITS: Not applicable

• EXTINGUISHING MEDIA: Water spray, CO2,

foam, dry powder.

• FIRE & EXPLOSION

• HAZARDS: Pesticide fires have potential to emit

hazardous gases such as carbon monoxide, carbon
dioxide, hydrogen fluoride, hydrogen chloride,
nitrogen oxides, sulfur oxides, acid halides. If product

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 is heated above decomposition temperature, toxic
vapours will be released. The substances/groups of
substances mentioned can be released if the product is
involved in a fire.

• FIRE-FIGHTING

PROCEDURES: Isolate fire area and evacuate

downwind. DO NOT breathe gases, smoke or vapors
generated. Wear self-contained breathing apparatus
and full-protective clothing.

HAZARDOUS DECOMPOSITION PRODUCTS:

May release irritating and toxic gases due to thermal

decomposition.

SECTION 6. ACCIDENTAL RELEASE MEASURE

ACTION TO TAKE FOR SPILLS/LEAKS: Take appropriate protective measures. Wear
positive pressure self-contained breathing apparatus (SCBA). Clear area. Dike spillage. Do
not touch or walk through spilled material. Shut off source of leak only under safe
conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate
ventilation. Take up with sand or other non-combustible absorbent material and place into
containers for later disposal. Prevent entry into waterways, sewers, basements or confined
areas

SECTION 7. HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING:
Do not contaminate water, food, or feed by storage or disposal or cleaning of equipment.
Carefully open containers and after partial use close container tightly. Avoid contact with
skin, eyes or clothing. Avoid breathing spray mist. Wash thoroughly with soap and water
after handling. Remove contaminated clothing and wash before reuse.
PRECAUTIONS TO BE TAKEN IN STORAGE:
Store unused product in original container only out of reach of children and animals.
STORAGE TEMPERATURE (MIN/MAX): Normal ambient temperatures.

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 SECTION 8. EXPOSURE CONTROLS/PERSONAL
PROTECTION

• HAND PROTECTION: Chemical-resistant gloves.

• SKIN PROTECTION: Long-sleeve shirt, long pants, shoes

plus socks.

• EYE PROTECTION: Protective eyewear or chemical

safety glasses with side shields or chemical goggles when
working in non-ventilated spaces.

RESPIRATOR REQUIREMENTS : If handling

without sufficient ventilation, wear a dust/mist filtering
respirator (MSHA/NIOSH approval number prefix TC-21C0
or a NIOSH approved respirator with any N, R, P or HE class
filter.

VENTILATION: Whenever possible, adequate ventilation

should be used to minimize the need for personal protective
equipment

ADDITIONAL PROTECTIVE
MEASURES:
Follow manufacturer’s instructions for cleaning/maintaining
PPE. If no such instructions for washables, use detergent and
hot water. Keep and wash PPE separately from other
laundry. Discard clothing and other absorbent materials that
have been drenched or heavily contaminated with this
product. Do not reuse them.

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 USER SAFETY
RECOMMENDATIONS:
Users Should:

• Wash hands before eating, drinking, and chewing

gum, using tobacco, or using the toilet.

• Remove clothing immediately if pesticide gets inside.

Then wash thoroughly and put on clean clothing.

• Remove PPE immediately after handling this

product. Wash the outside of gloves before
removing. As soon as possible, wash thoroughly and
change into clean clothing.

ENGINEERING CONTROLS:

Minimize airborne concentration.

SECTION 9. PHYSICAL AND CHEMICAL

PROPERTIES

Appearance Liquid flowable suspension

PH 5-7(1% in water)
Flash point Not applicable
Density 1.06 g/ml@26 oC

SECTION 10. STABILITY AND REACTIVITY

• STABILITY: Stable under normal conditions.

• CONDITIONS TO AVOID: Strong oxidizing agents.

Avoid excessive heat.

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 • HAZARDOUS DECOMPOSITION PRODUCTS: May
release irritating and toxic gases due to thermal
decomposition.

• HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11. TOXICOLOGICAL

INFORMATION
Acute Oral LD50 (Rat):1,999mg/kg
Acute Dermal LD50 (Rabbit): > 2,000 mg/kg
Acute Inhalation LC50 (Rat): > 1.7 mg/L/4 hr
Eye Irritation: Slightly irritating
Skin Irritation: Slightly irritating
Dermal Sensitization: Not a skin sensitizer

SECTION 12. ECOLOGICAL INFORMATION

ENVIRONMENTAL HAZARDS:
This pesticide is toxic to birds, fish and aquatic invertebrates.
Do not apply directly to water or to areas where surface waters
present or to intertidal areas below the mean high water mark.
Runoff from treated areas may be hazardous to aquatic
organisms in neighboring disposal of wastes. Do not
contaminate water when disposing of equipment wash waters.

ECOTOXICOLOGICAL
INFORMATION (data on Fipronil)
Bluegill sunfish (Lepomis macrochirus LC50 (96 h) – 0.083 mg/L
Rainbow trout (Onchorhynchus mykiss) LC50 (96 h) – 0.246 mg/L
Sheephead minnow LC50 (96 h) – 0.13 mg/L
Water flea (Daphnia magna) NOEL – 9.8 μg/L; LOEL - 20 μg/L
Bobwhite quail LD50 - > 11.3 mg/kg

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 SECTION 13. WASTE DISPOSAL
CONSIDERATIONS
• PESTICIDE DISPOSAL: Pesticide wastes are acutely
hazardous. Improper disposal of excess pesticide,
spray mixture, or rinsate is a violation of Federal Law.
Dispose of excess or waste pesticide by use according
to label directions, or contact your State Pesticide or
Environmental Control Agency, or the Hazardous
Waste representative at the nearest EPA Regional
Office for guidance.

• CONTAINER DISPOSAL: Dispose of product

containers, waste containers, and residues according to
label instructions and local, state, and federal health
and environmental regulations.

SECTION 14. TRANSPORT INFORMATION

• Ground Domestic

• (DOT): Not regulated.

• Vessel (IMDG): UN3082, Environmentally Hazardous

substances, liquid, n.o.s. (Fipronil), 9, PG III, Marine
Pollutant

Air (IATA): UN3082, Environmentally Hazardous

substances, liquid, n.o.s. (Fipronil), 9, PG III

SECTION 15. REGULATORY INFORMATION

This safety datasheet complies with the requirements
of local regulation

SECTION 16. OTHER INFORMATION

No data available