2015 Second LS

‫ االستثنائيـة‬5102 ‫دورة العام‬ ‫امتحانات الشهادة الثانوية العامة‬ ‫وزارة التربية والتعليم العالي‬
5102 ‫ آب‬01 ‫االثنين‬ ‫ علوم الحياة‬:‫فرع‬ ‫المديرية العامة للتربية‬

‫دائرة االمتحانات‬
:‫االسم‬ ‫مسابقة في مادة الكيمياء‬
:‫الرقم‬ ‫المدة ساعتان‬
This Exam Includes Three Exercises. It Is Inscribed on 4 Pages Numbered From 1 to 4. The
Use of A Non-programmable Calculator is Allowed.
Answer The Three Following Exercises:
First Exercise (7 points)

Acid-Base Reaction
The label of a bottle containing a commercial hydrobromic acid solution shows, among others,
the following indications:
46 % by mass of HBr; density: 1.47 g.mL-1.
The aim of this exercise is to perform an acid-base study of a dilute aqueous hydrobromic acid
solution.
Given: - M( HBr ) = 81 g.mol-1

- pKa (NH 4 /NH3) = 9.2
1- Dilution of the Commercial Solution
1.1- Show that the molar concentration of the commercial solution is C0 = 8.35 mol.L -1.
1.2- Describe the experimental procedure to be followed in order to prepare 1 L of a solution (S)
by diluting the commercial solution 200 times .
1.3- The pH of the solution (S) is equal to 1.38

1.3.1- Show that HBr is a strong acid.
1.3.2- Write the equation of its reaction with water.
2- Titration of an Aqueous Ammonia Solution.
The solution (S) is added, progressively, into a beaker containing a volume Vb = 10.0 mL of an
ammonia solution (NH3) of concentration Cb, in the presence of an appropriate colored indicator.
The volume of the acid added to reach equivalence is VaE= 12ml
2.1- Write the equation of the titration reaction.

2.2- Justify, based on the chemical species present at equivalence, the acid character of this
medium.
2.3- Show that the concentration of the ammonia solution is Cb = 5.0×10 -2 mol.L -1.
2.4- Calculate the volume of ammonia gas needed to prepare 1 L of the ammonia solution of
concentration Cb, knowing that the molar volume of a gas is Vm = 24 L.mol-1.
1
3- Preparation of a Buffer Solution
Determine the volume V1 of the solution (S) that should be added to a volume V2 = 50 mL of the
ammonia solution of concentration Cb in order to prepare a buffer solution of pH = 9.0
Second Exercise (6 points)

Synthesis of an Ester
Available are two flasks: one containing glacial (pure) ethanoic acid and the other contains a
liquid of a pure saturated noncyclic chain organic compound (A).
The aim of this exercise is to identify the organic compound (A) then to study its reaction with
ethanoic acid.
1- Identification of the Family of (A)
In order to identify the chemical family of the compound (A), the experiments listed below are
carried out:
Number of the Experiment Result of the experiment

experiment
1 (A) + sodium metal Hydrogen gas release.
Heating a mixture of : Formation of an organic compound
2 (A)+ thionyl chloride (SOCl2) (B) accompanied with the release of
two gases.
Moreover, a study of the compound (B) shows that the molecule of the compound (B) contains only
carbon, hydrogen and chlorine.
1.1- Interpret the result of experiment 1.

1.2- Deduce from the experiment 2, the possible chemical families of the compound (B).
1.3- Show that the compound (A) is an alcohol of general formula CxH2x+2O.
2- Esterification Reaction
A mixture of 0.5 mol of ethanoic acid and of 0.5 mol of the compound A is heated. At equilibrium, a
quantity of 0.3 mol of an ester E of molecular formula C6H12O2 is obtained.
Given: The equilibrium constant K, associated with the equation:

RCOOH(l) + R′OH(l) ⇄ RCOOR′(l) + H2O(l)
is equal to 4.12 if the alcohol is primary and to 2.25 if the alcohol is secondary.
2.1- Determine the molecular formula of the alcohol (A).

2.2- Write the possible condensed structural formulas of the ester (E).
2.3- Show that the equilibrium constant of the equilibrium realized above is equal to 2.25
2.4- Identify the alcohol (A) and name the ester (E).
2
2.5- Represent, according to Cram, the two enantiomers of the alcohol (A).
Third Exercise (7 points)

Oxidation of Iodide Ions
A solution (S) is prepared by mixing a volume 100 mL of a potassium iodide solution(K+ + I-) of
concentration C1 = 0.80 mol.L -1 with a volume 100 mL of sodium peroxydisulfate solution
(2 Na+ + S2O 82  ) of concentration C2 = 0.20 mol.L-1.
A brown color is observed which intensifies with time representing a complete reaction that takes
place according to the following equation:
S2O 82  + 2 I – → 2 SO 24  + I2
At different time intervals, a precise volume of the solution (S) is taken and the iodine formed is
titrated,in the presence of starch solution, using a sodium thiosulfate solution(2 Na+ + S2O 32  )
according to the equation:
I2 + 2 S2O 32  → 2 I – + S4O 62 
Given:
- Fe2+ is a catalyst for the reaction of formation of iodine.
- M (Na2S2O3. 5 H2O) = 248 g.mol-1
1- Preparation of Sodium Thiosulfate Solution
The sodium thiosulfate solution, used to titrate iodine, is prepared by dissolving a mass
m = 25.0 g of the hydrated powder (Na2S2O3.5H2O) in distilled water in order to have a solution
of volume V = 500.0 mL.
1.1- List the essential materials needed to carry out this preparation.
1.2- Calculate the molar concentration C of this solution.
2- Titration of Iodine
2.1- Propose, by justifying, an experimental way to stop the formation of iodine in each
volume taken before carrying out titration.
2.2- Specify the color change at equivalence.
3- Kinetic Study
3.1- Given the shapes of the two curves a and b.

Choose the one that corresponds to the change of the iodine concentration, in the solution S,
versus time: [I2] = f (t).Justify
3
3.2- The experimental study shows that this reaction ends at t = 70 min.
3.2.1- Define the half- life time of the reaction
3.2.2- Choose, by justifying, among the three following proposals, the appropriate one for the
half-life time :
t 1/2 = 35 min ; t 1/2 > 35 min ; t 1/2 < 35 min.
3.3- The interval of time ∆t denotes the end time of reaction for each of the reacting mixtures
considered in the table below:
Reacting mixture Temperature of the ∆t

mixture
Mixture (1) :a volume V of solution (S) 40oC ∆t1
Mixture (2) :a volume V of solution (S) 20oC ∆t2
+ few mL of a solution of Fe2+ ions
(without a noticeable change in
volume).
Verify whether ∆t1 and ∆t2 could be compared.

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‫ االستثنائيـة‬5102 ‫دورة العام‬ ‫امتحانات الشهادة الثانوية العامة‬ ‫وزارة التربية والتعليم العالي‬

5102 ‫ آب‬01 ‫االثنين‬ ‫ علوم الحياة‬:‫فرع‬ ‫المديرية العامة للتربية‬

Answer The Three Following Exercises:

First Exercise (7 points)

Given: - M( HBr ) = 81 g.mol-1

1- Dilution of the Commercial Solution

1.3- The pH of the solution (S) is equal to 1.38

2- Titration of an Aqueous Ammonia Solution.

2.1- Write the equation of the titration reaction.

Second Exercise (6 points)

1- Identification of the Family of (A)

Number of the Experiment Result of the experiment

1.1- Interpret the result of experiment 1.

Given: The equilibrium constant K, associated with the equation:

2.1- Determine the molecular formula of the alcohol (A).

Third Exercise (7 points)

1- Preparation of Sodium Thiosulfate Solution

3.1- Given the shapes of the two curves a and b.

Reacting mixture Temperature of the ∆t

Verify whether ∆t1 and ∆t2 could be compared.

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