Fm3chem Notes
Fm3chem Notes
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Chemistry section
Separation (Topic 1)
They are many methods used to separate substances eg filtration, evaporation, magnetism,
decanting, hand picking, chromatography, winnowing and distillation
Distillation
Is used to separate a pure liquid from a mixture of liquids
Only works when the liquids in a mixture have a different boiling points
Boiling point of a substance is a temperature at which it boils and turns to a gas.
Distillation is used in producing pure water in the laboratory
Procedure
Impure water (tap water) is heated to the boiling temperature of 100 degrees Celsius
Water boils and evaporates and become steam
Steam is cooled inside the condenser and condenses to form liquid water
Pure water is collected in the conical flask as the distillate
Impurities in the water are left behind in the boiling flask
Distillation can be used to separate pure water from sea water
Fractional distillation
Differs from distillation in that it separates a mixture into a number of parts called fractions
Tall column is fitted above the mixture with several condensers coming off at different
heights
Column is hot at the bottom and cool at the top
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Substances with high boiling point condense at the bottom and substance with low boiling
point condenses at the top
Fractional distillation column applications
Application 1: Purication of ethanol
Ethanol is separated from a mixture of ethanol and water by fractional distillation
Method works because the liquid in the mixture have different boiling points.
Ethanol boils at 78.4℃ , water at 100℃
Matter(Topic 2)
Atom
Is the smallest indivisible particle of matter that take part in a chemical change.
Element
Is a substance made up of only one type of an atom
Atoms of different elements are different
Structure of an atom
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1. Hydrogen H
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2. Helium He
3. Lithium Li
4. Beryllium Be
5. Boron B
6. Carbon C
7. Nitrogen N
8. Oxygen O
9. Fluorine F
10. Neon Ne
11. Sodium Na
12. Magnesium Mg
13. Aluminium Al
14. Silicon Si
15. Phosphorus P
16. Sulphur S
17. Chlorine Cl
18. Argon Ar
19. Potassium K
20. Calcium Ca
Nuclide notation
Is a way of summarizing the structure of an atom of a specified element.
Chemical bonding
A compound is a chemical combination of two or more element e.g. water, carbon dioxide
To make a compound the atoms of different elements have to join or bond
Elements that react have incomplete shells
Bonding occurs through ionic bonding or covalent bonding
Ionic bonding
Is formed between metals and non-metals
Metals form positive ions (cations) because they lose electrons
Nonmetals form negative ions (anions because they gain electrons
Ions of opposite charges attract one another and so form ionic bond
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a Sodium chloride
b Magnesium oxide
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Sodium oxide.
Covalent bonding
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Examples
Bonding in Hydrogen molecule
e.g
Cu S O4 =64 +32+16(4) = 64 +32+64=160g
H 2 S O 4 =1(2) + 32+16(4) =2 + 32+64 =98g
HCl=1+35.5=36.5 g
NaOH =23+16+1=40 g
Ca ¿
C O2=12+16 ( 2 )=44 g
Mole
Is the amount of substance that contains 6,023x 1023 particles (atoms/molecules?)
6,023x 1023= Avogadros constant
A mole of atoms has a mass equal to the Ar of the atom
A mole of molecules has a mass equal to the molecular mass of the substance
Mass of a mole= molar mass=formula mass/molecular mass
mass
number of moles=
molecular mass
M
n=
Mr
Example
Calculate the number of moles in 6g of carbon
M
n= ,
Mr
M=6, Mr/Ar of carbon =12 therefore
6
n= =0 . 5 moles
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Empirical formula
It is the simplest formula of a substance
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C atom H atom
Mass 80g 20g
Ar 12 1
No of moles (n) 80 20
=6.67 =20
12 1
Simplest ratio 6.67 20
=1 =2.998=3
6.67 6.67
Emperical formula C H3
Example 2
Give the formula of the compound that is formed when 3.3g of carbon is combined with 9.0g of
oxygen
C atom O atom
Mass 3.3g 9g
Ar 12 16
No of moles (n) 3.3 9
=0.275 =0.5625
12 16
Simplest ratio 0.275 0.5625
=1 =2
0.275 0.275
Emperical formula C O2
Concentration/(Molarity)
Concentration is the amount of solute in grams or moles that is dissolved in 1 d m3 of a
solution
n m
C = ∨ where c=concentration
v v
mol
dm
3 ( )
∨(gramm/d m )
3
n= number of moles
v=volume (d m3 ¿
m=mass in grams
If the volume is in cm3 or ml divide by 100 to get d m3
Example
Calculate the concentration of a solution that contains
a) 0.01moles in 200ml
n
C = = 0.01/ (200÷1000) = 0.05mol/d m3
v
n
C = = 2mol/3d m3= 0.66mol/d m3
v
Indicators
Litmus
Indicates that the solution is acidic or alkaline
They are two types, blue litmus paper and red litmus paper
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pH scale
Runs from pH 0 to pH 14
Measures how acidic
or alkaline a solution
is.
Experiment
Aim: To investigate the reaction of acids with carbonates
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Method
Put a small amount of each carbonate into two separate test tubes
Pour dilute HCl into each of the test tubes until they are about half full.
Observe the mixture for a few minutes
Test for carbon dioxide using lime water
Experiment
Aim To investigate the reaction of acids with metal
Method
Place a small piece of magnesium in 3 separate test tubes
Repeat the process with zinc in 3 different test tubes
Pour dilute HCl over each metal until it just covers the metal
Repeat the process for nitric acid
Pour sulphuric acid into the last 2 test tubes
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The liquid air is pumped into a fractional distillation column and the liquid air is heated
Electrolytic cell
It consist of
1. Electrolyte—contain ions and can be broken down by electrolysis
2. Electrodes --- which are conductors through which electricity enters or leave a substance,
electrodes are generally made up of carbon (graphite)
Carbon electrodes have a high melting point and are inate
The electrode connected to the negative terminal of the battery is the cathode
The anode is connected to the positive terminal of the battery
A container for the liquid is needed
Observations
Observation Explanation
Anode Bubbles of brown gas Bromine vapour
Cathode Silvery liquid Lead produced
Electrolysis of water
A compound is a group of two of two or different atoms that are bonded together e.g. water
H2 O
Electrolysis of water produces hydrogen and oxygen
Hydrogen comes off at the cathode and oxygen is collected at the anode
Pure water does not conduct electricity, so for electrolysis to occur sulphuric acid is added to
it
Carbon electrodes are used to carry current into and out of the electrolyte
Method
Add few drops of H 2 S O 4 to the beaker
Allow current to pass through the water
Remove one test tube at a time and quickly place your thumb over the mouth of the test tube
Test the gas at the anode with a glowing splint and the gas at the cathode with a lit splint
Diagram
Observations
cathode Anode
Effect of gas on splint The splint burns with a The gas relights a glowing
popping sound splint
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Volume of the gas collected Is twice that is collected at Is half of that collected at the
the anode cathode
Conclusion
Sulphuric acid is added to the water for electrolysis as water is not a good conductor of
electricity
Electrolysis of water results in the production of oxygen gas at the anode and hydrogen gas at
the cathode
This electrolysis is often called the electrolysis of acidified water
Uses of hydrogen
Is used as a fuel
A lifting agent in ballons
Used in manufacturing of margarine
Used in harber process (ammonia synthesis)
Electroplating
Is a process of depositing a thin coating of one metal on top of a different metal through the
chemical process of electrolysis.
Electroplating is meant is meant to prevent metals from rust
Copper, chrome, nickel are used to electroplate more reactive metals for protection as the do
not corrode
Reactive metals are those that are able to form a reaction with acids, water, oxygen eg of
reactive metals are zinc, iron
Steel is hard alloy of iron and carbon and is susceptible to corrosion
Electroplating is also done to decorate objects
Electroplating iron nail with copper
The cathode is the object to be coated (plated) nail
Anode electrode should be the metal that you want to coat the object with (copper)
Electrolyte is copper 11 sulphate solution acidified with sulphuric acid
Nail to be cleaned to ensure when the copper atoms from the electrolyte are deposited onto it
(nail) form a good bond
Diagram
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Expt
Aim: To demonstrate the reduction of copper 11 oxide
Method
Place about 100mg of block copper 11 oxide in the test tube. Set up the test tube as shown
above
Insert a rubber bung with a short glass tube in the test tube
Connect a rubber tube from a gas cylinder to the glass tube
Allow a very slow stream of gas to flow through the app and burn it at small hole
Adjust the gas so the flame is not more than 2cm high
Heat the copper 11 oxide with a burner until there is change in colour and remove the heat
source
Extraction of Iron from iron ore
Raw materials used in the extraction of iron ore
Iron ore
Rocks from which metallic iron can be extracted
Largest iron ore are deposits found in sedimentary rocks
The iron ore is known as haematite (iron 111 oxide)
Oxygen must be removed from the iron 111 oxide to leave iron behind (reduction)
Coke
Contains carbon which act as a reducing agent
It burns in air to produce heat and reacts to form carbon dioxide.
Air
Contains oxygen which allow coke to burn to produce heat and reacts to form carbon
monoxide
Limestone (calcium carbonate) CaCO3
Helps remove acidic impurities by reacting with them to form molten slag
NB Mwanesi mine is a large iron mine located in central Zimbabwe
Raw- materials are added to the blast furnace
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Formation of slag
Silica (main impurity /silicon dioxide) reacts with the calcium oxide (CaO) formed from the
decomposition of calcium carbonate (CaCO3 ¿ ¿ form/produce slag ( calcium silicate CaSi
O3 ¿
Calcium oxide + silicon dioxide ⟶calcium silicate
CaO +SiO2 ⟶ CaSi O3 (slag)
Molten slag floats on top of the molten iron as it is less dense and is tapped off separately
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Expt
Aim: To investigate the effect of heating Fe2 O3on a charcoal block
Apparatus
Wooden spatula (will provide the charcoal )
Burnsen burner
Iron 111 oxide
Method
Hold a small wooden spatula on a blue gas flame for a few seconds
Try to char it, the black material you have made is charcoal
Dip the charcoal end of the stick into powdered iron 111 oxide until it has become coated
with powder
Put the coated end of the stick into the hot blue flame and heat it until it glows orange
Stub it out and grind the result ash
Stroke the ash with a small bar magnet and look for tiny crystals of iron sticking to the
magnet
Try to stroke the magnet over the iron 111 oxide powder.
Conclusion
The charcoal acts as the reducing agent
It burns in air and reacts to produce carbon dioxide which reduces the iron 111 oxide to iron
A chemical reaction has taken place as can be seen when using the magnet.
Iron sticks to the magnet, iron ore.
ORGANIC CHEMISTRY (TOPIC 6)
Hydrocarbons
Are organic compounds that contain the element carbon and hydrogen
Carbon is the building block of carbon compounds
Organic compounds can contain other elements such as oxygen nitrogen and chlorine
A wide variety of carbon compounds are possible as carbon can form up to four single
covalent bonds
Organic compounds are represented in different ways
Molecular formula e.g methane (C H 4 )
Structural formula eg ethane
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Carbon can bond to itself in different structures including chains, rings and branches
Homologous Series
Is a series of organic compounds with the same general formula and with the same functional
group
The compounds differ in the length of carbon chain
Functional group of a compound is an atom or a group of atoms that form the centre of
chemical activity in the compound
NB number of carbon atoms determine the prefix of the name and functional group the suffix
They are said to be saturated hydrocarbons because of the single bonds between the carbon
atoms and because they are saturated they do not react that much
The functional group of all alkanes is:
Alkenes
A homologous series that is characterized by at least one double bond between the carbon atoms
in the chain
Their general formula isC n H 2 n
The fact that they have at least one double bond means they are unsaturated
The functional group is
The name of alkene compounds always end with the suffix –ene
Eg of alkene include methane, propene
Uses of hydrocarbons
Are important source of energy
The form of energy is chemical energy
When burning the fuels energy is released in the form of heat and light.
Hydrocarbon Use
Methane It is mainly in heating as a fuel of stove water heaters
Main constituency of natural gas
Ethane Used in heating and also needed for the production of ethane and used
in many chemical processes
Propane Used as fuels for engine
Also used for portable camping stoves
Ethene Used as a building block of chemicals such as plastics, anti – freeze
solutions and solvents
Propene Mainly used in the production of polypropylene which is used in many
ways eg for textiles, furniture, packaging of food and toys
Time
The length of time that the organic waste needs to be in the digester depends on the type of
organic waste fed into the digester
Metals
Metals must be introduced into digesters as some metals cause microorganisms which carry
out the fermentation process to die
Uses of biogas
Can be used to cook, generated electricity or heat buildings.