Adobe Scan 20-Jul-2023
Adobe Scan 20-Jul-2023
Adobe Scan 20-Jul-2023
Level
Introductory Questions
1. The combination of atoms take place so that:
(a) They can gain two electrons in the outermost shell
(b) They get eight electrons in the outermost shell
(c) They acquire stability by lowering of energy
(d) They get eighteen electrons in the outermost shell.
Lewis Dot Structure
2. N,0 has a linear, unsymmetrical structure that may be thought of as a
hybrid oftwo resonance
forms. If a resonance form must have a satisfactory Lewis structure, which twO of the five
structures shown below are the two resonance forms of N0?
+
(a) :N=N=0: (b) :N=N=0: (c) :N=G Ô:
3. Which of the following molecular species/compound is not
(d) :N=N=-0:
(a) CH; hypovalnt ?
(b) B,H6 (c) NH; \(0 AlF,
4. N,CO has three possible structures ;
ONCN (nitrosyl cyanide), ONNC (nitrosyl isocyanide) NOCN (isonitrosyl cyanide).
Which of the following structure has lowest potential energy?
(a) ONCN (b) ONNC
(c) NOCN (d) All have same energy
5. Which of the following statement is correct for NO, ion ?
(a) Sum of all formal charges =+1
(b) Formal charge on one of the oxygen atom =-2
YFormal charge on nitrogen atom =+1
1
(a) Average formnal charge on oxygen atom 3
INORGANIC CHEMISTRY
68
incorrect ?
Which of the following Lewis dot structure of CO, is (d) None of these
6. (c) :0C Q:
(a) :0C=0: LcQ-C-ö: bond pairs around central atom is
zreater than
structure the number of
7. According to Lewis dotfollowing anion
four for which of the () PO o None
(b) NO,
(a) CO
lonic Bond
of electricity because :
8. Solid NaCl is a bad conductor ions
(a) in solid NaCI there are no
(b) solid NaCl is covalent
of ions
in solid NaCl there is no mobility
d) in solid NaCl there are no electrons
likely to be formed when :
9. An ionic compound AB is most electron affinity of B is low
(a) the ionization energy of A high and affinity of B is high
the ionization energy of Ais low and electron
electron affinity of B are high
(c) both, the ionization energy of A and affinity ofBare low
(d) both, the ionization energy of Aand electron
the oxidation of A =+2, B=+5and
10. Acompound contains three elements A, B and C, if
C=-2, the possible formula of the compound is :
(b) Az(BC4)2 (c) A,(BC,)2 (d) ABCz
(a) A,(B4,C)2
11. Which pair of atoms form strongest ionic bond?
(a) Al and As (b) Al and N
(c) Al and Se 1dY Al and O
12. In which of the following species the bonds are non-directional ?
(a) NCI, (byRbCI (c) BeCl, (d) BCl,
13. A bond formed between two like atoms cannot be :
| ionic (b) covalent (c) coordinate (d) metallic
14. An electrovalent compound does not exhibit space isomerism because of :
(a) Presence of oppositively charged ions (b) High melting points
(c) Non-directional nature of the bond (d) Crystalline nature
15. Two elements Aand Bhave following electronic configuration.
A=1s2s2p632 V=2 2 t3=
B=1s25'2p 3s?3p v=5
If expected compound formed by A and B is A,B, then sum of x and y is :
(a) 2 (b) 3 (c) 4
Lottice Energy
16. The lattice energies of KE KCI, KBr and KI follow the order :
\ KE > KCl > KBr > KI (b) KI> KBr > KCl> KF
(c) KF KCl>KI> KBr (d) KI> KBr > KF> KC1
17. Which set of compounds in the following pair of ionic
energy? compounds has the higher latt
HEMICALBONDING(Bascl)
69
Mgo (ii) LiF or LiBr
(i) KCIor (iii) Mg N, or NaCl
(a) KCI, LiBI,NaCI
Mg,N2 (b) MgO, LiBr, Mg ,N2
Li
(c) MgO, Mgo, LiF, Mg,N 2
Theincorrect order of lattice energy is :
18. MgF,
(a) AlF3 > LiF (b) Li,N >li,0
(c) NaCl> (d) TiC> ScN
Whichjonic compound has the largest amount of lattice energy?
19. NaF (b) AlF3 (c) AIN (d) MgF
The order of increasing lattice energy of the following salt is:
20. CaO < NaBr < BaO
(a) NaCI < \ NaBr < NaCl < BaO < CaO
o) NaCI < NaBr < BaO CaO (d) NaBr < NaCl < CaO < BaO
Which combination will give strongest ionic bond ?
21-
(a) Na and Cl (b) Mg and CI
(c) Nat and 02 and 2
mong the following isostructural compounds, identifythe compound, which has the highest
lattice energy :
(a) LiF (b) LiC1 (c) NaCI
23. In which of the following ionic compounds, AH, is negative only due to lattice energy ?
() NaF (ii) MgO (ii) Li,N (iv) Na,S
(a) Only (iv) (b) Only (iii), (iv)
(e Only ii), (ii), (iv) (d) All of these
94. Select the correct reason for given statement Flouride of Al is ionic while chloride of Al is
covalent".
(a) IE of Al in AlF3> AlCl (b) EA of Flourine> Chlorine
1(er Lattice energy of AIFz > AlCl, (d) EA of Flourine < Chlorine
Covalent Bond
25. Which pair of elements can form multiple bond with itself and oxygen?
(a) FN (b) N, CI (c) N, P (d) N, C
26. Which of the following is a covalent compound?
(a) Al,03 (b) AlF3 (d) Al,(SO4)3
27. Which of the following is an example of super octet molecule?
(a) ClF'3 (b) PCls (c) IF, All the three
atom
70
exactlv
INORGANIC CHEMISTG
central atom is NOT surrounded by 8
33. In which of the following species
electrons?
(c) PCI
valene
(a) BF, (b) NCI,
electrons when it is forming covalent bona.
34. Which atom can have more than eight valence
(a) H (b) N (c) F
35. Whieh bond is expected to be the least polar?
(b) PF (c) Si-N (d) B-F
36. Which set contains only covalently bonded molecules?
La BCl3, SiCl4, PCl, (b) NHBr, N
,H4, HBr
(c) Ih, H,S, Nal (d) Al, O3, As4
37. Which molecule does not exist?
(a) OF2 OF, (c) SF2 (d) SF4
38. Which of the following does not contain any coordinate bond ?
(a) NH,Cl (b) Na BF4] (c) H,0* () CO
39. A : tetracyanomethane B: carbondioxide
C: benzene D: 1,3-buta-di-ene
Ratio of oand bonds is in order:
(a) A =B<C<D (b). A=B<D<C
(c) A =B =C=D (d) C<D<A< B
40. In a compound
NC
NC C=c M(CO),
C,Hs
the number of sigma and pi bonds respectively are :
(a) 19, 11 (b) 19, 5 (c) 13, 11 (d) 7, 3
41. Which of the following dÍes not contain any co-ordinate bond?
ká) H,0* Le) BF; (c) HF,
42. Which of the following molecules does not have co-ordinate bonds?
(a) PH Weehenis
(b) NO2
43. Which of the following bonds have
(c) O3
(a) C-C
lowest bond energy?
(b) N-N (c) H-H
44. The bond having the minimum bond
(a) C-C energy is :
(c) S s (d) P P
Valence Bond Theory
45. The fluorine molecules is formed by:
(a) p-p orbitals (sideways overlap) b p-p orbitals
(c) sp-sp orbitals (d) s-s orbitals
(end-to-end overlap)
46. Which of the following leads to bonding?
S-orbital p-orbital S-orbital p-orbital p-orbital p-orbital
(a) (c) (d)
CHEMICAL BONDING (Basic)
Hybridisation
sp and sp-hybridised carbon atoms are present respectively in the following
77. How many
y compound ?
H
ee H
H
ee
H
(d) 5, 1
(c) 3, 3
(b) 6, 0 and
(a4, 2one of the following is the correct set with respect to molecule, hybridization
n
78. Which
planar
shape? (b) BeCl,, sp", triangular
(a)BeCl,, sp", linear (d) BCls, sp
,tetrahedral
d e BCI, sp, triangular planar
74
9. The hybridization of
the central atom in ICI 2 1s :
(c) sp
INORGANICRElN
(a) dsp? (b) sp in the othere.
of the central atom is not the same as
O 1ne tate of
hybridization
(c) N in NH, (d) P in PCI,
Bin BF, SP H,0*
(b) O in
benzene are :
81. The number of sp s sigma bonds in
(c) 12 (d) none of these
(a) 3
change when
82, The hybridization of the central atom will
(a) NH, combines with Ht (b) HB0, combines with OH
(c) NH, forms NH2 (d) H,Ocombines with Ht
83. CH,-CH,-CH=CH, has hybridisation: Sp
(a) sp, sp, sp", sp (b) sp
osp°,sp,sp, sp (d) sp Sp, sp Sp
84. What is the state of hybridjsation of Xe in cationic part of solid XeF,?
(a) sp°a (c) sp'd (d) sp
85. During the complete combustion of methane CH4, what change in hybridisation dow
carbÍn atom undergo?
13 sp to sp (b) sp to sp (c) sp to sp (d) sp to sp
86. The bybridisation of central iodine atom in IFs, I; and I; are
respectively :
o sp°d², sp°d, sp (b) sp°d, sp°d, sp³ () sp°, sp°d, sp (d)
87. In which of the following combination spd, sp°d
hybridisation of central atomn (") does not change
(a) H,0+o, (b) H, BO+OH (c) BF, + NH,
88. Which of the following species (d) None of these
used both axial set of d-orbitals in
atom?
hybridisation of centra
(a) PBr (b) PCI,
89. Which bonds are formed by a (c) ICl, (d) None of these
carbon atom with
(a) 4n-bonds
1(Y ln-bonds and 3o-bonds
sp-hybridisation?
(b) 2-bonds and
90. What are the (d) 46-bonds
26-bonds
hybridisation of the carbon atoms labeled C, and C,
(a) sp
sp
respectively in glycne
H H
(b) sp sp3
(d) sp
H-N-C
H
91. The H-0-H
these bonds arebond angles in Ha0* are
(a) p-orbitals
best described as : approximately 107°, The orbitals used by oxy8
(c) sp-hybrid orbital (b) sp-hybrid orbitals
Le sp°-hybrid orbital
EMISTRY CHEMICALBONDING (Basic) 75
Molecular Geometry/Shape
isostructural pairs :
o2. Among given species identify the
(a) [NFzand BF3] 1 (BE,and NH] (c) [BCl,and BrCl,J (d) [NH3 and NO3]
ng 001 mole of H,PO, is completely neutralised by 0.56 gram of KOH hence :
e (a) x =3 and given acid is dibasic
(b) X=2 and given acid is monobasic
(c) x=3 and given acid is monobasic
(d) x=4 and given acid forms three series of salt
exists as :
94. Phosphorus pentachloride in the solid
(a) PCl, (b) PCI}CI (c) PCIPCI; (d) PCl,Cl,
O5. The ratio of o-bond and r-bond in tetracyano ethylene is : (d) None of these
(a) 2:1 (b) 1:1 (c) 1:2
96. Bonds present in N,Os (nitrogen pentaoxide) are :
(a) only ionic (b) only covalent
covalent and co-ordinate (d) covalent and ionic
(c)
s the
97. The pair of species with similar shape is :
1aPCl,, NH, (b) CF4,SF4 (c) PbCl,,CO2 (d) PFs,Fs
allene molecule, CH?
98. Which of the following statements is correct in the context of the
(a) The central carbon is sp hybridized
sp (b) The terminal carbon atoms are sp hybridized
perpendicular to pemit the
Be? (c) The planes containing the CH, groups are mutually
formations two separate -bonds
(d) All are correct
ntral
99. Number of S -S bond is H,S,O% :
(c) (n -2) (d) (n + 1)
(a) n
100. How manyS Sbonds, S O-Sbonds, o-bonds, r-bonds are present in trimer of sulphuE
trioxide?
(b) 0, 3, 12, 6 (c) 0, 6, 12, 16 (d) 0, 4, 12, 6
(a) 0, 3, 16, 2
is :
101. Number of identical Cr-O bonds in dichromate ion Cr,0,
(c) 7 (d) 8
(a) 4 (b) 6
located in :
ne? 102. The nodal plane in the r-bond of ethene is
(a) the molecular plane
(b) a plane parallel to the molecular pl¡ne which bisects the carbon-carbon o bond
(c) a plane perpendicular to the molecular plane
right angle
plane perpendicular to the molecular plane which contains the carbon-carbon bond
(@) a and isostructural?
103.Which of the following are isoelectronic
NO3, C0,Clo,, SO,
in (b) SO3, NO, (c) ClO3, CO (d) co,Clo,
electronic structure of H,SO A, the total number of unshared electrons is :
104. In the (d) 8
16j 16 (c) 12
(a) 20
76 INORGANIC CHEMIS
105. Which of the following xenon compound has the same number of lone pairs as in I,?
(c) XeF2 (d) XeO3
(a) XeO4 (b) XeFA
106. The shape of XeF; is :
(b) Pyramidal
(a) Trigonal planar (d) See-saw
107.Ler Bentof Tshape
Which the following shape are not possible for possible value of'n' in XeF, molecule
() (II) (III)
(a) I > II > II
(c) II > I> III (d) II >I> II
144, Which of the following is not true about H,0 molecule?
1(ay The molecule has u -0
76) The molecule can act as a base
(c) Shows abnormally high boiling point in comparison to the hydrides of other elements of
Oxygen group
(d) The molecule has a bent shape
145. The boiling points at atmospheric pressure of HF, H,S, NH,can be arranged in the following
order :
(a) HF > NH, > H,S (b) HF> H,S> NH,
higher (c) HF < H,S< NH, (d) HF < NH, <H,S
146. The correct order of strength of H-bond in the following compound :
(a) H,0> H,0, > HF > H,S (b) HF > H,0,> H,0 > H,S
(c) HF > H,0> H,S> H,0, (a) HF >H,0>H,O, >H,S
rrect? 147. Which compound does not have electrovalent, covalent, co-ordinate as well as hydrogen
bond?
(a) [Cu(H,0) 4]S04 ·H,0 (b) [Zn(H,0) 6]S0 4H,0
(c) [Fe(H,0) 6]S04 H,0 (d) [Fe(H,0)6]Cl,
148. Which statement is correct?
group due to intermolecular
(a) m.p. of H,0, NH, are maximum in their respective
H-bonding
due to weak intermnolecular force of
(b) b.p. of CH, out of CH4, SiH4, GeH, and SnH, is least
attraction
(c) formicacid forms dimer by H-bonding
(d) all are correct
149. Which of the following molecules are
expected to exhibit intermolecular H-bonding?
(I) o-nitrophenol (I) m-nitrophenol (IV) o-boric acid
(I) Acetic acid
Select correct alternate: (d) II, II, IV
elting (b) I, I, IV (c) I, III, IV
(a) I, II, II H-bonding with each other ?
following compounds can form
150.Which of the (b) Phenol and CH4
(a) CH,COOH and H,0
(c) CHF, and acetone (d) PH, and HF
151. Correct order of bond length is: (b) N, > N;
(a) O, >0, (d) H, >H}
(c) Cz >C;
B0
diamagnetic nature respectively:
and
152. Select pair of molecules with paramagnetic (b) Cz,N2
(a) B,C, (d) O2B2 behaviour?
(c) N2,O2
hassame bond order but different magnetic
pair
153. Which of the following (b) N and N
(a) H} and H;
(d) C and Cz
() 0j and O, elec
the following molecule bond length increases by either gain of an
154. For which of
removal of an electron?
(c) N2 (d) O2
(a) B2 (b) C2
mentioned is brackets:
155.Select the incorrect order of property
(a) Li, > F, (Bond length) (b) C>O, (Bondenergy)
() H,> F, (Bond energy) (d) O, > F, (Bond energy)
bond energy?
156. Which of the following pairs have nearly identical values of
(a) O, and H2 (b) F, and H,
(c) Ng and CO (d) O, and Cl,
157. In which of the following set all the species are paramagnetic in nature?
(a) O,,0;, N (b) B2, G2, H,
(c) 0;,0;,O2 (d) Nz, O;, F
158. Which of the following characteristics are incorrect for order : F, <O,?
(a) Bond length (b) Bond energy
(c) HOMO has same symmetry (d) All molecular orbitals are not fille
159. Select correct statement about the following transformation
NÌ+ ’NO
(a) Reduction ofN O bond order (b) Increase of magnetic moment
(c) Increase of N-O bondlength (d) All of these
160. Which of the following species have the same bond order?
i) NOt (ii) NO (ii) CN (iv) OF
(a) (i) and (i)
(b) (i) and (iii)
(c) i) and (iii)
(d) (i) and (iv)
161. If sp mixing of orbitals is absent in
molecule only o-bond is present? following molecules, then in which of the f
(a) B2 (b) Cz
162. Which of the following species (c) N2 (d) O2
transition? absorb maximum energy in its HOMO-LUMO
(a) O2 (b) Nz
163. In which of the following (c) G2 (d) N2
behaviour has changed? transformation, the bond order has increased and the
(a) C ’C2
(c) O , 0 (b) NO* NO
(d) N , N
CHEMICALBONDING (Basic)
81
164. N, and O2 are converted into cations N; and O, respectively. Which is incorrect statement for
these cations?
(a) In O2, paramagnetism decreases w.r.tO,
(b) NG becomes diamagnetic
(c) In N2, N N bond weakens w.r.t N,
(a) In O;,0 0 bond order increases w.r.t 0,
165. Increasing order of bond length in NO, NO and NO are:
(a) NO> NO > NO+ (b) NO < NO <NO
(c) NO <NO* < NO (d) NO<NOt = NO
166. Which of following statement is incorrect?
(a) O, is paramagnetic, O, is also paramagnetic
(b) O, is paramagnetic, O3 is diamagnetic
(c) B, is paramagnetic, C, is diamagnetic
(d) C-Obond length decreases when COt is formed from CO
167. N, and O, are converted to monocations N,and 0; respectively, which is wrong statement?
(a) In N,the N -N bond weakens (b) In 0,the O-0 bond order increases
(c) In 0;, the paramagnetism decreases (d) N becomes diamagnetic
168. Which of the following property is different between NO and 0;?
(a) sp mixing (b) Magnetic behaviour
(c) Bond order (d) o and -bond
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