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Co-Ordination Compound (Question Paper)

This document contains a practice test on coordination compounds for the IIT-JEE exam. It has three sections - single answer multiple choice questions, multiple answers multiple choice questions, and integer answer questions. The test covers topics like geometry and hybridization of complexes, isomerism, magnetic properties, redox behavior and coordination numbers. An answer key is provided at the end.

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72 views

Co-Ordination Compound (Question Paper)

This document contains a practice test on coordination compounds for the IIT-JEE exam. It has three sections - single answer multiple choice questions, multiple answers multiple choice questions, and integer answer questions. The test covers topics like geometry and hybridization of complexes, isomerism, magnetic properties, redox behavior and coordination numbers. An answer key is provided at the end.

Uploaded by

Param shah
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE

IIT – JEE: 2020 TW TEST (ADV) DATE: 11/08/19


TIME: 1 Hr. TOPIC: CO-ORDINATION COMPOUND MARKS: 80

SECTION-I (SINGLE ANSWER CORRECT TYPE)


This section contains 05 Multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONLY ONE is correct. (+4, –1)

21. Select correct statement about anionic part of Zeise’s salt, K[Pt(n2 – C2H4)Cl3] :
(A) C=C bond is coplanar with Pt and 3 Cl atoms.
(B) Oxidation state of Pt is +3.
(C) HCH bond angle is not same as that in free ethylene molecule.
(D) Pt–Cl bond is not affected by synergic bonding between Pt and C2H4

22. Number of stereoisomers possible for bis (benzoylacetanato)beryllium(II) are


(A) 2 (B) 3 (C) 4 (D) 6

23. Total number of Co–N (cobalt-nitrogen linkages in

(Gly–1 = Glycinate).
(A) 3 (B) 8 (C) 6 (D) 4

24. Consider the following complex for given question dichloro bis(ethylenediamine)chromium(III)
chloride
* Number of unpaired electrons in complex = X

* One mole complex mole of AgCl.


* Total stereoisomeric forms of above complex = Z
The sum of X, Y and Z is
(A) 6 (B) 7 (C) 8 (D) 4

25. Consider the following statements


S1 : [Cr(NH3)6]3+ is inner orbital complex with crystal field stabilization energy equal to –1.2 o
S2 : The complex formed by joining the CN– ligands to Fe3+ ion has theoretical value of ‘spin only’
magnetic moment equal to 1.73 B.M.
S3 : Na2S + Na2 [Fe(CN)5NO]  Na4[Fe(CN)5NOS], In reactant and product the oxidation states of
iron are same
and arrange in the order of true/false.
(A) F T F (B) T T F (C) T T T (D) F F F

CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI #1
SECTION-II (MULTIPLE ANSWER(S) CORRECT TYPE)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO incorrect
option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will
result in –2 marks, as a wrong option is also darkened.

26. Select CORRECT option(s) for K2Ba[Ni(NO2)6] complex :


(A) Octahedral geometry on central metal

(B) Paramagnetic and


(C) According to VBT sp3d2 hybridisation of central metal

(D) As per C.F.T. unpaired electrons are present in and 3dxy orbital of central metal

27. Which of the complex/es is/are optically active and paramagnetic :


(A) [Cr(gly)3]0 (B) [Pt(en)3]4 (C) [Ru(en)3]3 (D) [Zn(gly)2]0

28. Which of the following statement(s) is/are correct?


(A) [Co(NH3)6]3+, [Co(CN)6]3– and [Co(NO2)6]3– are diamagnetic involving d2sp3 hybridisation.
(B) [Zn(NH3)4]2+, [FeCl4]– and [Ni(CO)4] are diamagnetic involving sp3 hybridisation.
(C) The magnetic moment of [Fe(H2O)6]3+ is 5.92 B.M. and that of [Fe(CN)6]3– is 1.73.
(D) The magnetic moment of K4[MnF6] and K3[FeF6] are same.

29. Which of the following statement(s) is/are true for [Cu(NO2)6]4– and [Fe(H2O)6]3+?
(A) Both are outer orbital complexes.
(B) Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.
(C) The former complex is paramagnetic with one unpaired electron while later one is paramagnetic
with five unpaired electrons.
(D) The former is outer complex and later is inner orbital complexes respectively.

30. Select incorrect statement(s) for [Cu(CN)4]3–, [Cd(CN)4]2– and [Cu(NH3)4]2+ complex ion.
(A) Both [Cd(CN)4]2– and [Cu(NH3)4]2+ have square planar geometry
(B) [Cu(CN)4]3– and [Cu(NH3)4]2+ have equal no. of unpaired electron
(C) Mixture of [Cu(CN)4]3– and [Cd(CN)4]2– can be separated on passing H2S gas.
(D) All the three complexes have magnetic moment equal to zero.

31. Which of the following is/are correct about [Cu(NH3)4]SO4?


(A) It is a square planar complex.
(B) It is paramagentic with one unpaired in the d-subshell.
(C) It gives white ppt with BaCl2
(D) Its aqueous solution does not conduct electricity.

32. Which of the following complex(s) is/are low spin?


(A) K4[Fe(CN)6] (B) [PtCl4]2– (C) [Co(C2O4)3]3– (D) [CoF6]3–

CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI #2
33. Which is correct statement(s)?
(A) [Ag(NH3)2]+ is linear with sp hybridised Ag+ ion
(B) and have tetrahedral geometry
(C) [Cu(NH3)4] , [Pt(NH3)4] & [Ni(CN)4]2– have dsp2 hybridisation of the metal ion
2+ 2+

(D) Fe(CO)5 has trigonal bipyramidal structure with hybridised iron.

34. Which of the following complex / molecule acts as a reducing agent?


(A) [Co(NH3)6]2+ (B) [Mn(CO)6] (C) NO (D) CO

35. Select the correct statement.


(A) [Co(H2O)6]3+ is Co(III), low spin, 0 unpaired electron, diamagnetic
(B) [CoF6]3– is Co(III), high spin d6, 4 unpaired electron, paramagnetic
(C) [RhF6]3– is Rh(III), low spin d6, 0 unpaired electrons diamagnetic
(D) [Fe(CN)6]4– is high spin d6, 0 unpaired electron diamagnetic

SECTION-III (INTEGER ANSWER TYPE)


This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. 6.25, 7.00, 0.33, 30.27, 127.30) (+4, –1)

36. Consider following complexes


[NiCl3Br2(H2O)]–3, [Fe(C2O4)Cl4]–3, [CuCl4(H2O)Br]–3,
[Pd(gly)Cl4] –1, [Fe(C2O4)3]3–, [Mg(EDTA)]–2
Let number of complexes showing
(i) Only geometrical isomerism = x
(ii) Only optical isomerism = y
(iii) neither geometrical nor optical isomerism = z
(iv) Showing both geometrical and optical isomerism = t

Find

37. How many of the following species have C–O bond angle longer than that of free CO molecule
[V(CO)6]–, [Ti(CO)6]2–, [Co(NH3)3(CO)3]3+, [Cr(CO)6], HMn(CO)5, Mn2(CO)10, CO2, CO32–,
[Fe(CN)5(CO)]3–

38. (a) A = no. of unpaired electron(s) is/are present in t2g orbital of [Fe(NH3)6]2+ complex ion
(b) B = co-ordination number of central atom of cis-platin.
(c) C = no. of d-orbital(s) is / are involve in hybridisation of Fe in K4[Fe(CN)5O2].
(d) D = no. of electron(s) is / are present in eg orbitals of [Co(C2O4)3]3–.
Find A + B + C + D

39. The oxidation number of iron in sodium nitroprusside is _______

40. Find out the total number of stereoisomer possible for [Co(CN)2(NO2)2(NH3)(py)]– is _______

CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI #3
MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE
IIT – JEE: 2020 TW TEST (ADV) DATE: 11/08/19
TOPIC: CO-ORDINATION COMPOUND

ANSWER KEY

21. (C) 22. (A) 23. (D) 24. (B) 25. (C)

26. (ABC) 27. (AC) 28. (ACD) 29. (AC) 30. (ABD)

31. (ABC) 32. (ABC) 33. (AB) 34. (ABCD) 35. (ABC)

36. (2) 37. (9) 38. (8) 39. (2) 40. (8)

CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI #4

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