SAFETY DATA SHEET

MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MULTITROPE™ 1214-LQ-(MV)

Registered Product Identity : MULTITROPE 1214
Product code : PTR1050
Chemical Name : Phosphate esters
Manufacturer or supplier's details
Company : Croda Inc.
Address : 777 Scudders Mill Road, Bldg. 2
Plainsboro, NJ 08536
Telephone : (609) 212-2500
Telefax : (609) 212-2501

Emergency telephone : USA: 24 Hour Emergency Response Information CHEMTREC

toll free: 1-800-424-9300; direct/international: 1-703-527-3887.
CANADA: GFL 1-877-898-7222. EUROPE: 00 32 3575 5555.
ASIA PACIFIC - excl. China:+65 6542-9595. CHINA: +86 816-
635 2206. AUSTRALIA: +61 2 7808 3390. SOUTH AFRICA:
+32 3 575 55 55. BRASIL: Ambipar 0800 117 2020. LATAM:
Suatrans (+55) 11 98149-0850 / (+55) 19 3833-5300. INDIA:
+91 22 30948601/2. JAPAN: +65 6542 9595 (24時間日本語対
応無料通話, シンガポール). TÜRKIYE: Sağlik Bakanliği Ulusal
Zehir Merkezi - 114
Recommended use of the chemical and restrictions on use
Recommended use : Surfactant

Prepared by : Product Safety and Regulatory Affairs Department

(732) 417-0800

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Skin corrosion : Category 1A
Serious eye damage : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H314 Causes severe skin burns and eye damage.

Precautionary Statements : Prevention:

P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response:

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MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT

induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at
rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste disposal
plant.

Other hazards which do not result in classification

May cause irritation of respiratory tract.
Ingestion may cause irritation to mucous membranes.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients

Chemical Name CAS-No. Concentration [%]

Alkoxylated phosphate ester 68130-47-2 >= 90 - <= 100
Phosphoric acid 7664-38-2 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

If inhaled : If breathed in, move person into fresh air.

If symptoms persist, call a physician.

In case of skin contact : In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If eye irritation persists, consult a specialist.

If swallowed : If swallowed, call a poison control center or doctor

immediately.

Most important symptoms and : None known.

effects, both acute and delayed
Notes to physician : None known.

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SAFETY DATA SHEET

MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

SECTION 5. FIRE-FIGHTING MEASURES

Flammable properties
Flash point : > 93 °C (> 199 °F)
Method: closed cup

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.

Unsuitable extinguishing media : High volume water jet

Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fire.
fighting Do not allow run-off from fire fighting to enter drains or water
courses.

Specific extinguishing methods : Standard procedure for chemical fires.

Further information : Use water spray to cool unopened containers.

Special protective equipment for : In the event of fire, wear self-contained breathing apparatus.
fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective : Use personal protective equipment.

equipment and emergency Ensure adequate ventilation.
procedures
Environmental precautions : Prevent product from entering drains.
Do not allow material to contaminate ground water system.

Methods and materials for : Neutralize with chalk, alkali solution or ammonia.
containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin, eyes and clothing.
Handle in accordance with good industrial hygiene and safety
practice.

Conditions for safe storage : Store in original container.

Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Keep container tightly closed in a dry and well-ventilated place.

Materials to avoid : No special restrictions on storage with other products.

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MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control parameters Basis
(Form of / Permissible
exposure) concentration
Phosphoric acid 7664-38-2 TWA 1 mg/m3 ACGIH
STEL 3 ppm ACGIH
TWA 1 mg/m3 NIOSH REL
ST 3 mg/m3 NIOSH REL
TWA 1 mg/m3 OSHA Z-1
TWA 1 mg/m3 OSHA P0
STEL 3 mg/m3 OSHA P0

Personal protective equipment

Respiratory protection : In the case of vapor formation use a respirator with an
approved filter.
No personal respiratory protective equipment normally
required.

Hand protection
Remarks : Impervious gloves

Eye protection : Tightly fitting safety goggles

Face-shield

Skin and body protection : impervious clothing

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : viscous liquid

Color : clear
Odor : No data available
Odor Threshold : No data available
pH : 1, 10% In water
1
Melting point : No data available
Boiling point : > 93 °C (> 199 °F)
Flash point : > 93 °C (> 199 °F)Method: closed cup

Evaporation rate : No data available

Vapor pressure : No data available

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MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

Relative vapor density : No data available

Relative density : 1.2
Density : No data available
Solubility(ies)
Water solubility : No data available
Solubility in other solvents : Solvent: No data available

Partition coefficient: n- : No data available

octanol/water
Thermal decomposition : No data available

Viscosity
Viscosity, kinematic : No data available
Explosive properties : Method: No information available.

Oxidizing properties : No data available

Surface tension : not determined

Conductivity : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No data available

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Hazardous polymerization does not occur.

reactions Stable under normal conditions.

No decomposition if used as directed.

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : In case of fire hazardous decomposition products may be produced

products such as:
Carbon monoxide
Carbon dioxide (CO2)
Oxides of phosphorus

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:

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MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

Acute oral toxicity :

Remarks: No data available

Skin corrosion/irritation
Product:
Result: Corrosive
Classification: Causes burns.
Method: In vitro study

Serious eye damage/eye irritation

Product:
Result: May cause irreversible eye damage.

Result: Causes burns.

Respiratory or skin sensitization

Product:
Remarks: No data available

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: No data available
Carcinogenicity
Product:

Remarks: This information is not available.

Reproductive toxicity
Product:
Effects on fertility :
Remarks: This information is not available.

STOT-single exposure
Product:
Assessment: No data available

STOT-repeated exposure
Product:
Assessment: No data available

Aspiration toxicity
No data available

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MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

Further information
Product:
Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish :
Remarks: No data available

Toxicity to daphnia and other : EC50 (calculated) (Daphnia magna (Water flea)): 8.80 mg/l
aquatic invertebrates Exposure time: 48 h
Test Method: Immobilization
Method: OECD Test Guideline 202

Toxicity to algae : EbC50 (Desmodesmus subspicatus (green algae)): 26 - 35 mg/l

Exposure time: 72 h
Test Type: semi-static test

EC50 : 8.8 mg/l

Exposure time: 48 h

ErC50 (Desmodesmus subspicatus (green algae)): 63 - 78 mg/l

Exposure time: 72 h
Test Type: semi-static test

NOEC : 6.25 mg/l

Persistence and degradability

Product:
Biodegradability : Test Type: aerobic
Result: Biodegradable
Biodegradation: 87 %
Exposure time: 28 d
Method: Directive 67/548/EEC Annex V, C.4.B.
Remarks: This surfactant complies with the biodegradability criteria
as laid down in Regulation (EC) No.648/2004 on detergents. Data to
support this assertion are held at the disposal of the competent
authorities of the Member States and will be made available to them,
at their direct request or at the request of a detergent manufacturer.

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: No data available

Partition coefficient: n- : Remarks: No data available

octanol/water
Mobility in soil

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SAFETY DATA SHEET

MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

No data available
Other adverse effects
Product:
Environmental fate and : Remarks: No data available
pathways
Results of PBT and vPvB : Remarks: No data available
assessment
Additional ecological : There is no data available for this product.
information

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.

Do not re-use empty containers.
Empty containers should be taken to an approved waste handling
site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR
UN/ID No. : 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s.
(phosphoric acid ester)
Class : 8
Packing group : II
Labels : 8
Packing instruction (cargo : 855
aircraft)
Packing instruction : 851
(passenger aircraft)
IMDG-Code
UN number : 3265
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(phosphoric acid ester)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

Domestic regulation

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SAFETY DATA SHEET

MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

49 CFR
UN/ID/NA number : 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s.
(phosphoric acid ester)
Class : 8
Packing group : II
Labels : 8
ERG Code : 153
Marine pollutant : no
Special precautions for user
Not applicable

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : E: Corrosive Material

SARA 311/312 Hazards : Chronic Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

US State Regulations
Pennsylvania Right To Know
Alkoxylated phosphate ester 68130-47-2 90 - 100 %
Phosphoric acid 7664-38-2 1 - 5 %

New Jersey Right To Know

Alkoxylated phosphate ester 68130-47-2 90 - 100 %
Phosphoric acid 7664-38-2 1 - 5 %

California Prop 65 This product does not contain any chemicals known to the State
of California to cause cancer, birth, or any other reproductive
defects.
The ingredients of this product are reported in the following inventories:
TSCA All chemical substances in this product are listed on the TSCA
Inventory.
REACH On the inventory, or in compliance with the inventory
CH INV The mixture contains substances listed on the Swiss Inventory
DSL All components of this product are on the Canadian DSL.
AICS On the inventory, or in compliance with the inventory
ENCS On the inventory, or in compliance with the inventory
ISHL On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory

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SAFETY DATA SHEET

MULTITROPE™ 1214-LQ-(MV)
Version 1.0 Revision Date 11/24/2014 Print Date 01/19/2021

PICCS On the inventory, or in compliance with the inventory

IECSC On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS II:

Flammability

HEALTH 3
1
Instability
Health

3 0 FLAMMABILITY 1
Reactivity 0
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

The information provided in this Material Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in
the text.

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