Combustion Solutions

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Combustion topic test solutions

SECTION A: Multiple-choice questions (1 mark each)

Question 1

Answer: B

Explanation:

The definition of specific heat capacity – the energy required to raise the temperature of 1 g of the substance by
1 0C.

Question 2

Answer: D

Explanation:

Question 3

Answer: A

Explanation:

The question refers to the reverse reaction. The value of ΔH can be read from the graph

Question 4

Answer: D

Explanation:

The energy from hydrogen will be 10 × 141 = 1410 kJ


Mass ethane = 1410/51.9 = 27.2

Question 5

Answer: C

Explanation:

2C2H6(g) + 7O2(g)  4CO2(g) + 6H2O(l)


The volume of O2 will be 4 × 7/2 = 14

 POSHEA 2019 Page 1 of 4


2019 CHEMISTRY KEY TOPIC TEST
Question 6

Answer: B

Explanation:

Energy = 1.2 × 29600 = 35520 J

Change in temp = 35520/(4.18×800) = 10.6

Question 7

Answer: B

Explanation:

Energy from 13 mol is 5660 kJ.


From 1 mol it will be 435 kJ

Question 8

Answer: A

Explanation:

The formula is obtained by substituting m = n × M into n =

Question 9

Answer: B

Explanation:

From Boyle’s Law, pressure and volume are inversely proportional as this graph shows.

Question 10

Answer: D

Explanation:

Incomplete combustion usually forms arrange of products. The amount of carbon formed will increase as
oxygen becomes more scarce.

© POSHEA 2019 Page 2 of 4


2019 CHEMISTRY KEY TOPIC TEST
SECTION B: Short-answer questions

Question 1 (9 marks)
a. 173 K 383 K
b. 263 kPa 93.3 kPa 2 marks
nRT 1× 8.31 ×373
c. V = = = 31.0 L 2 marks
P 100

d. 12 L. The pressure has gone up by a factor of 4 so the volume will drop by a factor of 4 1 mark
e. n(N2) = 60/28 = 2.14 mol V = 2.14×24.8 = 53.1 L 2 marks

Question 2 (7 marks)
a. i. enthalpy of the products is less enthalpy of the reactants 1 mark
ii. temperature of the surroundings will be hotter 1 mark

iii. the change in enthalpy is considered to be the enthalpy of the products – the enthalpy of the reactants:
this will lead to a negative answer for an exothermic reaction

b. A large ΔH for the energy and a large activation energy making it safe to handle 2 marks

c. Activation energy: 576 kJ mol-1 ΔH +220 kJ mol-1 2 marks

Question 3 (10 marks)


a. i. 9.5 0C 2 marks
ii. 0.60 g

b. i. energy = 4.18 ×136 ×9.5 = 5400 J 1 mark

ii. n(methanol) = 0.6/32 = 0.0188 mol


ΔH mole-1 = 5400/0.0188 = 287000 J = 287 kJ 2 marks

iii. ΔH g-1 = 5400/0.6 = 9000 J = 9kJ g-1 1 mark

iv. 2COH4(l) + 3O2(g)  2CO2(g) + 4H2O(l) ΔH = - 574 kJ mol-1 2 marks

c. The values obtained by experimentation will be low due to heat losses during combustion. The water
would need to have a lid, be insulated and stirred. 2 marks

© POSHEA 2019 Page 3 of 4


2019 CHEMISTRY KEY TOPIC TEST

Question 4 (8 marks)
a. i. energy = 80.8× 47.9 = 3870 kJ 1 mark
80.8
ii. n(octane) = = 0.709 mol n(CO2) = 0.709 × 8 = 5.67 mol
114
mass = 5.67 × 44 = 249 g 3 marks
nRT 5.67 ×8.31 ×627
iii. V = = = 328 L 2 marks
P 90

b. mass = 1000/47.9 = 20.9 mol 2 marks

Question 5 (6 marks)
a. 40 L of ethane is reacted with 84 L of oxygen gas. (Conditions are held constant)
i. 48 L (O2 scarce) 1 mark
ii. 72 L 1 mark
iii. 40 – 24 = 16 L ethane 1 mark

b. n(ethane) = 0.28 ×2/7 = 0.08 mol V = 0.08× 24.8 = 1.98 L 2 marks

c. 2C2H6(g) + 5O2(g)  4CO(g) + 6H2O(g)


1 mark

© POSHEA 2019 Page 4 of 4

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