Chemical Reactions and Equations-1
Chemical Reactions and Equations-1
Chemical Reactions and Equations-1
3. Write a balanced chemical equation with state symbols for the following reactions
i) Solutions of Barium chloride and Sodium sulphate in water react to give insoluble
Barium sulphate and solution of Sodium chloride.
ii) Sodium hydroxide solution in water reacts with the hydrochloric acid solution to
produce Sodium chloride solution and water.
Solution:
i) BaCl2 + Na2SO4 → BaSO4 + 2NaCl
ii) NaOH + HCl → NaCl + H2O
2. Why is the amount of gas collected in one of the test tubes in Activity 1.7 double the
amount collected in the other? Name this gas.
Solution:
In activity 1.7, gas collected in one of the test tubes is double of the amount collected in the other
because water gets hydrolysed to release H2 and O2 gas. Here, after electrolysis two molecules of
Hydrogen and one molecule of oxygen gas are released; hence, the amount of Hydrogen collected
would be double than that of oxygen.
3. Identify the substances that are oxidised and that are reduced in the following equation.
i) 4Na(s) + O2(g) → 2Na2O(s)
ii) CuO(s) + H2(g) → Cu(s) + H2O(l)
Solution:
The Sodium (Na) in the first equation is getting oxidized with the addition of Oxygen (O2), and the
Copper (Cu) in the second equation is reduced due to the addition of Hydrogen (H2).
Exercise Question:
1. Which of the statements about the reaction below are incorrect?
2PbO(s) + C(s) → 2Pb(s) + CO2(g)
a) Lead is getting reduced
b) Carbon Dioxide is getting oxidised
c) Carbon is getting oxidised
d) Lead oxide is getting reduced
i) (a) and (b)
ii) (a) and (c)
iii) (a), (b) and (c)
iv) all the above
Solution:
(i) (a) and (b)
Explanation: (a) Because Oxygen is being removed and (b) Because the removed oxygen from
Lead is added to the elemental Carbon.
Solution:
4. Displacement reaction.
Explanation: The Oxygen from the Ferrous oxide is getting displaced to the Aluminium metal to
form Aluminium Oxide. In this reaction, Aluminum is a more reactive metal than Fe. Therefore,
Al will displace Fe from its oxide. This type of chemical reaction, called displacement reaction, is
in which one of the elements displaces another. Here, less reactive metal is displaced by more
reactive metal. Since one-time displacement is occurring, it is called a single displacement
reaction.
3. What happens when dilute hydrochloric acid is added to iron fillings? Tick the correct
answer.
1. Hydrogen gas and Iron chloride are produced.
2. Chlorine gas and Iron hydroxide are produced.
3. No reaction takes place.
4. Iron salt and water are produced.
Solution:
1. Hydrogen gas and Iron chloride are produced.
Explanation: The Chlorine from Hydrogen chloride is displaced by the Iron fillings to undergo
the following reaction.
2HCl + Fe → FeCl2 + H2
5. Translate the following statements into chemical equations and balance them.
a) Hydrogen gas combines with nitrogen to form ammonia.
b) Hydrogen sulphide gas burns in the air to give water and sulphur dioxide.
c) Barium chloride reacts with aluminium sulphate to give Aluminium chloride and a
precipitate of barium sulphate.
d) Potassium metal reacts with water to give potassium hydroxide and Hydrogen gas.
Solution:
(a) Unbalanced: H2 + N2 → NH3
Balanced: 3H2 + N2 → 2NH3
(b) Unbalanced: H2S + O2 → H2O + SO2
Balanced: 2H2S + 3O2 → 2H2O + 2SO2
(c) Unbalanced:
BaCl2 + Al2(SO4)3 → AlCl3 + BaSO4
Balanced: 3BaCl2 + Al2(SO4)3 → 2AlCl3 + 3BaSO4
(d) Unbalanced: K + H2O → KOH + H2
Balanced: 2K + 2H2O → 2KOH + H2
7. Write the balanced chemical equation for the following reactions. Calcium hydroxide +
Carbon dioxide → Calcium carbonate + Water
Zinc + Silver nitrate → Zinc nitrate + Silver
Aluminium + Copper chloride → Aluminium chloride + Copper
Barium chloride + Potassium sulphate → Barium sulphate + Potassium chloride Solution:
2Ca(OH)2 + 2CO2 → 2CaCO3 + 2H2O
Zn + 2AgNO3 → Zn(NO3)2 + 2Ag
2Al + 3CuCl2 → 2AlCl3 + 3Cu
BaCl2 + K2SO4 → BaSO4 + 2KCl
8. Write a balanced chemical equation for the following and identify the type of reaction of
each case. KBr + BaI2 → KI + BaBr2
ZnCO3 → ZnO + CO2
H2 + Cl → HCl
Mg + HCl → MgCl2 + H2
Solution:
2KBr + BaI2 → 2KI + BaBr2 (Double Displacement Reaction)
ZnCO3 → ZnO + CO2 (Decomposition Reaction)
H2 + Cl → 2HCl (Combination Reaction)
Mg + 2HCl → MgCl2 + H2 (Displacement Reaction)
In most cases, the decomposition reaction is endothermic since the heat from the surrounding or
induced heat is used to break the bonds of the larger molecule. A few examples of decomposition
reactions are
ZnCO3 → ZnO + CO2
CaCO3 + Energy → CaO + CO2
2HgO → 2Hg + O2
12. Write one equation each for decomposition reactions in which energy is supplied in the
form of heat, light or electricity.
Solution:
(a) Thermal decomposition reaction (Thermolysis)
Decomposition of potassium chlorate: When heated strongly, potassium chlorate decomposes into
potassium chloride and oxygen. This reaction is used for the preparation of oxygen.
2KClO3 + Heat → 2KCl + 3O2
13. What is the difference between displacement and double displacement reactions? Write
relevant equations for the above.
Solution:
A displacement reaction is one when a more reactive substance displaces a less reactive one from
its salt solution, whereas a double displacement reaction is one where a mutual exchange of ions
happens between two compounds.
In a displacement reaction, only a single displacement takes place, whereas in the double
displacement reaction, as the name suggests, two displacement takes place between the molecules.
Example:
Displacement reaction
Mg + 2HCl → MgCl2 + H2
Double displacement reaction
2KBr + BaI2 → 2KI + BaBr2
14. In the refining of Silver, the recovery of silver from Silver nitrate solution involves
displacement reaction by Copper metal. Write down the reaction involved.
Solution:
Cu(s) + 2AgNO3(aq) → Cu(NO3)2(aq) + 2Ag(s)
16. Explain the following in terms of the gain of oxygen with two examples each.
a) Oxidation
b) Reduction
Solution:
(a) In a chemical reaction, when the oxygen is added to the element to form its respective oxide it
is the element being oxidised. Example:
4Na(s) + O2(g) → 2Na2O(s)
H2S + O2 → H2O + SO2
(b) In a chemical reaction, when the oxygen is removed from the compound, then it is said to be
reduced. Example:
CuO(s) + H2(g) → Cu(s) + H2O(l)
2HgO → 2Hg + O2
17. A shiny brown coloured element ‘X’ on heating in the air becomes black in colour. Name
the element ‘X’ and the black-coloured compound formed.
Solution:
The shiny brown-coloured element is Copper metal (Cu). When the metal is heated in air, it reacts
with atmospheric oxygen to form copper oxide. Hence, the black-coloured compound is copper
oxide.
2Cu(s) + O2(g) → 2CuO(s)
19. Oil and Fat containing food items are flushed with Nitrogen. Why?
Solution:
The main purpose of flushing Nitrogen into food packets that contain oil and fat items is to prevent
Rancidity which occurs when the oil or fat reacts with the oxygen letting out an unpleasant smell
and taste. Therefore, by flushing Nitrogen, an unreactive surrounding is created, thus preventing
rancidity.
3. PbS reacts with ozone (O3) and forms pbso4. As per the balanced equation, molecules of
ozone required for every one molecule of PbS is / are
a) 4
b) 3
c) 2
d) 1
Ans. (a) 4
4. Chemically rust is
a) Hydrated ferrous oxide
b) hydrated ferric oxide
c) only ferric oxide
d) none of these
Ans. (b) hydrated ferric oxide
6. Copper displaces which of the following metals from its salt solution:
a) ZnSO 4
b) FeSO 4
c) AgNO 3
d) NiSO 4
Ans. (c) AgNO3
11. Take about 5 ml of dil. HCl in a test tube and add a few pieces of fine Zn granules to
it. Which gas is evolved?
a) Chlorine
b) Hydrogen
c) HCl
d) Nitrogen
Ans. (b) Hydrogen
15. The reaction between lead nitrate and potassium iodide present in aqueous
solutions is an example of
a) Decomposition Reaction
b) Displacement Reaction
c) Double Displacement Reaction
d) Neutralisation Reaction
Ans. (c) Double Displacement Reaction
16. What happens when dilute hydrochloric acid is added to iron filling? Tick the
correct answer
2 Marks Questions
1. Identify the type of chemical reaction
(i) A→B+C
(ii) AD + CD → AD +CB
Ans. (i) Decomposition reaction
(ii) Double displacement reaction
2. Why does not silver evolve hydrogen on reacting with dil H2So4?
Ans. Silver do not evolve hydrogen on reacting with dil. H 2SO 4 as silver is less
reactive metal than hydrogen.
3. Way do diamond and graphite, the two allotropic forms of carbon evolve
different amounts of heat on combustion?
Ans. Diamond and graphite are the two allotropes of carbon but they do not evolve
same amount of heat on combustion because they differ in the arrangement of carbon
atoms and also their shapes one different.
8. What happens to lime water when Co2 gas is bubbled through it in excess?
Ans. When CO 2 gas is bubbled through lime water in excess then initially it
becomes milky but then its milkiness disappears.
13. A student took 2-3 g of a substance X in a glass beaker & poured water over it slowly.
He observed bubbles along with hissing noise. The beaker becomes quite hot. Identify X.
What type of reaction is it?
Ans. X = Calcium oxide (Quick lime), Combination reaction.
14. A substance X used for coating iron articles is added to a blue solution of
a reddish brown metal Y,the color of the solution gets discharged Identify X
and Y & also the type of reaction.
Ans. X= Fe, Y = Cu, Displacement reaction.
15. A student burnt a metal A found in the form of ribbon. The ribbon burnt with a
dazzling Flame & a white powder B is formed which is basic in nature. Identify A &
B. Write the Balanced chemical equation.
Ans. X = Mg, Y = MgO, Mg + O 2 → 2MgO
17. Write the balanced chemical equation with state symbols for the following
reactions?
Ans. Balance chemical reaction with state symbols are as follows-
(i) BaCl2(aq) + Na2 SO4 (aq) → BaSO 4 (s) + 2NaCl (aq)
(ii) NaOH (aq) + HCl (aq) → NaCl (aq) + H2O
19. Which of the following statement about the reaction below are incorrect?
2PbO (s) + C (s) → 2Pb (s) + CO2 (g)
a) Lead is getting reduced.
b) Carbon dioxide is getting oxidized
c) Lead oxide is getting oxidized
d) Lead is getting reduced
(i) (a) and (b)
(ii) (a) and (c)
(iii) (a), (b) and (c)
(iv) All
Ans. As statement (a) and (b) are incorrect, answer (i) is correct.
20. In refining of silver, the recovery of silver from silver nitrate solution involved
displacement by copper metal. Write down the reaction involved.
Ans. The reaction involved is: Cu(s) + 2AgNO 3(aq) → Cu(NO 3)2(aq) + 2Ag(s)
22. A shiny brown coloured element ‘X’ on heating in air becomes black in colour. Name
the element ‘X’ and the black coloured compound formed.
Ans. The brown coloured element ‘X‘ is copper. On heating in air it forms
copper oxide, which is black in colour.
2CuS + O 2 → 2CuO
24. Oil and fat containing food items are flushed with nitrogen. Why?
Ans. Oil and fat containing items get rancid due to oxidation with atmospheric
oxygen. To prevent rancidity food items are flushed with nitrogen. Nitrogen do not
reacts with oil and fat containing items.
3.Marks Questions
1. (a) Define Rusting
(b) Why do you apply paint an iron article?
Ans. (a) The process of slow eating of the surface of metal iron when exposed to air
for a longer period of time is called rusting.
(b) We apply paint on iron articles because it forms a protective coating on the
surface of iron and we can protect it against rusting.
4. What are neutralization reactions? Why are they named so? Give one example?
Ans. A neutralization reaction is the chemical reaction between an acid and base
dissolved in water
For eg →KOH(aq) + NHO3(aq) → KNO3(aq) + H2O(aq)
It is called neutralization reaction because both KNO 3 and H2O formed as the products, are
neutral in nature.
10. When you mix solutions of lead (II) nitrate and potassium iodide,
(i) What is the colour of the precipitate formed? Name the compound evolved?
(ii) Write a balanced chemical reaction?
(iii) Is this a double displacement reaction?
Ans. (i) The precipitate is yellow in colour and the compound is lead (II) Iodide.
(ii) Pb(NO 3 ) 2 (aq) + 2kI(aq) → PbI 2 (s) + 2KNO 3 (aq)
(iii) Yes it is a double displacement reaction.
11. Transfer the following into chemical equations and balance them.
(i) Hydrogen gas combines with nitrogen to from ammonia.
(ii) Hydrogen sulphide gas burns in air to give water and sulphurdioxide.
(iii) Potassium metal reacts with water to give potassium hydroxide and hydrogen
gas.
14. An aqueous solution of metal nitrate P reacts with sodium bromide solution to
form yellow ppt of compound Q which is used in photography. Q on exposure to
sunlight undergoes decomposition reaction to form metal present in P along with
reddish brown gas. Identify P &Q. Write the chemical reaction & type of chemical
reaction.
Ans: P = Ag NO 3, Q = AgBr 2AgBr (s) → 2Ag(S) + Br2(g)
,
Photochemical decomposition.
15. Bhawana took a pale green substance A in a test tube. And heated it over the
flame of a burner. A brown colored residue B was formed along with evolution of
two gases with burning smell of sulphur. Identify A & B. Write the chemical
reaction involved.
Ans: 2FeSO 4(s) Heart Fe2O 3(s) + SO 2(g) + SO 3(g)
A(green) B(brown)
16. A reddish brown vessel developed a green colored solid X When left open in air for a
long time. When reacted with dil H2SO4 , it forms a blue colored solution along with brisk
efficient due to colourless & odourless gas Z. X decomposes to form black colored oxide Y
of a reddish brown metal along with gas Z, Identify X, Y, & Z.
Ans:
X = CuCo3 Cu(OH), Y = CuO, Z = CO2
17. A student has mixed the solutions of lead (II) nitrate and potassium iodide.
(a) What was the colour of the precipitate formed? Can you name the compound?
(b) Write the balanced chemical equation for this reaction.
(c) What type of reaction is it?
Ans. (i) Yellow, Lead iodide
(ii) Pb(NO3)2 +Kl → Pbl2 +2KNO3
(iii) Double displacement reaction
18. Name the type of reaction seen in the diagram below. Write the reaction for the
Same.
Ans. Displacement Reaction
Fe(s) + CuSO 4 → FeSO 4aq + Cu
Oxygen and is being oxidized.
19. A student dropped few pieces of marble in dilute HCI contained in a test tube.
The gas evolved was passed through lime water. What change would be observed in
lime water? Write chemical reactions for both the changes observed.
Ans.
Ca (OH) 2(aq) + CO 2 (g) → CaCO 3(s) + H 2O(l)
Ca(OH) 2(aq) + CO 2(g) → CaCO 3(s) + H 2O(l)
(Calcium (Calcium
Hydroxide) carbonate)
20. Astha has been collecting silver coins and copper coins. One day she observed a black
Coating on silver coins and a green coating on conner coins. Which chemical phenomenon is
responsible for these coatings? Write the chemical name of black and green coatings?
Ans. Corrosion is responsible for this coating. Black coating is due to formation of
Ag2 S And green coating is due to formation of CuCO 3, Cu (OH) 2
21. Write the balance equation for the following reactions Give reasons for the following
reactions?
i. Hydrogen + Chlorine → Hydrogen chloride
ii. Barium chloride + Aluminium sulphate → Barium sulphate + Aluminium
chloride
iii. Sodium + water → Sodium hydroxide + water
5 Marks Questions
1. You are given with
a) Iron Nails
b) CuSO4 solution
c) Bacl2
d) Cu powder
e) Ferrous sulphate crystal
f) Quick lime.
Make five reactions that can take place from these materials.
Ans: (i) BaCl2(aq) + CuSO4(aq) → BaSO4(aq) + CuCl2(aq)
(ii) 2Cu(s) + O2(g) → 2CuO(s)
(iii) 2FeSO 4(s) heat Fe2O3 + SO 2 + SO 3
(iv) FeSO 4-7H2O heat Fe2SO3(s) + 7H 2O
(v) CaO(s) + H 2O → Ca(OH)2(s) + Heat
2. A metal is heated with dil. H2SO4. The gas evolved is collected by the method shown
in the figure: Answer the following
3. With the help of an activity show that iron is more reactive than copper?
Ans. First take some aqueous solution of Cuso 4 (blue is colour) and dip iron nails
into it leave for half an hour the blue colour of the solution changes into light green.
At the same time brown deposit appears on the nails. This happens because iron is
placed above copper in reactivity series hence it displaces copper from cuso 4
solution. The brown deposit is of copper.
i.e. Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s)
The copper (II) ovide is losing oxygen and is being reduced. The hydrogen is
gaining
6. Why does the colour of copper sulphate solution change when an iron nail is
dipped in it?
Ans. When iron nail is dipped in copper sulphate solution, than iron sulphate
solution and copper solution and copper metal are formed:
CuSO4 (aq) + Fe (s) → FeSO4 (aq) + Cu (s)
In this reaction, iron displaces copper from copper sulphate solution. The deep blue
colour of copper sulphate fades due to the formation of light green solution of iron
sulphate.
7. Identify the substances that are oxidized and the substances that are reduced in
the following reactions.
(i) 4Na (s) + O2 (g) 2Na2O (s)
(ii) CuO (s) + H2 → Cu (s) + H2O (l)
Ans. (i) 4Na + O 2 → 2Na2O
In this reaction, Na is oxidized because it combines with O 2 to form Na 2O. O 2
is reduced because it is converted into Na 2O.
(ii) CuO + H 2 → Cu + H2O
In this reaction, CuO is reduced because it loses oxygen. H 2 is oxidized because
it combines with oxygen of CuO to form water
8. Translate the following statements into chemical equations and then balance them.
(a) Hydrogen gas combines with nitrogen to form ammonia.
(b) Hydrogen sulphide gas burns in air to give water and Sulpher dioxide.
(c) Barium chloride reacts with aluminum sulphate to give aluminum chloride
and precipitate of barium sulphate
Ans. (a) H 2 +N2 → NH3
3H 2 +N2 → 2NH3
(d) K + H 2O → KOH + H 2
2K + 2H 2O → 2KOH + H 2
10. Write the balanced chemical equations for the following reactions.
a) Calcium hydroxide + Carbon dioxide → Calcium carbonate + Water
b) Zinc + Silver nitrate → Zinc nitrate + Silver
c) Aluminum + Copper chloride → Aluminum chloride +Copper
d) Barium chloride + Potassium sulphate → Barium sulphate + potassium chloride
Ans. Balanced chemical equation for reactions are
(a) Ca(OH)2 + CO2 → CaCO 3 + H2O
(b) Zn + 2AgNO 3 → Zn(NO 3)2 +2Ag
(c) 2Al + 3Cl2 → 2AlCl3 + 3Cu
(d) BaCl2 + K2SO4 → BaSO 4 + 2KCl
11. Write the balanced chemical equation for the following and identify the type of
reaction in each case.
a) Potassium bromide (s) + Barium iodide (aq) → Potassium iodide (aq) + Barium
bromide(s)
b) Zinc carbonate (s) → Zinc oxide (s) + Carbon dioxide (g)
c) Hydrogen (g) + Chlorine (g) → Hydrogen chloride (g)
d) Magnesium (s) + Hydrochloric acid (aq) → Magnesium chloride (aq) + Hydrogen
(g)
12. What does one mean by exothermic and endothermic reactions? Give examples.
Ans. A reaction in which energy is released in the form of heat or light is called
exothermic reaction. Example of exothermic reaction are:
CH4 + 2O 2 → CO2 + 2H2O + heat
2Al + FeO 3 → Al2O 3 + Fe + heat
A reaction in which energy is absorbed from the surrounding and cooling is
produced is called endothermic reaction. Example of exothermic reaction are:
(a) CaCO 3 → CaO + CO2
(b) N2 + O 2 → 2NO
14. Write one equation each for decomposition reactions where energy is supplied
in the form of heat, light or electricity.
Ans. Decomposition by heat:
CaCO 3(S) + heat → CaO (s) + CO 2 (g)
Decomposition by electricity:
2H2O + light → 2H2 (g) + O2 (g)
Decomposition by light:
2AgBr (s) + light → 2Ag (s) + Br2
16. Explain the following in terms of gain and loss of oxygen with two examples
each?
a) Oxidation
b) Reduction
Ans. Oxidation- addition of oxygen or removal of hydrogen in a chemical reaction
is called oxidation reaction. For example
2Cu +O 2 → 2CuO
4Al + 3O 2 → 2Al2O3
Reduction- addition of hydrogen or removal of oxygen in a chemical reaction is
called oxidation reaction. For example
CuO +H 2 → Cu +H2O
H2S + Cl2 → 2HCl +S
2. Assertion (A) : When HCl is added to zinc granules, a chemical reaction occurs.
Reason (R) : Evolution of a gas and change in colour indicate that the chemical reaction is taking
place.
Ans: b
3. Assertion (A) : Calcium carbonate when heated gives calcium oxide and water.
Reason (R) : On heating calcium carbonate, decomposition reaction takes place.
Ans: d
4. Assertion (A) : Brown fumes are produced when lead nitrate is heated.
Reason (R) : Nitrogen dioxide gas is produced as a byproduct due to the decomposition of lead
nitrate.
Ans: a
6. Assertion (A): Pungent smelling gas is produced when sulphur burns in air.
Reason (R) : Sulphur trioxide is formed on reaction of sulphur with oxygen.
Ans: c
7. Assertion (A) : In a reaction of copper with oxygen, copper serves as a reducing agent.
Reason (R) : The substance which gains oxygen in a chemical reaction acts as a reducing agent.
Ans: a
8. Assertion (A) : In electrolysis of water, the volume of hydrogen liberated is twice the volume
of oxygen formed.
Reason (R) : Water (H,0) has hydrogen and oxygen in the ratio of 1:2 by volume.
Ans: c
10. Assertion (A) : The balancing of chemical equations is based on law of conservation of mass.
Reason (R) : Total mass of reactants is equal to total mass of products.
Ans: a
11. Assertion (A): In a balanced chemical equation, total mass of the reactants is equal to the total
mass of the products.
Reason (R): Mass can neither be created nor destroyed during a chemical change.
Ans: a
12. Assertion (A): Iron articles are painted so as to prevent them from rusting.
Reason (R): When the surface of iron is coated with paint, its surface does not come in contact
with oxygen and moisture therefore rusting does not take place.
Ans: a
13. Assertion (A) : Chemical reaction changes the physical and chemical state of a substance.
Reason (R) : When electric current is passed through water (liquid), it decomposes to produce
hydrogen and
oxygen gases.
Ans: b
14. Assertion (A): When calcium carbonate is heated, it decomposes to give calcium oxide and
carbon dioxide.
Reason (R): The decomposition reaction takes place on application of heat, therefore, it is an
endothermic reaction.
Ans: b
15. Assertion (A): Zinc reacts with sulphuric acid to form zinc sulphate and hydrogen gas and it is
a displacement reaction.
Reason (R): Zinc reacts with oxygen to form zinc oxide
Ans: b
16. Assertion (A): Chips manufacturers usually Ilush bags of chips with gas such as nitrogen to
prevent the chips from getting oxidised.
Reason (R): This increases the taste of the chips and helps in their digestion.
Ans: c
17. Assertion (A): Exposure of silver chloride to sunlight for a long duration turns grey due to the
formation of silver by decomposition of silver chloride.
Reason (R): In this process, sublimation of silver chloride takes place.
Ans: c
18. Assertion (A): Rusting of iron metal is the most common form of corrosion.
Reason (R): The effect of rusting of iron can be reversed if they are left open in sunlight.
Ans: c
21. Assertion (A): A lead nitrate on thermal decomposition gives lead oxide, brown coloured
nitrogen dioxide and oxygen gas.
Reason (R): Lead nitrate reacts with potassium iodide to form yellow ppt. of lead iodide and the
reaction is double displacement as well as precipitation reaction.
Ans: b