Chemical Bonding DTS-1

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Date Planned : __ / __ / __ Daily Tutorial Sheet - 1 Expected Duration : 90 Min

Actual Date of Attempt : __ / __ / __ Level - 1 Exact Duration :_________

1. The octet rule is not obeyed in :

(A) CO2 (B) Zn 2  (C) SiCl4 (D) CO

2. Which of the following compounds is expected to be the most ionic?


(A) PbCl2 (B) PbCl 4 (C) CCl 4 (D) SiCl4

3. Which of the following pairs can form a compound with the maximum ionic character ?
(A) Na and Cl (B) Cs and F (C) Cs and I (D) Na and F

4. Which of the following molecules is formed without following the octet rule ?
(A) BeCl2 (B) IF7 (C) SF6 (D) All of these

5. During the formation of an ionic bond, the cation may achieve :

(A) ns2 or ns2 np6 configuration (B) pseudo noble – gas – configuration
(C) inert-pair configuration (D) All of these configurations

6. A pure covalent bond is formed between :


(A) An electronegative element and an electropositive element
(B) An electronegative element and an electronegative element
(C) An electropositive element and an electropositive element
(D) None of these

7. In H3O  the formal charge on the oxygen atom is :

(A) +1 (B) 1 (C) zero (D) +2

8. Which combination will give the strongest ionic bond?

(A) K  and Cl  (B) K  and O2 (C) Ca 2 and Cl  (D) Ca 2  and O2

9. Mg 2 O2  is formed since : [IE = Ionization energy, EA = Electron affinity]


(A) IE of Mg is low (B) EA of O is low
(C) IE of Mg is high (D) IE of O is low

10. Select the correct statement.


(A) Both lattice energy and hydration energy decrease with ionic size
(B) Lattice energy can be calculated using Born-Haber cycle
(C) If the cation is large compared to the anion, the lattice energy will remain almost constant within
a particular group
(D) All of the above are correct statements

11. Which of the following compounds has both ionic and covalent bonding?
(A) NaBr (B) Ba(CN)2 (C) PCl5 (D) CH3CH2OH

12. The formal charge on the O atoms in the ion :O ɺɺ   is:
ɺɺ  N  O:
 
(A) 2 (B) 1 (C) 0 (D) +1

DTS - 1 88 Level - 1 | Chemical Bonding – I & II


*13. MgSO4 is soluble while BaSO4 is insoluble in H2O. This is because :
(A) Lattice energy of BaSO4 is greater than MgSO4
(B) BaSO4 is more covalent than MgSO4
2+ 2+
(C) Hydration energy of Mg is greater than Ba
(D) Lattice energy of MgSO4 is greater than BaSO4

14. In terms of polar character, which one of the following order is correct?
(A) NH3 < H2O < HF < H2S (B) H2S < NH3 < H2O < HF
(C) H2O < NH3 < H2S < HF (D) HF < H2O < NH3 < H2S

15. Correct Lewis structure is:

(A) (B)

(C)
(D)

DTS - 1 89 Level - 1 | Chemical Bonding – I & II

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