Chapter 13 (Assignment + Review) - Withput Answers

Chapter 13 Assignment problems
(7/11 10:00 PM)

15. Write the mathematical expression for the reaction quotient, Qc, for each of the following reactions:
NB; Only (aq) and (g) are ALLOWED

to be used in formula
We can’t use (s) nor (l)
23. For which of the reactions in (Exercise 15) does Kc

(calculated using concentrations) equal Kp (calculated using
pressures)?
This situation occurs in (a) and (b).

17. The initial concentrations or pressures of reactants and products are given for each of the following
systems. Calculate the reaction quotient (Qc) and determine the direction in which each system will proceed
to reach equilibrium.
25. Convert the values of Kc to values of Kp or the values of Kp to values of Kc
NB; Only (aq) and (g)
are ALLOWED
There’s only 2 R values in chemistry;

1) In pressures and gases: R = 0.0821
2) In Energy: R = 8.314
T in Kelvin
37. Suggest four ways in which the concentration of PH3 could be increased in an
equilibrium described by the following equation:
39. How will an increase in temperature affect each of the following equilibria?
How will a decrease in the volume of the reaction vessel affect each?
40. Methanol (CH3OH) can be prepared from carbon monoxide (CO) and hydrogen (H2) at high temperature and pressure
in the presence of a suitable catalyst.
(a) Write the expression for the equilibrium constant (Kc) for the reversible reaction
(b) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if more H2 is added?
(c) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if CO is removed?
(d) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if CH3OH is added?
(e) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if the temperature of the
system is increased? (decreased)
(f) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if more catalyst is added?
53. Hydrogen is prepared commercially by the reaction of methane and water vapor at elevated temperatures.
What is the equilibrium constant (Kc) for the reaction if a mixture at equilibrium contains gases with the
following concentrations: CH4, 0.126M; H2O, 0.242M; CO, 0.126M; H2 1.15M, at a temperature of 760 °C?
55. At 1 atm and 25 °C, NO2 with an initial concentration of 1.00M is 0.0033% decomposed into NO and O2. Calculate
the value of the equilibrium constant (Kc) for the reaction.
𝑰𝒏𝒊𝒕𝒊𝒄𝒂𝒍 𝑪𝒉𝒂𝒏𝒈𝒆 𝑬𝒒𝒖𝒊𝒍𝒊𝒃𝒓𝒊𝒖𝒎 𝑰𝑪𝑬 𝑴𝒆𝒕𝒉𝒐𝒅

57. When heated, iodine vapor dissociates according to this equation:
At 1274 K, a sample exhibits a partial pressure of I2 of 0.1122 atm and a partial pressure due to I atoms of 0.1378 atm.
Determine the value of the equilibrium constant, Kp, for the decomposition at 1274 K.
59. At a temperature of 60 °C, the vapor pressure of water is 0.196 atm. What is the value of the equilibrium constant Kp
for the vaporization equilibrium at 60 °C?
65. Calculate the number of moles of HI that are at equilibrium with 1.25 mol of H2 and 1.25 mol of I2 in a 5.00−L flask
at 448 °C.
69. Carbon reacts with water vapor at elevated temperatures.
Assuming a reaction mixture initially contains only reactants, what is the concentration of
CO in an equilibrium mixture with [H2O] = 0.500M at 1000 °C?

75. Assume that the change in concentration of COCl2 is small enough to be neglected in the following problem.
(a) Calculate the equilibrium concentration of all species in an equilibrium mixture that results from the
decomposition of COCl2 with an initial concentration of 0.3166 M.
(b) Confirm that the change is small enough to be neglected.
76. Assume that the change in pressure of H2S is small enough to be neglected in the following problem.
(a) Calculate the equilibrium pressures of all species in an equilibrium mixture that results from the
decomposition of H2S with an initial pressure of 0.824 atm.
(b) Confirm that the change is small enough to be neglected.
78. What are the concentrations of PCl5, PCl3, and Cl2 in an equilibrium mixture produced by the decomposition of a
sample of pure PCl5 with initial [PCl5] = 2.00M?

80. Butane exists as two isomers, n−butane and isobutane.
Kp= 2.5 at 25 °C
What is the pressure of isobutane in a container of the two isomers at equilibrium with a total pressure of 1.22 atm?
Chapter 13 Review problems
(7/X 00:00 PM)
1) The oxidation of sulfur dioxide produces sulfur trioxide.
2 SO3(g) → 2 SO2(g) + O2(g)
Calculate the value of Kc , given that Kp = 3.6 X 10-3 at 999 K. (R = 0.08206 L·atm/mol·K)
T in Kelvin
2) At a given temperature, 0.0524 mol NO2(g) is placed in a 1.00 L flask. After reaching
equilibrium, the concentration of NO2(g) is 3.9 × 10-3 M. What is Kc for the reaction below?
2 NO2(g) → N2O4(g)
3) At 800 K, the equilibrium constant, Kp, for the following reaction is 3.2 X 10-7
2 H2S(g) → 2 H2(g) + S2(g)
A reaction vessel at 800 K initially contains 3.50 atm of H2S. If the reaction is allowed to
equilibrate, what is the equilibrium pressure of H2?
4) Given the following equilibria,
PbBr2(s) → Pb2+(aq) + 2 Br-(aq) K1 = 6.6 X 10-6

Pb(OH)2(s) → Pb2+(aq) + 2 OH-(aq) K2 = 1.4 X 10-15
determine the equilibrium constant, Kc, for the following reaction.
PbBr2(s) + 2 OH-(aq) → Pb(OH)2(s) + 2 Br-(aq)

Chapter 13 (Assignment + Review) - Withput Answers

Uploaded by

Copyright:

Available Formats

Chapter 13 (Assignment + Review) - Withput Answers

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chapter 13 (Assignment + Review) - Withput Answers

Uploaded by

Copyright:

Available Formats

Chapter 13 Assignment problems

(7/11 10:00 PM)

NB; Only (aq) and (g) are ALLOWED

23. For which of the reactions in (Exercise 15) does Kc

This situation occurs in (a) and (b).

There’s only 2 R values in chemistry;

𝑰𝒏𝒊𝒕𝒊𝒄𝒂𝒍 𝑪𝒉𝒂𝒏𝒈𝒆 𝑬𝒒𝒖𝒊𝒍𝒊𝒃𝒓𝒊𝒖𝒎 𝑰𝑪𝑬 𝑴𝒆𝒕𝒉𝒐𝒅

𝑰𝒏𝒊𝒕𝒊𝒄𝒂𝒍 𝑪𝒉𝒂𝒏𝒈𝒆 𝑬𝒒𝒖𝒊𝒍𝒊𝒃𝒓𝒊𝒖𝒎 𝑰𝑪𝑬 𝑴𝒆𝒕𝒉𝒐𝒅

𝑰𝒏𝒊𝒕𝒊𝒄𝒂𝒍 𝑪𝒉𝒂𝒏𝒈𝒆 𝑬𝒒𝒖𝒊𝒍𝒊𝒃𝒓𝒊𝒖𝒎 𝑰𝑪𝑬 𝑴𝒆𝒕𝒉𝒐𝒅

PbBr2(s) → Pb2+(aq) + 2 Br-(aq) K1 = 6.6 X 10-6

You might also like

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.