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Classroom Test-7

The document is a classroom test on chemical equilibrium consisting of 20 multiple-choice questions. It covers key concepts such as equilibrium conditions, equilibrium constants, reaction quotients, and the effects of concentration changes on equilibrium. Each question tests the understanding of fundamental principles related to chemical reactions at equilibrium.

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Rudra Sarkar
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8 views

Classroom Test-7

The document is a classroom test on chemical equilibrium consisting of 20 multiple-choice questions. It covers key concepts such as equilibrium conditions, equilibrium constants, reaction quotients, and the effects of concentration changes on equilibrium. Each question tests the understanding of fundamental principles related to chemical reactions at equilibrium.

Uploaded by

Rudra Sarkar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 6

Dr.

Rudra Sir Mob: 9830657153

CHEMICAL EQUILIBRIUM
Classroom Test-7 /Marks – 20
Section A
1. Which of the following is true about a system at equilibrium?
a. The concentration(s) of the reactant(s) is equal to the concentration(s) of the product(s).
b. No new product molecules are formed.
c. The concentration(s) of reactant(s) is constant over time.
d. The rate of the reverse reaction is equal to the rate of the forward reaction and both rates are equal
to zero.

2. Equilibrium is reached in chemical reactions when:


a. the rates of the forward and reverse reactions become equal.
b. the concentrations of reactants and products become equal.
c. the temperature shows a sharp rise.
d. all chemical reactions stop.

3. The value of the equilibrium constant, K, is dependent on:


I. the temperature of the system
II. the nature of the reactants and products
III. the concentration of the reactants
IV. the concentration of the products

a. I, II
b. II, III
c. III, IV
d. It is dependent on three of the above choices.

4. If the equilibrium constant for A + B C is 0.175, then the equilibrium constant for 2C 2A + 2B
is
a. 0.650
b. 5.71
c. 0.350
d. 32.7

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5. Indicate the mass action expression for the following reaction:
2X(g) + Y(g) 3W(g) + V(g)
a. [X]2[Y][W]3[V]
b.

c.

d.

6. Given the equilibrium constants for the following reactions:

4Cu(s) + O2(g) 2Cu2O(s), K1


2CuO(s) Cu2O(s) + O2(g), K2

what is K for the system 2Cu(s) + O2(g) 2CuO(s) equivalent to?


a. (K1)(K2)
b. [(K2) / (K1)]
c. [(K1) / (K2)]

d. (K1) / (K2)

7. Consider the chemical system: CO + Cl2 COCl2; K = 4.6 × 109 L/mol.


How do the equilibrium concentrations of the reactants compare to the equilibrium concentration of the
product?
a. They are much smaller.
b. They are much bigger.
c. They are about the same.
d. They have to be exactly equal.

8. If the concentration of the product were to double, what would happen to the equilibrium constant?
a. It would double its value.
b. It would become half its current value.
c. It would quadruple its value.
d. It would not change its value.

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9. Consider the following reaction: CS2(g) + 4H2(g) CH4(g) + 2H2S(g). The equilibrium constant K is
about 0.27 at 900°C. What is Kp at this temperature?
a. 2.5 × 103
b. 2.8 × 10–3
c. 2.9 × 10–5
d. 2.6 × 101

10. Consider the reaction At 1273 K, the Kp value is 167.5. What is the at
equilibrium if the is 0.25 atm at this temperature?
a. 3.2 atm
b. 0.130 atm
c. 13 atm
d. 6.5 atm

11. The reaction quotient for a system is 7.2 × 102. If the equilibrium constant for the system is 36, what will
happen as equilibrium is approached?
a. There will be a net gain in product.
b. There will be a net gain in reactant.
c. There will be a net gain in both product and reactant.
d. There will be no net gain in either product or reactant.

12. Consider the following reaction:


2HF(g) H2(g) + F2(g) (K = 1.00 10–2)
Given 1.00 mole of HF(g), 0.291 mole of H2(g), and 0.750 mole of F2(g) are mixed in a 5.00 L flask,
determine the reaction quotient, Q.
a. Q = 0.0437
b. Q = 0.218
c. Q = 0.0546
d. Q = 2.04

13. Consider the following equilibrated system: 2NO2(g) 2NO(g) + O2(g). If the Kp value is 0.648, find
the equilibrium pressure of the O2 gas if the NO2 gas pressure is 0.520 atm and the PNO is 0.300 atm at
equilibrium.
a. 1.12 atm

Page 3 of 5
b. 26.6 atm
c. 0.374 atm
d. 1.95 atm

14. A 10.0-g sample of solid NH4Cl is heated in a 5.00-L container to 900°C. At equilibrium the pressure of
NH3(g) is 1.27 atm.
NH4Cl(s) NH3(g) + HCl(g)
The equilibrium constant, Kp, for the reaction is:
a. 1.27
b. 1.61
c. 2.54
d. 5.81

15. Consider the reaction H2 + I2 2HI for which K = 39.1 at a high temperature. If an equimolar mixture
of reactants gives the concentration of the product to be 0.50 M at equilibrium, determine the equilibrium
concentration of the hydrogen.
a. 1.1 × 10–1 M
b. 8.0 × 10–2 M
c. 4.0 × 10–2 M
d. 1.3 × 101 M

16. A sample of solid NH4NO3 was placed in an evacuated container and then heated so that it decomposed
explosively according to the following equation:
NH4NO3(s) N2O(g) + 2H2O(g)
At equilibrium the total pressure in the container was found to be 2.34 atm at a temperature of 500.°C.
Calculate Kp.
a. 0.608
b. 1.22
c. 0.475
d. 1.90

17. Given the equation 2A(g) 2B(g) + C(g). At a particular temperature, K = 1.6 × 104.
If you mixed 5.0 mol B, 0.10 mol C, and 0.0010 mol A in a one-litre container, which direction would the
reaction initially proceed?
a. To the left.
b. To the right.
c. The above mixture is the equilibrium mixture.

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d. Cannot tell from the information given.

18. The questions below refer to the following system:

Co(H2O)62+ + 4 Cl– CoCl42– + 6H2O

(pink) (blue)

When cobalt(II) chloride is added to pure water, the Co2+ ions hydrate. The hydrated form then reacts with
the Cl– ions to set up the equilibrium shown here. Which statement below describes the change that the
system will undergo if hydrochloric acid is added?
a. It should become more blue.
b. It should become more pink.
c. The equilibrium will shift to the right.
d. The equilibrium will shift to the left.

19. For a certain reaction at 25.0°C, the value of K is 1.2 × 10–3. At 50.0°C the value of K is 3.4 × 10–1. This
means that the reaction is
a. exothermic
b. endothermic
c. never favorable
d. more information needed

20. Consider the following equilibrium: 2H2(g) + X2(g) 2H2X(g) + energy


Addition of X2 to a system described by the above equilibrium
a. will cause [H2] to decrease
b. will cause [X2] to decrease
c. will cause [H2X] to decrease
d. will have no effect

Page 5 of 5

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