CIEM5760_Lecture_2_2020_upload.pdf
CIEM5760_Lecture_2_2020_upload.pdf
1. Rock-forming minerals
What are minerals?
Geologists define a mineral as a naturally occurring, solid,
crystalline substance, generally inorganic, with a specific
chemical composition.
Non-silicate minerals
• Carbonates – contain carbonate ion CO32- 䬛懤湅
Calcite (CaCO3), Aragonite (CaCO3), Dolomite (Ca, Mg)CO3
• Oxides – contain oxygen ion O2- and metallic cations 㾒ԗ࣒
Magnetite (Fe3O4), Hematite (Fe2O3), Corundum (Al2O3)
• Sulfides – contain sulfide ion S2- and metallic cations 䫚ԗ࣒
Pyrite (FeS2), Galena (PbS)
• Sulfates – contain sulfate ion SO42- and metallic cations 䫚懤湅
Gypsum (CaSO4.H20) , Anhydrite (no H20), Barite (BaSO4)
• Halides – contain Cl-, F-, I-, or Br- 渽ԗ࣒
Fluorite (CaF2), Halite (NaCl), Sylvite (KCl)
• Hydroxides – contain hydroxyl ion (OH-) 㾖㾒ԗ࣒
• Native elements – masses of all the same element
metallically bonded eg. copper (Cu) 3
4
Physical characters
Properties of minerals such as: color, luster, form,
hardness, cleavage, fracture, tenacity, and specific
gravity.
Colour:
- Some minerals have a distinctive color e.g. green color
of chlorite.
Streak
The streak of a mineral is the colour of its powder which is produced by
rubbing mineral on a piece of rough unglazed porcelain. It is often quite
different from that of a larger piece of the mineral, and can be a diagnostic
feature used in mineral identification.
⻱䩥⽖
Magnetite (Fe2O4) black/gray streak 8
streak of minerals
9
Photos ©Guillermo Rocha/Brooklyn College
ًҰ
࣬ࣸҰ
㷇劮Ұ
劮Ұ
࣮࣯Ұ
В僙Ұ
擟ीҰ
Dull No luster
10
Hardness, or resistance to abrasion, is measured relative to a
standard scale of ten minerals, known as Mohs’ Scale of
Hardness, which is a highly diagnostic property in mineral
identification.
࢝ी
ी匰 (2.5)
ސઆी (3)
㾋ी
䭝ࢱी (5.5?)
࠳斴ी (6)
ीਸ਼ Unglazed porcelain
ۺ٧ी streak plate (7)
⤔ࣥ
擟ी 11
Hardness
1. Talc 4. Fluorspar 8. Topaz
5. Apatite
2. Gypsum 9. Corundum
6. Orthoclase Feldspar
12
Cleavage :
Cleavage
Cleavage plane
Plane
copper 15
quartz
SiO42-
Silica Tetrahedron
Single chain Double chain
3D network of
tetrahedrons
Sheet of tetrahedrons 17
2 planes at 90°
Single chains
2 planes at 60°
and 120° Double chains
1 plane Sheets
Muscovite: ग曾࠾
曾࠾ Micas KAl2(AlSi3O10)(OH)2
Biotite: ௲曾࠾
K(Mg, Fe)3AlSi3O10(OH)2
2 planes at 90° Three-dimensional
framework
Orthoclase feldspar: ࠳斴ी
斴ी Feldspars KAlSi3O8
Plagioclase feldspar: ފ斴ी 18
(Ca, Na) AlSi3O8
Augite (pyroxene)
In many ways augite (a member of the
pyroxene family) resembles hornblende
(amphibole) in terms of color and
composition.
Augite is distinguished from hornblende by its shorter,
stubbier crystals and the fact that its two cleavage
planes are close to a right angle.
Hornblende (amphibole)
Identifying Characteristics: elongated
crystals (prism or needle-like), dark
color, cleavage angles
20
The mica group:
Muscovite: KAl2 (Si3Al) O10 (OH)2 More weathering resistant
21
Carlsbad twinning
orthoclase
23
Tiger striping
Smoky
quartz
(c) The section viewed along
Milky the c axis, demonstrating24the
quartz trigonal symmetry
Simplified Mineral Identification Chart: Common Rock-forming Minerals
One perfect One perfect Three good No Two good Two good
cleavage cleavages
cleavage cleavage cleavages at cleavage cleavages at
75o and 105o at 90o 60o, 120o
color & Glassy Light Dark Glassy or Glassy, White, Dark Dark
Black Green
luster or colored colored white grey, or grey or glassy glassy
sugary white pink or or
pearly pearly
name Gypsum Graphite Chlorite Muscovite Biotite Calcite, Quartz Felspar Pyroxene Amphibole
Dolomite
SiO2
CaSO4·2H2O Carbon CaCO3 : Network
Sheet silicate
Ca, Mg(CO3)2 Chain silicates
silicate
Diff. react with
HCl
Plagioclase Orthoclase
NaAlSi3O8 KAlSi3O8
CaAlSi3O8
25
Network silicate
ל暔愄俩ڛ
ࡢࡎЗ劵 ࡢ㈩ Continental ઈ
㈩ڛ Mid-ocean Island margin arc Rift
Island arc ridge
㤣㐛Зڵ
䒟溟 ғ妧߂⸇
Spreading center
Hotspot Subducting plate
27
More
resistant
Less
resistant
Weathering
28
Magmatic Differentiation (Basaltic intrusion at Palisades of New Jersey)
THE PALISADES INTRUSION
Sandstone
Basalt
Mostly sodium-rich
Basaltic intrusion
Calcium-rich
plagioclase feldspar
and pyroxene;
no olivine
Olivine
Basalt
Magmatic differentiation
• A process by which rocks of varying composition can arise from a uniform parent
magma.
• The first minerals to crystallize from a cooling magma are the ones that are the
last to melt.
• Fractional crystallization is the process by which the crystals are formed in a
29
cooling magma and are segregated from the remaining liquid.
~1200°C ~600°C
Plagioclase Plagioclase
Olivine Plagioclase
crystals f
feldspar feldspar
f
feldspar
Pyroxene Pyroxene
Magma with
Olivine Olivine composition C
Magma with Magma with Magma with
composition A composition B composition C
Volcanoes transport magma from Earth’s interior to its surface, where rocks
are formed and gases are injected into the atmosphere 31
Country Volcano
rock
Sill
Dikes cut
Sill
across layers
of country
Sill rock…
33
(Acid)
(Basic)
ferro-magnesian 34
Classification of Igneous Rocks
• Texture
Acid Basi • Mineral compositio
c
Fine grained
Coarse grained
Igneous rocks
can be
classified by
the
proportions of
silica and
silicate
minerals they
contain.
Viscosity increasing 35
Vitric
38
Sequence of events:
formation of a fissure
eruption
39
Fissure eruption: Laki fissure, Iceland
Flood basalts:
Columbia Plateau,
Washington
40
Central eruptions:
Pyroclastic flow
Lava
Lahar 42
Pyroclasts Volcanic ash Bomb Pumice
Extrusive pyroclasts
form in violent
eruptions from lava
in the air.
The volcanic rocks that occur in Hong Kong are predominantly of rhyolitic
composition, consisting mainly of ash. These rocks were formed by violent
eruptions of ash from caldera-type volcanoes. Ash clouds from caldera-type
volcanoes are commonly so large, that they collapse under gravity and flow over the
landscape like a fiery fluid.
http://hkss.cedd.gov.hk/hkss/eng/education
/GS/eng/hkg/chapter2.htm?tab=3 45
48
Volcanic rocks alone account for approximately 50% of Hong
Kong's surface area
Tuffs (Pyroclastic) Joint
surface
Grain sizes
• Fine ash (<0.06 mm)ࢮٌࢱ
• Coarse ash (0.06-2 mm)
• Lapilli (2-60 mm) /ləˈpɪlʌɪ / ࢮٌ䮐
• Blocks and bombs (>60 mm)
+.8677XIIࠍ⚠ዙ
49
Volcanic bomb Volcanic breccia
Volcanic Breccia
50
In terms of their physical characteristics, the tuffs of Hong Kong are classified
according to the recommendations for pyroclastic rocks of the International Union
of Geological Sciences (Schmid, 1981; Le Maitre, 1989) (Figures 5.2 & 5.3).
Tuffs are classified according to particle size and the relative amount of pumice /
glass, crystal fragments and rock fragments that made up the rocks 51
Whole-rock chemical
compositions are
determined according to
the widely used total alkali
versus silica diagram
(Na2O+K2O vs SiO2) of Le
Maitre (1989)
52
http://www.cedd.gov.hk/eng/about/organisation/vol.html
Volcanic rock Caldera
⚛ኡ
Granite
Quartz
Monzonite
Columnar jointing
54
Fine ash Coarse ash
55
56
Rhyolite Lava ⍱㌻ዙ
Rhyolite is an igneous rock type with the same mineral composition as
granite but of very fine grain size, the latter resulting from the extrusion of
the molten rock at the earths surface and its consequent rapid cooling.
‘flow’ banding
Sharp Island
(Photo: G Wang)
Flow-banded lava in the Lantau Volcanic Group on the flanks
of Nei Lak Shan, Lantau Island (Sewell et al. 2000)
57
Bedding
Folding
花崗岩
花崗閃長岩
石英二長岩
Distribution of
Plutonic Rocks
in Hong Kong
Quartz 35 30 <20
Alkali 25 10 35
Feldspar
Plagioclase 25 40 35 Quartz
feldspar A P Monzonite
Biotite mica/ <10 >10 <10
Hornblende Composition of the plutonic rocks 60
(Sewell et al., 2000)
Granite Alkali-feldspar
Micro-granite
Mica
Quartz
Quartz Monzonite ीਸ਼и斴㈏
61
㣡ፇ䮳䮧ዙ
Granodiorite㣡
- granitic rocks in
which the plagioclase
feldspar content is
greater than that of the
alkali-feldspar
(Orthoclase); their
dark minerals (biotite,
amphibole) are usually
rather more plentiful
than in granite, and
the amount of quartz
is less.
62
Glossary -- Minerals
Granodiorite 花崗閃長岩
Pumice 浮石
Breccia 角礫岩 Pluton 深成火成岩
Dyke 岩牆
Porphyritic 斑狀 Phenocrysts 斑晶
Sill 岩床
Vesicular 有氣泡的 Vesicle
Vein 岩脈
phaneritic 顯晶狀 aphanitic 微晶狀
Batholith岩基
fissure 裂縫,裂隙 Laccolith岩蓋
Glossary -- Sedimentary rock - 沉積岩 diagenesis 成岩作用