Le Chatelier's

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Le Chatelier’s Principle

“Equilibrium" refers to a state in which the rates of the forward and reverse reactions of a
reversible chemical reaction are equal, resulting in no net change in the concentrations of
reactants and products over time. At equilibrium, the system is said to be in a dynamic
state, with molecules constantly moving between reactants and products, but the overall
concentrations of the reactants and products remain constant. Le Chatelier's Principle is
a fundamental concept in chemistry that predicts the e ect of changes in temperature,
pressure, concentration, and other factors on a chemical system at equilibrium. In
summary, the principle states:

When a system at equilibrium is subjected to a stress or change, the system will adjust to
counteract the stress and restore equilibrium.

The principle is widely used in chemistry to explain and predict how chemical reactions
respond to changes in their environment. This can include a change in concentration,
temperature and pressure. For example, if the concentration of one reactant in a reaction
at equilibrium is increased, the system will shift to favor the production of the products in
order to counteract the increase in concentration of the reactant. Similarly, if the
temperature of the system is increased, the system will shift in a direction that absorbs
heat to counteract the temperature increase.

The following table summarises the e ects of changes in temperature, pressure, and
concentration on chemical equilibria, based on Le Chatelier's Principle:

Change E ect on Equilibrium


Temperature increase Endothermic reaction is favoured as this reaction takes in
more heat and reduces temperature.
Temperature decrease Exothermic reaction is favoured as this reaction released more
heat to increase temperature.
Pressure increase Reaction shifts to the side with fewer molecules as this
reaction reduces the number of molecules present and thus
reduces pressure. (NOTE: Look at balancing numbers to
determine number of molecules.)
Pressure decrease Reaction shifts to the side with more molecules as this
reaction increases the number of molecules present and thus
increases pressure.
Concentration increase Reaction shifts to the side that consumes the added species;
reaction shifts away from the side of the added species.
Concentration decrease Reaction shifts to the side that produces the removed species;
reaction shifts towards the side of the removed species.
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