blackhole1
blackhole1
Brian P. Dolan
Department of Mathematical Physics, National University of Ireland,
Maynooth, Ireland
and
Dublin Institute for Advanced Studies, 10 Burlington Rd., Dublin, Ireland
e-mail: bdolan@stp.dias.ie
1
and conclusions.
2 Enthalpy
Consider a black hole with mass M in the presence of a cosmological constant
Λ. The cosmological constant generates a pressure
Λ
P =− (1)
8πGN
and has an energy density ǫ associated with it with ε + P = 0, i.e. the
enthalpy density associated with Λ is zero. If the black hole has a volume V
the total energy contained in V is
E = M + εV = M − P V ⇒ M = E + P V,
hence M is most naturally associated with the enthalpy H of the black hole
H = E + P V.
It is not obvious what the volume of a black hole should be. The naı̈ve
identification of V with the volume of a sphere with the radius of the event
horizon rh is too simplistic since the radial co-ordinate is time-like inside the
4πr 3
horizon and 3 h is not the volume of any space-like section of space-time
inside the horizon. It is suggested in [9] that V be identified with the volume
excluded by the black hole horizon from a spatial slice exterior to the black
4πr 3
hole, giving the naı̈ve result V = 3 h but from a more physically acceptable
perspective. For the moment we shall leave V unspecified and determine it
below from thermodynamic considerations.
The natural variables for enthalpy are entropy and pressure, so we should
view M as a function of S and P ,
M = H(S, P ).
πrh2 πrh2
S= = 2 , (2)
h̄GN ℓ
2
√
where l = h̄GN is the Planck length.1
The metric of four-dimensional space-time is given by
d2 s = −f (r)dt2 + f −1 (r)dr 2 + r 2 dΩ2 ,
with
2GN M Λ
f (r) = 1 −− r2, (3)
r 3
and dΩ2 = dθ2 + sin2 θdφ2 the solid angle area element. The event horizon
is defined by f (rh ) = 0,
Λ 3
r − rh + 2GN M = 0. (4)
3 h
One can solve the cubic equation to find rh (M, Λ) analytically, but the
explicit
√ form will not be needed in the following. For Λ > 0 and 0 <
3M ΛGN < 1 there are two event horizons and the region of space-time
outside the black hole horizon √
but inside the de Sitter horizon lies between
them. They coincide when 3M ΛGN = 1. Each event horizon has a differ-
ent Hawking temperature associated with it and the system is not in thermal
equilibrium. In order to ensure thermal equilibrium we shall assume Λ < 0
in the following.
Equation (3) gives the mass as
rh Λ
M= 1 − rh2 . (5)
2GN 3
Identifying M with the enthalpy and using (1) and (2) gives
!1
ℓ2 S 8GN ℓ2 SP
!
1 2
H(S, P ) = 1+ . (6)
2GN π 3
The usual thermodynamic relations can now be used to determine the
temperature and the volume,
1
h̄(1 − Λrh2 )
!
∂H h̄ π
2
T = ⇒ T = 2
(1 + 8P GN ℓ2 S) = (7)
∂S P
4π ℓ S 4πrh
3
4 (ℓ2 S) 2 4πrh3
!
∂H
V = ⇒ V = √ = . (8)
∂P S
3 π 3
1
In the ensuing analysis we shall make factors of GN and h̄ explicit in order to exhibit
clearly which aspects of the physics are classical and which are quantum. Note that
ℓ2 S = πrh2 is a classical quantity, S diverges in the classical limit while ℓ2 S remains finite.
3
The Hawking temperature (7) comes as no surprise since it follows from the
usual formula relating the temperature to the surface gravity κ at the event
horizon
h̄κ h̄f ′ (rh )
T = = .
2π 4π
Varying (4) gives
2GN r2
df = − dM − h dΛ + f ′ (rh )drh = 0,
rh 3
so
∂M rh ′ ∂M h̄ ′
= f (rh ) ⇒ = f (rh ),
∂rh Λ
2G ∂S P
4π
which is equation (7). Equation (8) suggests that the “naı̈ve” volume is
indeed the correct one to use in thermodynamic relations.
Legendre transforming (6) gives the internal energy
s
1 ℓ2 S
E(S, V ) = H(S, P ) − P V = , (9)
2GN π
but the Legendre transform is not invertible: because H(S, P ) is linear in
P , E(S, V ) is independent of V and so the pressure cannot be determined
from a knowledge of E(S, V ) alone. For the same reason T = ∂E∂S V
gives the
wrong answer for the temperature if the pressure is non-zero.
Nevertheless we can still use (6) to determine the heat capacity at con-
stant pressure using the standard thermodynamic relation
T
CP = ∂T
.
∂S P
One finds
8GN P ℓ2 S + 1
!
CP = 2S . (10)
8GN P ℓ2 S − 1
The heat capacity at constant volume
T ∂S
CV = =T
∂T ∂T V
∂S V
vanishes, if we use the Hawking formula (2), since the variation of the entropy
is necessarily zero when the volume, and hence rh , is fixed.
4
It could have been anticipated in advance that CV = 0, from (9): E
2
depends only on S and S = ℓπ2 3V 4π
3
is a function of V alone so E is constant
if V is held fixed as the temperature is varied.
Local stability requires that CP > 0 so 8GN P ℓ2S > 1, or equivalently
−Λrh2 > 1,
5
Figure 1 shows T (V ) for various pressures and figure 2 shows the black
hole indicator diagram, P (V ), for various temperatures. The temperature as
a function of entropy, at constant pressure, is shown in figure 3, for compar-
ison with the J = Q = 0 case in figure 1 of [5].
T I = −T ln Z, (16)
6
But is this the Helmholtz free energy F (T, V ) or the Gibbs free energy
G(T, P )?
The functional integral is performed with fixed T and Λ, so F (T, Λ)
should be though of as a function of T and Λ and, using (7), it is readily
shown that
πr 2 r3
dF = − h dT − h dΛ. (18)
GN h̄ 6GN
Hence
∂F πrh2 ∂F 4πrh3
∂F
− = =S and = −8πGN == V.
∂T Λ
GN h̄ T
∂P T
∂Λ3
(19)
These are the thermodynamic relations associated with the Gibbs free energy,
G(T, P ), and not the Helmholtz free energy. It is natural therefore to identify
F = G(T, P ) with the Gibbs free energy. The enthalpy is the Legendre
transform of the Gibbs free energy H = G + T S and a simple calculation
shows that H = M is the black-hole mass.
Euler’s equation for thermodynamic potentials follows from dimensional
analysis. Equation (4) is invariant under the rescalings rh → ηrh , Λ → η −2 Λ
and M → ηM (keeping GN fixed). Hence
which is easily checked. This is Smarr’s formula [16] treated from the same
point of view as in [9]. A simple consequence of this scaling argument is that
M(S, P ) must have the functional form
√
M = SΦ(SP )
for some function Φ(SP ): in fact (6) shows that Φ(SP ) is a linear function.
Corrections to the entropy can modify this simple scaling analysis.
7
where d = D − 2 and dΩ2(d) is the line element on a d-dimensional sphere of
unit radius. Denoting the volume of the unit sphere by
d
2π 2
Ω(d) =
d
Γ 2
8
The analysis of §2 is easily repeated with minor modifications. In D
dimensions the Planck length is given by ld = h̄GN and the entropy is
Ω(d,k) rhd
S= . (23)
4 ld
Equating M with the enthalpy and Λ = − 16πG
d
N
P results in3
!− 1 !1
h̄S R(d) 4ld S d
16πGN P 4ld S d
H(S, P ) = + , (24)
4π d − 1 Ω(d,k) d+1 Ω(d,k)
Ω(d,k) rhd+1
V = , (25)
d+1
and the equation of state is
!− 1 ! 1
h̄ (d + 1)V d+1
(d + 1)V d+1
T = R(d) + 16πGN P . (26)
4πd Ω(d,k) Ω(d,k)
For positive k there is a minimum temperature and volume for any given
fixed pressure
s ! d+1
2h̄ R(d) GN P Ω(d,k) R(d) 2
Tmin = , V (Tmin ) =
d π d+1 16πGN P
3
We use the convention Rµν = Λgµν , giving Einstein tensor Rµν − 12 R gµν =
D−2
Λ gµν . Identifying − D−2
− 2 2 Λ gµν = 8πGN Tµν , with Tµν an energy-momentum
tensor, leads to the quoted identification Λ = − 16πG
D−2 P . The gravitational action is
N
1
R √ D
SGrav = 16πGN R − (D − 2)Λ −g d x.
9
which diverges at Tmin and is negative for T < Tmin . There is thus a Hawking-
Page phase transition for any positive curvature event horizon in D ≥ 4
dimensions, for spatially flat event horizons the specific heat CP = Sd is
always positive while for R(d) < 0 there is no minimum temperature, but
there is still a minimum value of |Λ| below which CP is negative. In all cases
one must have
|R(d) |
|Λ| >
d rh2
for a black hole to be stable in anti-de Sitter space-time.
r2
f (r) = −8GN M + ,
L2
with cosmological constant Λ = − L22 giving a pressure P = 1
8πGN L2
.
The black hole radius q
rh = 8GN M L (27)
is immediate. The event horizon is a circle and the entropy is one-quarter of
the circumference in Planck units,
πrh
S= ,
2l
where l = h̄GN in three dimensions. Identifying the mass with the enthalpy
then gives
4ℓ2 2
H(S, P ) = S P, (28)
π
10
from which
8ℓ2 h̄rh
T = SP = (29)
π 2πL2
2
4ℓ 2
V = S = πrh2 , (30)
π
the standard results (for uniformity of notation the symbol V is used for
the thermodynamic “volume”, even though it is an area in three space-time
dimensions). The Gibbs free energy is
4l2 S 2 P
G = H − TS = − 2M = −M.
π
∂T T
CP is easily calculated, since T is linear in S we have ∂S P
= S
so
T
CP = ∂T
= S > 0.
∂S P
11
where
r2 16G2N J 2
f (r) = −8GN M + 2 +
L r2
and J is the angular momentum, bounded above by J ≤ ML. There are now
two event horizons, and inner and an outer horizon at r+ and r− respectively,
with
2 # 12
"
J
2
r± = 4GN ML2 1 ± 1 − . (32)
ML
in the Euclidean sector and we see that r+ → rE,+ while r− → irE,− where
2 # 12
"
JE
2
rE,± = 4GN ML2 1 + ± 1 . (35)
ML
12
Equation (38) does not include non-perturbative quantum corrections, but
it suffices to illustrate this discussion of corrections to thermodynamic quan-
tities. (Note that τ in our notation is − τ1 in the notation of [21], and ZBT Z
here is denoted Z1,0 there).
We now specialise to the case of zero angular momentum, when
rE,+ h̄ r+ h̄ 2πiT L r+ 2 LT
T = 2
= , τ= =i and q = e−4π h̄ .
2π L 2π L2 h̄ L
The partition function in this case is
π 2 T L2 ∞ −2
2n T L
1 − e−4π
Y
ZBT Z = e 2h̄2 GN h̄ . (39)
n=2
TL
Thermodynamic functions can immediately be read off. Defining x = h̄
=
r+
2πL
the Gibbs free energy is
∞
π 2 x2 2
ln 1 − e−4π nx ,
X
G(T, P ) = −T ln ZBT Z = − + 2T (40)
2GN n=2
where the first term on the right hand side is the classical result.
The entropy was calculated in [21] and the enthalpy can be determined
using the standard formula H(S, P ) = G + T S, giving
∞
π 2 x2 n
− 8π 2 xT
X
H= 4π 2 nx , (41)
2GN n=2 e −1
but this is not expressed explicitly in terms of the natural variables S and
P = 8πG1N L2 , the S dependence is only implicit.
The quantum corrections embodied in the logarithmic terms of (40) mod-
ify the thermodynamic volume,
∞
" ! #
∂G GN h̄ X n
V = = πrh2 1 − 8π 4π 2 nx . (42)
∂P T
L n=2 e −1
We see that the quantum corrections serve to reduce the volume below its
classical value. Figure 4 plots the PV-diagram, quantum effects reduce the
volume to zero at finite pressure, the effect being more pronounced at lower
temperatures.
13
7 Conclusions
Some consequences of the suggestion in [9], that the correct thermodynamic
interpretation of black-hole mass in the presence of a negative cosmological
constant is that it should be associated with enthalpy rather than the more
usual interpretation of internal energy, have been explored and expanded
upon. The cosmological constant is treated as a thermodynamic variable
proportional to the pressure and the black-hole mass is identified with the
enthalpy rather than the internal energy. The interpretation of many thermo-
dynamic quantities is modified in this approach: specific heats, for example,
are naturally calculated as specific heats at constant pressure rather than at
constant volume and the Euclidean action gives the Gibbs free energy and
not the Helmholtz free energy.
Black-hole solutions of Einstein’s equations in any dimension, and with
any Einstein manifold with constant scalar curvature as event horizon, can
easily be constructed and the classical equation of state determined. The
Hawking-Page transition is manifest as a change in sign the specific heat and
is present for black-holes with an event horizon with positive curvature in
any space-time dimension greater than three.
Quantum corrections to the thermodynamics relations for the BTZ black-
hole in three dimensions have been derived from the partition function in [21],
which includes corrections to all orders in perturbation theory but does not
include non-perturbative corrections. These corrections reduce the volume at
a given pressure and temperature, with a finite pressure giving zero volume.
The considerations presented here will have important implications for
AdS/CFT approaches to condensed matter systems, in which the specific
heat at constant pressure has greater significance than the specific heat con-
stant volume.
It is a pleasure to thank the Perimeter Institute, Waterloo, Canada for
hosting a visit during which this work was initiated. This work was partly
funded by the EU Research Training Network in Noncommutative Geometry
(EU-NCG).
14
T
V
Figure 1: Black hole T-V diagram, showing curves of constant pressure
in AdS. The blue line shows the stability limit, the region to the left and
below the blue curve is unstable.
15
P
V
Figure 2: Black hole P-V diagram, showing curves of constant temperature
in AdS. The blue line shows the stability limit, the region to the left and
below the blue curve is unstable.
16
T
S
Figure 3: T-S diagram, showing curves of constant pressure.
The region left of the blue line is unstable, temperature
is an increasing function of entropy in the stable region.
17
P classical
quantum
V
Figure 4: Black hole P-V diagram, showing curves of constant temperature
in AdS3 . The blue lines show the classical curves, P ∝ √1V . Red lines show
the quantum corrected equation of state. The region left of the blue line is unstable,
temperature is an increasing function of entropy in the stable region.
18
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19
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[arXiv:hep-th/0403091].
[23] A. Gosh and P. Mitra, Mod. Phys. Lett. A11 (1996) 1231,
[arXiv:gr-qc/9408040].
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