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CHEMICAL BONDING (BASIC)

Level
Introductory Questions
1. The combination of atoms take place so that:
(a) They can gain two electrons in the outermost shell
(b) They get eight electrons in the outermost shell
(c) They acquire stability by lowering of energy
(d) They get eighteen electrons in the outermost shell.
Lewis Dot Structure
2. N,0 has a linear, unsymmetrical structure that may be thought of as a
hybrid oftwo resonance
forms. If a resonance form must have a satisfactory Lewis structure, which twO of the five
structures shown below are the two resonance forms of N0?
+
(a) :N=N=0: (b) :N=N=0: (c) :N=G Ô:
3. Which of the following molecular species/compound is not
(d) :N=N=-0:
(a) CH; hypovalnt ?
(b) B,H6 (c) NH; \(0 AlF,
4. N,CO has three possible structures ;
ONCN (nitrosyl cyanide), ONNC (nitrosyl isocyanide) NOCN (isonitrosyl cyanide).
Which of the following structure has lowest potential energy?
(a) ONCN (b) ONNC
(c) NOCN (d) All have same energy
5. Which of the following statement is correct for NO, ion ?
(a) Sum of all formal charges =+1
(b) Formal charge on one of the oxygen atom =-2
YFormal charge on nitrogen atom =+1
1
(a) Average formnal charge on oxygen atom 3
INORGANIC CHEMISTRY
68
incorrect ?
Which of the following Lewis dot structure of CO, is (d) None of these
6. (c) :0C Q:
(a) :0C=0: LcQ-C-ö: bond pairs around central atom is
zreater than
structure the number of
7. According to Lewis dotfollowing anion
four for which of the () PO o None
(b) NO,
(a) CO
lonic Bond
of electricity because :
8. Solid NaCl is a bad conductor ions
(a) in solid NaCI there are no
(b) solid NaCl is covalent
of ions
in solid NaCl there is no mobility
d) in solid NaCl there are no electrons
likely to be formed when :
9. An ionic compound AB is most electron affinity of B is low
(a) the ionization energy of A high and affinity of B is high
the ionization energy of Ais low and electron
electron affinity of B are high
(c) both, the ionization energy of A and affinity ofBare low
(d) both, the ionization energy of Aand electron
the oxidation of A =+2, B=+5and
10. Acompound contains three elements A, B and C, if
C=-2, the possible formula of the compound is :
(b) Az(BC4)2 (c) A,(BC,)2 (d) ABCz
(a) A,(B4,C)2
11. Which pair of atoms form strongest ionic bond?
(a) Al and As (b) Al and N
(c) Al and Se 1dY Al and O
12. In which of the following species the bonds are non-directional ?
(a) NCI, (byRbCI (c) BeCl, (d) BCl,
13. A bond formed between two like atoms cannot be :
| ionic (b) covalent (c) coordinate (d) metallic
14. An electrovalent compound does not exhibit space isomerism because of :
(a) Presence of oppositively charged ions (b) High melting points
(c) Non-directional nature of the bond (d) Crystalline nature
15. Two elements Aand Bhave following electronic configuration.
A=1s2s2p632 V=2 2 t3=
B=1s25'2p 3s?3p v=5
If expected compound formed by A and B is A,B, then sum of x and y is :
(a) 2 (b) 3 (c) 4
Lottice Energy
16. The lattice energies of KE KCI, KBr and KI follow the order :
\ KE > KCl > KBr > KI (b) KI> KBr > KCl> KF
(c) KF KCl>KI> KBr (d) KI> KBr > KF> KC1
17. Which set of compounds in the following pair of ionic
energy? compounds has the higher latt
HEMICALBONDING(Bascl)
69
Mgo (ii) LiF or LiBr
(i) KCIor (iii) Mg N, or NaCl
(a) KCI, LiBI,NaCI
Mg,N2 (b) MgO, LiBr, Mg ,N2
Li
(c) MgO, Mgo, LiF, Mg,N 2
Theincorrect order of lattice energy is :
18. MgF,
(a) AlF3 > LiF (b) Li,N >li,0
(c) NaCl> (d) TiC> ScN
Whichjonic compound has the largest amount of lattice energy?
19. NaF (b) AlF3 (c) AIN (d) MgF
The order of increasing lattice energy of the following salt is:
20. CaO < NaBr < BaO
(a) NaCI < \ NaBr < NaCl < BaO < CaO
o) NaCI < NaBr < BaO CaO (d) NaBr < NaCl < CaO < BaO
Which combination will give strongest ionic bond ?
21-
(a) Na and Cl (b) Mg and CI
(c) Nat and 02 and 2
mong the following isostructural compounds, identifythe compound, which has the highest
lattice energy :
(a) LiF (b) LiC1 (c) NaCI
23. In which of the following ionic compounds, AH, is negative only due to lattice energy ?
() NaF (ii) MgO (ii) Li,N (iv) Na,S
(a) Only (iv) (b) Only (iii), (iv)
(e Only ii), (ii), (iv) (d) All of these
94. Select the correct reason for given statement Flouride of Al is ionic while chloride of Al is
covalent".
(a) IE of Al in AlF3> AlCl (b) EA of Flourine> Chlorine
1(er Lattice energy of AIFz > AlCl, (d) EA of Flourine < Chlorine
Covalent Bond
25. Which pair of elements can form multiple bond with itself and oxygen?
(a) FN (b) N, CI (c) N, P (d) N, C
26. Which of the following is a covalent compound?
(a) Al,03 (b) AlF3 (d) Al,(SO4)3
27. Which of the following is an example of super octet molecule?
(a) ClF'3 (b) PCls (c) IF, All the three

28. Which of the following molecule is theoretically ngt poible?


(a) SF4 (b) OF, OF4 () 0F2
would be :
9. The phosphate of a metal has the formula MHPO4. The formula of its chloride
(a) MCI (c) MCl3 (a) M,Cl3
X-Cl bond is :
oU. The compound that has the highest ionic character associated with the
(a) PCls (b) BClg (c) CCl4 eto Sici,
31. The bond having the highest bond energy is : E
(d) P==N
(a) C=C (b) CS
32. Which of the following species is neither hypervalent nor hypovalent ?
(a) CIO, (b) BE; (c) So

atom
70
exactlv
INORGANIC CHEMISTG
central atom is NOT surrounded by 8
33. In which of the following species
electrons?
(c) PCI
valene
(a) BF, (b) NCI,
electrons when it is forming covalent bona.
34. Which atom can have more than eight valence
(a) H (b) N (c) F
35. Whieh bond is expected to be the least polar?
(b) PF (c) Si-N (d) B-F
36. Which set contains only covalently bonded molecules?
La BCl3, SiCl4, PCl, (b) NHBr, N
,H4, HBr
(c) Ih, H,S, Nal (d) Al, O3, As4
37. Which molecule does not exist?
(a) OF2 OF, (c) SF2 (d) SF4
38. Which of the following does not contain any coordinate bond ?
(a) NH,Cl (b) Na BF4] (c) H,0* () CO
39. A : tetracyanomethane B: carbondioxide
C: benzene D: 1,3-buta-di-ene
Ratio of oand bonds is in order:
(a) A =B<C<D (b). A=B<D<C
(c) A =B =C=D (d) C<D<A< B
40. In a compound
NC
NC C=c M(CO),
C,Hs
the number of sigma and pi bonds respectively are :
(a) 19, 11 (b) 19, 5 (c) 13, 11 (d) 7, 3
41. Which of the following dÍes not contain any co-ordinate bond?
ká) H,0* Le) BF; (c) HF,
42. Which of the following molecules does not have co-ordinate bonds?
(a) PH Weehenis
(b) NO2
43. Which of the following bonds have
(c) O3
(a) C-C
lowest bond energy?
(b) N-N (c) H-H
44. The bond having the minimum bond
(a) C-C energy is :
(c) S s (d) P P
Valence Bond Theory
45. The fluorine molecules is formed by:
(a) p-p orbitals (sideways overlap) b p-p orbitals
(c) sp-sp orbitals (d) s-s orbitals
(end-to-end overlap)
46. Which of the following leads to bonding?
S-orbital p-orbital S-orbital p-orbital p-orbital p-orbital
(a) (c) (d)
CHEMICAL BONDING (Basic)

Which of the following overlaps is incorrect (assuming 2-axis is internuclear axis) ?


’ T-Bond formation (B) 2p, + 2px ’o-Bond formation
(A)2py + 2p,
(C) 3d,y +3d,y ’ -Bond formation (D) 2s+ 2p y ’ -Bond formation
(E) 3d,y +3dgy ’ &-Bond formation (F) 2p, + 2p, ’ G-Bond fomation
(a) A, B, C (b) C, F (c) B, E \(YB,C, D
A8) Which of the following overlapping is not present in XeO, molecule ?
(a) sp + Px (b) sp +Py (c) dg + Px (d) sp° + s
A0. How many sigma bonds are in a molecule of diethyl ether, C,H,0C,H,?
(a) 14 (b) 12 (c) 8 (d) 16
50. Which combination of orbitals will form r-bond, if internuclear axis is x-axis ?
(a) Pr + Px (c) d,2_,2 +dey (d) d,yg + d
If d orbital of atom Aand p, orbital of atom Bform -bond along a particular molecular
5J axis. thenwhich bond will be formed along same molecular axis by combination of (d,y +d)
orbitals of (A) and (B) atom :
(a) o-bond (b) -bond 1eS-bond (d) Can't be predicted
52. Which of the following is correct order of g-bond strength ?
() 2s-2s (I)2s-2p (II) 2p -2p (IV) 3s -3s
(a) I> II> III> IV bYl> II> I> IV (c) IV > I> II> III (d) II> I>II> IV
53. Which of the following overlaps gives o-bond along x-axis as internuclear, axis ?
(a) p, andp, (b) sand Ps (c) sand Py and d,2y
54. Which of the following orbital combination can not formr-bond ?
(a)P, +Px sideways overlapping e d,,2 t Py sideways overlapping
(c) dy + d,y sideways overlapping (a)dyg t Py sideways overlapping
axis ?
55. Which of the following overlaps gives o-bond along x-axis as internuclear,
(a) P, and p, (b) s and p, (c) s and Py and d,2y?
56. Which of the following orbital combination can no formn
T-bond ?
(a) P, +Px sideways overlapping d,22+Py sideways overlapping
(c) dy t dy sideways overlapping (a) dyg tPy sideways overlapping
VSEPR Theory
57. In which of the following species maximum
atom can lie in sane plane
(b) PCls (c) AsH d) XeF4
(a) XeF,02
CF4 and XeF4 are:
58. Correct statement regarding molecules SF4,
respectively
(a) 2, 0 and 1 lone pairs of central atom
respectively
(b) 1, 0 and 1 lone pairs of central atom respectively
(c) 0, 0 and 2 lone pairs of central atom respectively
e 1, 0 and 2 lone pairs of central atom
geometrical arrangement of orbitals and shape of I3 are respectively:
59. The
shape
ya trigonal bipyramidal geometry, linear
(b) hexagonal geometry Tshapetriangular shape
(©) triangular planar geometry,
(d) tetrahedral geometry, pyramidal shape
72 INORGANIC CHEMISTRY
60. Which of the following statements is incorrect for PCls?
(a) Its three P-Cl bond lengths are equal (b) It involves sp°dhybridization
(
\ i t has an regular geometry (d) Its shape is trigonal bipyramidal
61. Molecular shapes of SF,, CF4 and XeF4 are :
(a) the same with 2,0 and 1 lone pair of electrons respectively
(b) the same, with 1,1 and 1 lone pair of electrons, respectively
(c) different, with 0,1 and lone pair of electrons, respectively
ik different with 1,0 and 2 lone pair of electrons, respectively
62. Thestructure of the noble gas compound XeF, is:
square planar (b) distorted tetrahedral
(c) tetrahedral (d) octahedral
63. The molecule exhibiting maximum number of non-bonding electron pairs 1.p.)around the
central atom is :
(a) XeOF4 (b) XeO2F2 (d) XeO3
64. Which is the following pairs of species have identjcal shapes?
(a) NO; and NO; (b) PCI, and BrFs \( XeF, and ICI, (d) TeCl, and Xe0,
65. The shapes of XeF4, XeF and SnCl, are :
(a) octahedral, trigonal bipyramidal and bent
(b) _square pyramidal, pentagonal planar and linear
) square planar, pentagonal planar and angular
(d) see-saw, T-shaped and linear
66. Whiçh is not correctly matched?
\a XeO-Trigonal bipyramidal (b) CIF3 bent Tshape
(c) XeOF4-Square pyramidal (d) XeF,-Linear shape
67. Amongst NO,, As0,CO,Clo, and SO,the non-planar species are
(a) co,so 6) AsO,cIo,, So
(c) NOJ, CO (d) so? ,NO,
68. The geometry of ammonia molecule can be best described as :
(a) Nitrogen at one vertex of a regular tetrahedron, the other three
vertices being occupied by
three hydrogens
j6) Nitrogen at the centre of the tetrahedron, three of the vertices being
occupied by three
hydrogens
(c) Nitrogen at the centre of an equilateral triangle, three corners being
occupied by three
hydrogens
(d) Nitrogen at the junction of a T three open ends being occupied by three
69. Which molecular geometry is least likely to result from a trigonal bipyramidal
hydrogens
electron
geometry?
Trigonal planar (b) See-saw (c) Linear (d) Bent Tshaped
70. Give the correct order of initials T or F for folowing statements. Use T if statement is true and
Fifit is false :
(D The order of repulsion between different pair of electrons is , ->l, -b, > b, -b,
RY
CHEMICAL BONDING (Bosic)
73
mIn general, as the number of lone pair of electrons on central atom
increases, value of
bond angle from normal bond angle also increases
(mThe number of lone pair on 0 in HO is 2 while on N in NH, is 1
(MThe structures of xenon fluorides and xenon Oxyfluorides could not be
explained on the
basis of VSEPR theory
(a) TTTF ( TFTF (c) TFTT (d) TFFF
71. Whiçh species is planar?
a co (b) so (c) ClO, (d) BF4
72. What is the geometry of the IBr, ion?
ka) Linear
he (b) Bent shape with bond angle of about 90°
(c) Bent shape with bond angle of about 109°
(d) Bent shape with bond angle of about 120°
73. What is the shape of the ClF, molecule?
(a) Trigonal planar (b) Trigonal pyramidal
Ler Tshaped (d) Tetrahedral
74. Which species has the same shape as NH,?
Ltso (b) co
(c) NO, (d) sOg
same plane?
75. According to VSEPR theory, in which species do all the atoms lie in the
1. CH 2. CH3
1only (b) 2 only
(c) both l and 2 (d) neither 1 nor 2
have same number of bond pairs and lone
76. Which of the following species/molecules does not
pairs? (d) O3
(a) OCN (b) H,O (c) C,H,Cl,

Hybridisation
sp and sp-hybridised carbon atoms are present respectively in the following
77. How many
y compound ?
H
ee H

H
ee
H
(d) 5, 1
(c) 3, 3
(b) 6, 0 and
(a4, 2one of the following is the correct set with respect to molecule, hybridization
n
78. Which
planar
shape? (b) BeCl,, sp", triangular
(a)BeCl,, sp", linear (d) BCls, sp
,tetrahedral
d e BCI, sp, triangular planar
74

9. The hybridization of
the central atom in ICI 2 1s :
(c) sp
INORGANICRElN
(a) dsp? (b) sp in the othere.
of the central atom is not the same as
O 1ne tate of
hybridization
(c) N in NH, (d) P in PCI,
Bin BF, SP H,0*
(b) O in
benzene are :
81. The number of sp s sigma bonds in
(c) 12 (d) none of these
(a) 3
change when
82, The hybridization of the central atom will
(a) NH, combines with Ht (b) HB0, combines with OH
(c) NH, forms NH2 (d) H,Ocombines with Ht
83. CH,-CH,-CH=CH, has hybridisation: Sp
(a) sp, sp, sp", sp (b) sp
osp°,sp,sp, sp (d) sp Sp, sp Sp
84. What is the state of hybridjsation of Xe in cationic part of solid XeF,?
(a) sp°a (c) sp'd (d) sp
85. During the complete combustion of methane CH4, what change in hybridisation dow
carbÍn atom undergo?
13 sp to sp (b) sp to sp (c) sp to sp (d) sp to sp
86. The bybridisation of central iodine atom in IFs, I; and I; are
respectively :
o sp°d², sp°d, sp (b) sp°d, sp°d, sp³ () sp°, sp°d, sp (d)
87. In which of the following combination spd, sp°d
hybridisation of central atomn (") does not change
(a) H,0+o, (b) H, BO+OH (c) BF, + NH,
88. Which of the following species (d) None of these
used both axial set of d-orbitals in
atom?
hybridisation of centra
(a) PBr (b) PCI,
89. Which bonds are formed by a (c) ICl, (d) None of these
carbon atom with
(a) 4n-bonds
1(Y ln-bonds and 3o-bonds
sp-hybridisation?
(b) 2-bonds and
90. What are the (d) 46-bonds
26-bonds
hybridisation of the carbon atoms labeled C, and C,
(a) sp
sp
respectively in glycne
H H
(b) sp sp3

(d) sp
H-N-C
H
91. The H-0-H
these bonds arebond angles in Ha0* are
(a) p-orbitals
best described as : approximately 107°, The orbitals used by oxy8
(c) sp-hybrid orbital (b) sp-hybrid orbitals
Le sp°-hybrid orbital
EMISTRY CHEMICALBONDING (Basic) 75

Molecular Geometry/Shape
isostructural pairs :
o2. Among given species identify the
(a) [NFzand BF3] 1 (BE,and NH] (c) [BCl,and BrCl,J (d) [NH3 and NO3]
ng 001 mole of H,PO, is completely neutralised by 0.56 gram of KOH hence :
e (a) x =3 and given acid is dibasic
(b) X=2 and given acid is monobasic
(c) x=3 and given acid is monobasic
(d) x=4 and given acid forms three series of salt
exists as :
94. Phosphorus pentachloride in the solid
(a) PCl, (b) PCI}CI (c) PCIPCI; (d) PCl,Cl,
O5. The ratio of o-bond and r-bond in tetracyano ethylene is : (d) None of these
(a) 2:1 (b) 1:1 (c) 1:2
96. Bonds present in N,Os (nitrogen pentaoxide) are :
(a) only ionic (b) only covalent
covalent and co-ordinate (d) covalent and ionic
(c)
s the
97. The pair of species with similar shape is :
1aPCl,, NH, (b) CF4,SF4 (c) PbCl,,CO2 (d) PFs,Fs
allene molecule, CH?
98. Which of the following statements is correct in the context of the
(a) The central carbon is sp hybridized
sp (b) The terminal carbon atoms are sp hybridized
perpendicular to pemit the
Be? (c) The planes containing the CH, groups are mutually
formations two separate -bonds
(d) All are correct
ntral
99. Number of S -S bond is H,S,O% :
(c) (n -2) (d) (n + 1)
(a) n
100. How manyS Sbonds, S O-Sbonds, o-bonds, r-bonds are present in trimer of sulphuE
trioxide?
(b) 0, 3, 12, 6 (c) 0, 6, 12, 16 (d) 0, 4, 12, 6
(a) 0, 3, 16, 2
is :
101. Number of identical Cr-O bonds in dichromate ion Cr,0,
(c) 7 (d) 8
(a) 4 (b) 6
located in :
ne? 102. The nodal plane in the r-bond of ethene is
(a) the molecular plane
(b) a plane parallel to the molecular pl¡ne which bisects the carbon-carbon o bond
(c) a plane perpendicular to the molecular plane
right angle
plane perpendicular to the molecular plane which contains the carbon-carbon bond
(@) a and isostructural?
103.Which of the following are isoelectronic
NO3, C0,Clo,, SO,
in (b) SO3, NO, (c) ClO3, CO (d) co,Clo,
electronic structure of H,SO A, the total number of unshared electrons is :
104. In the (d) 8
16j 16 (c) 12
(a) 20
76 INORGANIC CHEMIS
105. Which of the following xenon compound has the same number of lone pairs as in I,?
(c) XeF2 (d) XeO3
(a) XeO4 (b) XeFA
106. The shape of XeF; is :
(b) Pyramidal
(a) Trigonal planar (d) See-saw
107.Ler Bentof Tshape
Which the following shape are not possible for possible value of'n' in XeF, molecule

(a) Linear (b) Square planar


(d) Capped octahedral
ier Trigonal planar
108. BeCl, is not isostructural with :
(a) 1Cl, (b) CzH2 (c) XeF2 (d) GeCl2
109. Which statement is true about the most stable Lewis structure for CS,?
(a) There are no lone pairs in molecule
(b) Allbonds are double bonds
(c) The centralatom does not have an octet of electrons
(d) A sulfur atom must be the central atom for the structure to be stable
110. SbFs reacts with XeF, andXeF, to form ionic compounds [XeFJ[SbF,]and [XeFJfShF
then molecular shape of [XeF$] ion and [XeF] ion respectively :
(a) Square pyramidal, T-shaped (b) Bent-T-shape, square pyramidal
(c) See-saw, square pyramidal (d) Square pyramidal, see-saw
Dipole Moment
111. BF3 and NFz both are covalent compounds but NFz is polar whereas BF, is
because : non-polar. This
(a) Nitrogen atom is smaller than boron atom
(b) E-F bond is more polar than B-Fbond
e NF, is pyramidal whereas BF, is planar
(d) BFa is electron deficient whereas NF, is triangular
not
112. Dipole moment of NF, is smaller than :
(a) NH3 (b) CO (c) BF,
will have polar bonds but zero (d) cCl,
113. Which of the following
(a) O2
molecules dipole moment?
(b) CHCI,
114.Which has maximum dipole (d) none of these
moment?
C Cl
C CI Cl
Cl
(a)
(c)
(d)
Cl

115. Which of the -CI


(a) XeO4 following compound is planar and
non-polar ?
(b) SF4
(d) CF4
CHEMICAL BONDING (Basic)

116. H,0 has a net dipole momnent while BeF, has 77


(a) Fis more zero dipole
(b) Be is more electronegativity
than oxygen moment because :
electronegativity
than
(c) H,0 molecule is linear and BeF, isoxygen
BeF, molecule is linear and H,0 is bent
e? 117. Correct set of species with zero dipole
bent
(i) ÇO2 (ii) COCl,
moment is :
(a () and (iv) (ii)CH,Cl, (iv) BCl3
(c) (ii) and (iv) (b) (i)and (iv)
118. Which pair of
(d) (i), (iii) and (iv)
molecules are polar species?
(a) ÇO, and H,0
e) sO, and SCl, (b) BF, and PCl3
.s0 In which molecule does the (d) CS, and SO,
(a) HCI
chlorine atom has positive partial charge?
(b) BrCi (c) OCl, (d) sCl,
Bond Parameters
Fl 120. Least stable hydride is :
(a) stannaneGn (b) silane Si o plumbane Pb (d) germane Te
121. The lowest O-0 bond length in the following
molecule is :
(a) O,F2 (b) O2 (c) H,02
122. Which one of the following compounds has the smallest bond angle?
(d) O3
(a) OH, B 6) SH, 8 c) NH (d) SO2
is 123. Maximum bond angle is present in:
(a) BBr3 (b) BCl, (c) BE3 none of these
124. The correct order of H M-H bonds angle is i
(a) NH < PH < SbH, < BiH3 \b AsH < SbH3< PH, <NH,
(c) NH, < PH, < BiH, < SbHg (d) BiHg< SbH, < AsH, < PH,
125. The correct increasing order of adjacent bond angle among BF3, PF, and CIF,:
(a) BF, < PF, < CIF3 (b) PF, < BF < CIF3
Ver CIF, <PF, <BF3 (d) BF, =PF, =ClF,
126Among the following species, the Jeast angle around the central atom is in:
(a) O3 (c) NO, (d) PH3
127. The bond angles of NH,, NH and NH, are in the order :
(a) NH, > NH, > NH; \6 NHÊ >NH, >NH;
(c) NH, > NH; > NH (d) NH, >NHË> NH,
repulsion, the H-O-H angle in
128. The H-C-H bond angle in CH, 0s 109.5°, due to lone pair
H,0 will : (b) increase
(a) remain the same (d) become 180o
Lerdecrease
129. The molecule having the largest bond angle is(c): H,Se (d) H,Te
(b) H,S
78
INORGANIC CHE
XMX angles in the
130. The Compound MX, is
tetrahedral. The number
of
(b) four
compound i
(a) three L six
(c) five
131, The "O-Ñ 0" bond angle is maximum in : (d) NO,
(c) NO2
(a) N,O l(bY NO; angle ?
of the following is the correct order for increasing bond
132. Which (b) H,0<OF, <Cl,o
(a)NH, < PH <AsH < SbH3 (d) BF;<BCl, < BBr, < BI4
Le H,Tet <H Set <H,st <H,0*
Molecular Forces
133. Which of the following attraction is strongest ?
(b) CHClg)ECHCI)
(a) C:t: C
() CCl:,0) (d) C H , 0
134. Which is distilled first?
(a) Liquid H, (b) Liquid CO2
(c) Liquid O2 (d) Liquid N,
135. The molecular size of ICl and Br, is approximately same, but b.p. if IClis about 40°C %
than that of Br,. It is because :
(a) ICI bond is stronger than Br-Br bond (b) IE of iodine < IE of bromine
(c) ICl is polar while Br, is nonpolar (d) Ihas larger size than Br
136. Which of the following order of molecular force of
(a) HI> HBr > Cl,
attraction among given species is incor
(b) CH,Cl >CCl, > CH4
(c) n-pentane > iso-pentane >
neo-pentane (d) OH2 >O(CH3)2>OBr,
137. Which gas should not be collected over water because of its high
(a) H, (b) N, solubility in water?
138.Low melting point is expected for a (c) CH4 (d) HCI
(a) Ionic solid solid:
(c) Molecular solid (b) Metallic solid
139. Which substance has the (d) Covalent solid
(a) SiH4 strongest London dispersion forces?
140. (b) CH4 (c) SnH4
Which of the following (d) GeH4
(a) HF compounds has the lowest boiling point?
(b) HCI
141. When the Si, KCI, CH0H and C (c) HBr
point, whatsubstances
is the correct H, are
(d) HI
(a) Si, KCI, order? arranged in order of increasing m
CH,OH,
(c) KCl, Si, C,H6, CHCH6 (b) CH,OH,
142. Which substance has the OH (d) C,H, Si, KCI
(a) Co highest melting point? C,H6, CH OH, KCI, Si
(c) Sio2
(b) CO 2
(d) P4O10
EMISTRY
is: CHEMICAL BONDING (Basic)
79
Hydrogen Bond
143.The correct order of boiling point is :
OH OH OH
F CI Br

() (II) (III)
(a) I > II > II
(c) II > I> III (d) II >I> II
144, Which of the following is not true about H,0 molecule?
1(ay The molecule has u -0
76) The molecule can act as a base
(c) Shows abnormally high boiling point in comparison to the hydrides of other elements of
Oxygen group
(d) The molecule has a bent shape
145. The boiling points at atmospheric pressure of HF, H,S, NH,can be arranged in the following
order :
(a) HF > NH, > H,S (b) HF> H,S> NH,
higher (c) HF < H,S< NH, (d) HF < NH, <H,S
146. The correct order of strength of H-bond in the following compound :
(a) H,0> H,0, > HF > H,S (b) HF > H,0,> H,0 > H,S
(c) HF > H,0> H,S> H,0, (a) HF >H,0>H,O, >H,S
rrect? 147. Which compound does not have electrovalent, covalent, co-ordinate as well as hydrogen
bond?
(a) [Cu(H,0) 4]S04 ·H,0 (b) [Zn(H,0) 6]S0 4H,0
(c) [Fe(H,0) 6]S04 H,0 (d) [Fe(H,0)6]Cl,
148. Which statement is correct?
group due to intermolecular
(a) m.p. of H,0, NH, are maximum in their respective
H-bonding
due to weak intermnolecular force of
(b) b.p. of CH, out of CH4, SiH4, GeH, and SnH, is least
attraction
(c) formicacid forms dimer by H-bonding
(d) all are correct
149. Which of the following molecules are
expected to exhibit intermolecular H-bonding?
(I) o-nitrophenol (I) m-nitrophenol (IV) o-boric acid
(I) Acetic acid
Select correct alternate: (d) II, II, IV
elting (b) I, I, IV (c) I, III, IV
(a) I, II, II H-bonding with each other ?
following compounds can form
150.Which of the (b) Phenol and CH4
(a) CH,COOH and H,0
(c) CHF, and acetone (d) PH, and HF
151. Correct order of bond length is: (b) N, > N;
(a) O, >0, (d) H, >H}
(c) Cz >C;
B0
diamagnetic nature respectively:
and
152. Select pair of molecules with paramagnetic (b) Cz,N2
(a) B,C, (d) O2B2 behaviour?
(c) N2,O2
hassame bond order but different magnetic
pair
153. Which of the following (b) N and N
(a) H} and H;
(d) C and Cz
() 0j and O, elec
the following molecule bond length increases by either gain of an
154. For which of
removal of an electron?
(c) N2 (d) O2
(a) B2 (b) C2
mentioned is brackets:
155.Select the incorrect order of property
(a) Li, > F, (Bond length) (b) C>O, (Bondenergy)
() H,> F, (Bond energy) (d) O, > F, (Bond energy)
bond energy?
156. Which of the following pairs have nearly identical values of
(a) O, and H2 (b) F, and H,
(c) Ng and CO (d) O, and Cl,
157. In which of the following set all the species are paramagnetic in nature?
(a) O,,0;, N (b) B2, G2, H,
(c) 0;,0;,O2 (d) Nz, O;, F
158. Which of the following characteristics are incorrect for order : F, <O,?
(a) Bond length (b) Bond energy
(c) HOMO has same symmetry (d) All molecular orbitals are not fille
159. Select correct statement about the following transformation
NÌ+ ’NO
(a) Reduction ofN O bond order (b) Increase of magnetic moment
(c) Increase of N-O bondlength (d) All of these
160. Which of the following species have the same bond order?
i) NOt (ii) NO (ii) CN (iv) OF
(a) (i) and (i)
(b) (i) and (iii)
(c) i) and (iii)
(d) (i) and (iv)
161. If sp mixing of orbitals is absent in
molecule only o-bond is present? following molecules, then in which of the f
(a) B2 (b) Cz
162. Which of the following species (c) N2 (d) O2
transition? absorb maximum energy in its HOMO-LUMO
(a) O2 (b) Nz
163. In which of the following (c) G2 (d) N2
behaviour has changed? transformation, the bond order has increased and the
(a) C ’C2
(c) O , 0 (b) NO* NO
(d) N , N
CHEMICALBONDING (Basic)
81
164. N, and O2 are converted into cations N; and O, respectively. Which is incorrect statement for
these cations?
(a) In O2, paramagnetism decreases w.r.tO,
(b) NG becomes diamagnetic
(c) In N2, N N bond weakens w.r.t N,
(a) In O;,0 0 bond order increases w.r.t 0,
165. Increasing order of bond length in NO, NO and NO are:
(a) NO> NO > NO+ (b) NO < NO <NO
(c) NO <NO* < NO (d) NO<NOt = NO
166. Which of following statement is incorrect?
(a) O, is paramagnetic, O, is also paramagnetic
(b) O, is paramagnetic, O3 is diamagnetic
(c) B, is paramagnetic, C, is diamagnetic
(d) C-Obond length decreases when COt is formed from CO
167. N, and O, are converted to monocations N,and 0; respectively, which is wrong statement?
(a) In N,the N -N bond weakens (b) In 0,the O-0 bond order increases
(c) In 0;, the paramagnetism decreases (d) N becomes diamagnetic
168. Which of the following property is different between NO and 0;?
(a) sp mixing (b) Magnetic behaviour
(c) Bond order (d) o and -bond

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