Test - 08 11th JEE Main

DURATION : 180 Minutes DATE : 02/02/2025 M.MARKS : 300

Topics Covered
Physics: Full Syllabus (11th)
Chemistry: Full Syllabus (11th)
Mathematics: Full Syllabus (11th)

General Instructions:
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 75 questions. The maximum marks are 300.
4. There are three Sections in the question paper, Section I, II & III consisting of Section-I (Physics), Section-II
(Chemistry), Section-III (Mathematics) and having 25 questions in each part in which first 20 questions are of
Objective Type and Last 5 questions are integers type and all 25 questions are compulsory.
5. There is only one correct response among 4 alternate choices provided for each objective type question.
6. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
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[1]
 IMPORTANT CONSTANTS

Speed of light in free space, : 3.00 × 108 ms–1

Permeability of free space, : 4 × 10–7 Hm–1
Permittivity of free space, : 8.85 × 10–12 Fm–1
The Planck constant, : 6.63 × 10–34 Js
Rest mass of electron, : 9.1 × 10–31 kg
Rest mass of proton, : 1.67 × 10–27 kg
Molar gas constant, : 8.31 JK–1 mol–1
The Avogadro constant, : 6.02 × 1023 mol–1
The Boltzmann constant, : 1.38 × 10–23 JK–1
Gravitational constant, : 6.67 × 10–11 N m2kg–2
Acceleration of free fall : 9.8 ms–2
Rydberg Constant : 1.097 × 107 m–1
Atomic mass unit : 1.67 × 10–27 kg
Charge on proton : 1.6 × 10–19 C

IMPORTANT VALUES

2 = 1.414 ln 10 = 2.303
3 = 1.732 log102 = 0.3010
5 = 2.236 log103= 0.4770
 = 3.142 log107 = 0.845
e (Euler’s constant) = 2.718

* Use above values unless otherwise specified in a question.

❑❑❑

[2]
 SECTION-I (PHYSICS)
Single Correct Type Questions 4. Consider the following statements:
1. In the figure shown, the minimum force F to be I. A body has zero velocity and is still
applied perpendicular to the incline so that the accelerating.
block does not slide is: {Take g = 10 m/s2} II. In uniform circular motion rate of change of
acceleration is  a where  is angular
velocity vector and a is centripetal
acceleration vector.
III. An object’s speed may goes on increasing
even when magnitude of its acceleration
(1) 0 (2) 40 N
decreases.
(3) 120 N (4) 200 N
Which of the statements can be true?
(1) Only I and III (2) Only II
2. Two identical adiabatic vessels are filled with
(3) I, II and III (4) Only III
oxygen at pressure P1 and P2 (P1 > P2). The
vessels are interconnected with each other by an
5. A sphere is composed of an inner “core” of
insulting pipe. If U01 and U02 denote initial
diameter 4 cm made of Material A (density 3.0
internal energy of oxygen in first and second
g/cm3) and an outer “cladding” of outer diameter
vessels respectively and U f1 and U f2 denote final
10 cm and inner diameter 4 cm made of Material
internal energy values, then: B (density 0.5 g/cm3). If the sphere is released
U 01 P1 into a vessel containing water (density 1.0 g/cm3)
(1) = ,U f1  U f2
U 02 P2
U 01 P2
(2) = ,U f1  U f2
U 02 P1
U 01 P2
(3) = ,U f1 = U f2
U 02 P1 (1) It floats with 83% of its volume submerged
U 01 P1 inside the water
(4) = ,U f1 = U f2
U 02 P2 (2) It floats with 76% of its volume submerged
inside the water
3. A particle executes SHM on the x-axis. Its (3) It floats with 66% of its volume submerged
position x as a function of time t is: inside the water
 (4) It sinks

x ( t ) = A sin  t +  . Match each event in
 3
6. Inside a closed furnace held at a temperature of
Column-I to the correct time instant when this
400 K, we have a black body. A hole of area 10
event first occurs after t = 0.
cm2 is opened in the furnace so that sunlight starts
Column-I Column-II falling on black body. The intensity of sunlight is
A The particle is at its mean P  1000 W/m2. When seen, in the steady state
t=
position 6 (1) The black body and furnace can’t be
B The particle has the same Q  distinguished.
t=
speed as at t = 0 8 (2) The black body will appear darker than the
C The particle is at rest R  furnace
t= (3) The black body will appear brighter than the
3
D The magnitude of S 2 furnace
t= (4) Information insufficient
acceleration of the particle 3
is half its maximum
acceleration 7. It takes 100 kJ heat to raise the temperature of a
sample of an ideal monoatomic gas from 20°C to
T 
t= 120°C at constant pressure. The amount of heat
2
needed (in kJ) to raise the temperature of the same
A B C D
sample of gas from 120°C to 220°C at constant
(1) S Q P R
volume is:
(2) S R P T
(1) 60 (2) 166.7
(3) Q R P T
(3) 140 (4) 71.4
(4) Q P S R
[3]
8. A planet of core density 3 and outer crust of vx vx
(1) (2)
density  has small tunnel in core. A small 2 2
4 2
particle of mass m is released from end A then
vx 2 vx
time required to reach end B: (3) (4) 2
4

13. Two cuboidal blocks made of different materials

of thermal conductivity K and 3K are placed end
to end between two heat reservoirs maintained at
constant temperature TA and TB (such that TA >
 1  TB). The blocks have the same area of cross-
(1) (2)
G 2 G section, but lengths L and 2L respectively. The
temperature at the interface between the blocks is:
1 1
(3)  (4) 2
G G

9. A simple pendulum consists of metal wire of

coefficient of linear thermal expansion α (<<1) 1
attached to a heavy bob. The time period of this
(1) T = (TA + 6TB )
7
pendulum on a cold winter day with temperature 1
5°C is TC, and its time period on a hot summer (2) T = ( 6TA + TB )
7
T
day with temperature 35°C is TH. The ratio C is 1
TH (3) T = ( 2TA + 3TB )
5
close to: 1
(1) 1 + 30α (2) 1 – 30α (4) T = ( 3TA + 2TB )
5
(3) 1 + 15α (4) 1 – 15α
14. A physical quantity A is dependent on other four
10. A transverse wave is passing through a stretched
physical quantities p, q, r and s as given below
string with a speed of 20 m/s. The tension in the
string is 20 N. At a certain point P on the string, it pq
A = 2 3 . The percentage error of measurement
is observed that energy is being transferred at a r s
rate of 40 mW at a given instant. Find the speed in p, q, r and s 1%, 3%, 0.5% and 0.33%
of point P. respectively, then the maximum percentage error
(1) 40 cm/s (2) 20 cm/s in calculation of A is:
(3) 2 mm/s (4) 20 mm/s (1) 2% (2) 0%
(3) 4% (4) 3%
11. A ball of mass ‘m’ is released from the top of a
smooth moveable wedge of mass ‘m’. When the 15. An equilateral triangle ABC is cut out of thin
ball collides with the floor, velocity of the wedge metallic sheet. The triangle is placed on a smooth
is ‘v’. Then the maximum height attained by the horizontal table and its centroid is fixed such that
ball after an elastic collision with the floor is: the triangular lamina is free to rotate about an axis
(Neglect any edge at the lower end of the wedge). perpendicular to its plane passing through
centroid. Two horizontal forces F1 and F2 are
applied on the triangle at the vertices A and B as
shown. The forces are respectively directed
parallel to side BC, and perpendicular to side AB.
If the triangle remains in equilibrium, the correct
2v 2 v2 relation between F1 and F2 is:
(1) (2)
g 4g
4v 2 v2
(3) (4)
g 2g

12. A closed organ pipe of length  is sounded

together with another closed organ pipe of length
 + x (x < < ) both in fundamental mode. If v = (1) 2 F1 = 3F2 (2) F1 = 3F2
speed of sound, the beat frequency heard is: (3) 3F1 = 2 F2 (4) 3F1 = F2

[4]
16. The average degree of freedom per molecule of a
gas is 6. The gas performs 25 J work, while
expanding at constant pressure. The heat absorbed
by the gas is:-
(1) 75 J (2) 100 J
19 21
(3) 150 J (4) 125 J (1) mR 2 (2) mR 2
5 5
17. A uniform circular disc of radius a centred at O is 31 39
(3) mR 2 (4) mR 2
taken. A circular portion of radius b has been 20 20
removed from it as shown in the figure. If the
centre of hole is at a distance c from the centre of Integer Type Questions
the disc, the distance x2 of the centre of mass of 21. A ball is thrown vertically upwards with a speed
the remaining part from the initial centre of mass of 10 m/s from the top of a tower 200 m high and
O is given by:
another is thrown vertically downwards with the
same speed simultaneously. The time difference
between them in reaching the ground (g =10 ms–2)
is x seconds. Find x.

22. A particle executes SHM on the Y-axis with its

mean position at the origin. The speed of the
ab 2 cb 2 particle when it is at y = –1 cm is 24 cm/s, and its

( a 2 − b2 ) ( a 2 − b2 )
(1) (2)
speed when it is at y = 5 cm is 12 2 cm/s. The
maximum magnitude of acceleration of the
bc 2 ca 2 particle during the SHM (in cm/s2) is_____.
( a 2 − b2 ) ( c2 − b2 )
(3) (4)
23. When a longitudinal force is applied on a uniform
rod of diameter d made of Material P, the strain
18. A liquid is kept in a cylindrical vessel. When the produced is 0.01%. If the same magnitude of
vessel is rotated about its axis, the liquid rises at longitudinal force is applied on a uniform rod of
its walls. If the radius of the vessel is 0.05 m and diameter 2d of Material Q, the strain produced is
the speed of rotation is 2 revolutions per second, 0.02%. The ratio of the Young’s modulus of the
the difference in the heights of the liquid at the Y
centre and at the walls of the vessels will be materials, P is equal to_____.
YQ
(take g = 10 ms–2 and π2 = 10)
(1) 2 cm (2) 4 cm
(3) 1 cm (4) 8 cm 24. In a free space A big particle of mass (3 + m) kg is
initially at rest. It blasts into 3 pieces, such that a
19. A particle of mass m is projected horizontally particle of mass 1 kg moves along x-axis with
with velocity v from the top of a building of
velocity of magnitude 2 m/s and a particle of mass
height h. just before it strikes the horizontal
ground, the magnitude of angular momentum of 2kg moves with velocity of magnitude 1 m/s
the particle about the point of projection is: perpendicular to direction of 1 kg particle. If the
third particle moves with velocity of magnitude
2 m/s, then m (in Kg) is_____.

25. Two equilateral triangles of side lengths a and 2a

respectively are cut out from a large thin, uniform
(1) 2 mvh (2) 3 mvh
metallic sheet. The moment of inertia of the first
1 triangle about one of its side is I1 and the moment
(3) mvh (4) mvh
2 of inertia of the second triangle about one of its
I
20. Three identical solid spheres of mass m and radius sides is I2. The ratio 2 is equal to____.
I1
R each are joined together to from a rigid body
such that their centres form and equilateral
triangle. The moment of inertia of this body about
an axis passing through the centres of two of the
spheres is:
[5]
 SECTION-II (CHEMISTRY)
Single Correct Type Questions 33. Correct order of ionic size is
26. 1 mole of K 2 Cr2 O7 cannot oxidise (1) Be2+  Li+ < Na+ < Mg2+
(1) 3.6 moles of FeSO4 to Fe2 (SO4 )3 (2) Be2+ < Mg2+  Li+ < Na+
(3) Mg2+ < Na+ < Be2+ < Li+
(2) 1 mole of FeSO4 to Fe2 (SO4 )3
(4) Li+ < Be2+ < Mg2+ < Na+
(3) 1.8 moles of Sn2+ to Sn4+
(4) 4 moles of Sn2+ to Sn4+ 34. pH of HCl aq. solution is 6. If it is 100 times
diluted, then the pH of diluted solution will be
27. In which transition, in a sample of H atoms, only
(1) 8 (2) 6
one type of photon is emitted?
(3) 6.97 (4) 6.5
(1) n = 4 → n = 2 (2) n = 3 → n = 1
(3) n = 4 → n = 1 (4) n = 2 → n = 1
35. Which of the following undergoes sulphonation
28. In which of the following groups all the members fastest?
SO3H
have linear shape?
(1) NO 2 , N3− , ICl2 +
(2) N3− , I3− , NO2+ (1)
(3) XeF2 ,C2 H 2 ,SO2
(4) CO2 , BeCl2 ,SnCl2 CH3

CH N(Me) 3
29. The term – T  Stotal at constant temperature and
pressure is known as
(1) Gibb’s function (2) Bohr’s function (2)
(3) Pauli’s function (4) Helmholtz function
N(Me)3
30. The correct order of magnitude of heat of
hydrogenation/C atom is
(3)

CH2 CH 2 N(Me) 3

(4)
(1) x > y > w > z (2) y > x > w > z
(3) y > z > w > x (4) z > x > y > w
36. Which of the following conformer of ethylene
31. Correct order of bond length is glycol is most stable?
(1) F2  N 2  O2  Cl2 (1) Gauche (2) Fully eclipsed
(2) N 2  F2  O2  Cl2 (3) Anti (4) Partially eclipsed
(3) F2  Cl2  N 2  O2
(4) N 2  O2  F2  Cl2 37. Predict the product of the following reaction
CH OH
⎯⎯⎯⎯
3
o → Product
20 C
32. Find the enthalpy of combustion of propane gas
from the following data. Bond energy (kJ/mol)
BE C− H = a1 BE O = O = a 2 (1)
BE C = O = a 3 BE O− H = a 4
BE C−C = a 5
(2)
(1) 6a1 + a 5 + 5a 2 − 3a 3 − 4a 4
(2) 8a1 + 2a 5 + 5a 2 − 6a 3 − 8a 4
(3)
(3) 6a1 + a 5 + a 2 − a 3 − a 4
(4) 8a1 + 2a 5 + 5a 2 − 3a 3 − 8a 4
(4)

[6]
38. An element A in a compound AB has an 43. Which of the following has maximum number of
oxidation number –n. It is oxidised by Cr2O7 2− radial nodes in the curve plotted between 2(r)
(probability of finding electron) versus radius?
in acidic medium. In an experiment 1.68 × 10–3
(1) 3p
mole of K 2Cr2O7 was required for 3.36 × 10–3 (2) 4d
mole of the compound. Calculate the new (3) 5p
oxidation state of A. (Assume Bn+ to be inert) (4) 4f
(1) n – 3 (2) 3 – n
(3) 3 (4) –n –3 44. Hydrogen peroxide on decomposition gives
water and oxygen gas. Number of moles of
39. Which one of the following will not change pH hydrogen peroxide required for the formation of
of (10 ml 0.1 M NH 4Cl + 10 ml 0.1 M NH4OH) 16 g oxygen gas is
(1) 1 (2) 0.5
mixture on addition? (3) 2 (4) 3
(1) 10 ml water
(2) 10 ml 0.1 M NH 4OH 45. The correct order of 3rd ionisation energy is
(3) 10 ml 0.1 M NH 4Cl (1) Mg > Al > P > Si
(2) Mg > Si > P > Al
(4) Solid NH 4Cl
(3) P > Si > Al > Mg
(4) P > Al > Si > Mg
40. During the reaction given below
CO + I2O5 → CO2 + I2 Integer Type Questions
What are the equivalent weights of CO and I 2 O5 46. K sp of a substance MX 2 is 4 × 10–12 at
if their molar masses are M1 and M 2 temperature T. If molar mass of substance is 120
g/mol, then its solubility (in g/L) at temperature
respectively?
T is x, find 1000x.
M1 M 2
(1) ,
4 5
47. The gm equivalent weight of As 2S3 in given
M1 M 2
(2) , reaction is [At. mass S : 32, As : 75),
2 5
use (5.5)–1 = 0.18]
M1 M 2
(3) ,
4 10
14H2O + As2S3 → 2AsO4−3 + 3SO2 + 22e− + 28H+
M1 M 2
(4) , (Nearest Integer)
2 10

48. A thermally insulated vessel is divided into two

41. Which of the following has maximum keto
compartments A and B by a partition of
content? (Consider maximum values including
insulating material. Compartment A has 0.1 mole
100%)
of Helium at 427ºC and 1 atm and compartment
B has x mol of Neon at 127ºC and 1 atm. If
(1) (2) partition is removed and final temperature of gas
is 227ºC, then the value of 10x is____. [Assume
3R
Cv = for both gases]
2
(3) (4)

49. 10 g impure CaCO3 (lime stone) is heated to give

42. Relative basic strength of following compounds CO2 which is allowed to pass in water to form
is H2CO3. This solution is completely neutralised
by 500 ml of 0.2 M NaOH solution. The % purity
of lime stone is ___.

50. An oxide of vanadium has magnetic moment of

2.83 BM. The oxidation state of vanadium in its
(1) IV > II > III > I (2) II > IV > I > III given oxide would be
(3) I > III > II > IV (4) III > I > IV > II

[7]
 SECTION-III (MATHEMATICS)
Single Correct Type Questions
51. The value of ‘p’ so that both the roots of the 58. The real number x and y satisfy the equation xy =
equation (p – 5)x2 – 2px + (p – 4) = 0 are x 
positive, one is less than 2 and other is lying sin (2t) and = tan ( t ) where 0  t  . The
y 2
between 2 and 3, lies in the interval 2 2
value of x + y , is:
 49 
(1)  , 24  (1) 2 (2) 1
 4  (3) 2 (4) 4
(2) (5, )
 49 
(3) ( −, 4 )   ,   59. Among 10 people, everyone like at least one
 4  drink out of tea and coffee. 6 people like only
(4) (–, 4) coffee, 2 people like only tea, then consider the
statements
52. ABC is a variable triangle such that A is (1, 2), B S-I The number of people who like tea is 4
and C lie on the line y = x + λ (where λ is a S-II The number of people who like coffee is 5.
variable), then locus of the orthocenter of triangle (1) S-I is true, S-II is false
ABC is (2) S-I is false, S-II is true
(1) (x – 1)2 + y2 = 4 (2) x + y = 3 (3) Both S-I and S-II are true
(3) 2x – y = 0 (4) x = 2y (4) Both S-I and S-II are false

60. Point of intersections of the graph of f (x) and g

ax 2 + bx + c 1
53. If lim = then (x) are solutions of equation f (x) = g(x). Let
x→
1
2
( 2 x − 1)2 2 |x – 1| + |x – 2| = k, then match the value of k
with number of solutions of given equation and
lim
( x − a )( x − b )( x − c ) is select the correct option
x →2 x−2 Value of k Number of solutions
1 A k = –2 P Zero
(1) 0 (2) B k=0 Q 1
2
C k=1 R 2
(3) 2 (4) 6 D k=4 S Infinite
A B C D
54. The average marks of 10 students in a class was (1) P Q R S
60 with a standard deviation 4, while the average
(2) P P S R
marks of other ten students was 40 with a (3) P P Q S
standard deviation 6. If all the 20 students are (4) Q R P P
taken together, their standard deviation will be
(1) 5 (2) 7.5 61. Equation of the smallest circle passing through A
(3) 9.8 (4) 11.2 and B, where A and B are the intersection points
of circle x2 + y2 – 4x – 4y + 4 = 0 and line 4x + 4y
55. A straight line is drawn through P (4, 5) to meet = 5 is
the axis of x and y at A and B respectively. If the 2 2
rectangle OACB is completed, then locus of C,  3  3 7
(1)  x −  +  y −  =
is:  8  8 32
x y
+ =1
5 4 (2) (x – 1)2 + (y – 1)2 = 72
(1) (2) + =1
4 5 x y (3) (x – 2)2 + (y – 2)2 = 1
2 2
4 5 x y  5  5 7
(3) + =1 (4) + =1 (4)  x −  +  y −  =
x y 5 4  8  8 32

2
3  A   5A  
24
1 
56. If cos A = , then 32sin   sin  = 62. If 1 + x = 3 x, then   x n − n  is equal to:
2
4 2  2  n =1  x 
(1) 7 (2) 8 (1) 0 (2) 48
(3) 11 (4) 15 (3) –24 (4) –48
57. If lines x – y + 2 = 0 and 2x – y – 2 = 0 meet at a 63. Given (1 – 2x + 5x2 – 10x3) (1 + x)n = 1 + a1x +
point P then distance of focus of the parabola y2 =
8x from the point ‘P’ is: a2x2 + … and a12 = 2a2 then the value of n is:
(1) 10 (2) 20 (1) 6 (2) 2
(3) 5 (4) 3
(3) 30 (4) 40

[8]
64. Consider the word ‘CARCASSONNE’. Words (3) 1 (4) Not defined
are formed using all the letters of this word. If
number of words which contain the word ‘CAR’ 70. Value of
and vowels are separated is k(5!) then k is equal 4sin 9 sin 21 sin 39 sin 51 sin 69 sin 81
to: is
sin 54
(1) 157 (2) 315 equal to
(3) 630 (4) None of these 1 1
(1) (2)
65. If α, β are the roots of equation x2 + x – 1 = 0, 16 32
1 1
4 (  + 1) +  4 (  + 1)
4 4
(3) (4)
then the value of is 8 4
 2 + 2 +  + 
equal to: Integer Type Questions
1 1 71. Given that α, γ are the roots of the equation
(1) (2) − Ax2 – 4x + 1 = 0 and β, δ are the roots of the
2 2
(4) –2 1 1 1
(3) 2 equation of Bx2 – 6x + 1 = 0, such that , ,
  
66. On the sides AB, BC, CA of a ABC, 3, 4, 5 and
1
are in A.P., then A + B is
distinct points (excluding vertices A, B, C) are 
respectively chosen. The number of triangles that
can be constructed using these chosen points as 72. In a triangle ABC, if A(2, –1) and 7x – 10y + 1 =
vertices are: 0 and 3x – 2y + 5 = 0 are equations of an altitude
(1) 220 (2) 215 and an angle bisector respectively drawn from B,
(3) 210 (4) 205 then equation of BC is ax + by + 17 = 0 then |a –
b| is_____.
67. The number of real value(s) of θ in the interval
1 + i cos  73. An eight digit number is formed from 1, 2, 3, 4
[0, 2π] for which the expression is a
1 − 2i cos  such that product of all digits is always 3072, the
real number is (n  I)
(1) 1 (2) 2
( )
total number of ways is k . 8C5 , where the value

(3) 3 (4) 0 of k is

74. The number of ways in which 3 girls and 5 boys

68. If a, b, c are positive numbers then maximum
can be seated at a round table such that girls are
value of a2 bc2, when a + b + c = 15, is
(1) 24 34 (2) 24 35 together and boys are together, is
5 4
(3) 2 3 (4) 25 35
75. The number of different terms in the expansion of
(x + 1) (1 + x)50 is
3
69. log 1  sin 2 equals to:
cosec2 8
8 8
(1) 0 (2) 1/2

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[9]
 Test - 08 11th JEE Main

DURATION : 180 Minutes DATE : 02/02/2025 M.MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (4) 26. (4) 51. (1)
2. (4) 27. (4) 52. (2)
3. (2) 28. (2) 53. (4)
4. (3) 29. (1) 54. (4)
5. (3) 30. (3) 55. (3)
6. (2) 31. (4) 56. (3)
7. (1) 32. (2) 57. (4)
8. (2) 33. (2) 58. (3)
9. (4) 34. (3) 59. (1)
10. (2) 35. (4) 60. (2)
11. (1) 36. (1) 61. (4)
12. (2) 37. (1) 62. (4)
13. (3) 38. (2) 63. (1)
14. (3) 39. (1) 64. (2)
15. (1) 40. (4) 65. (2)
16. (2) 41. (3) 66. (4)
17. (2) 42. (3) 67. (2)
18. (1) 43. (3) 68. (2)
19. (3) 44. (1) 69. (3)
20. (2) 45. (2) 70. (3)
21. (2) 46. (12) 71. (11)
22. (84) 47. (11) 72. (4)
23. (8) 48. (2) 73. (23)
24. (2) 49. (50) 74. (720)
25. (16) 50. (3) 75. (52)

[1]
 SECTION-I (PHYSICS)
1. (4) (ii) The particle will have the same speed as at
t = 0 when it is at the same position as at t =
 2
0, i.e. at phase angle 2 =  − =
3 3
 2  
 − 
  −   3 3 
N = F – mg cos θ ….(i) t =  2 1  =  =
f – mg sinθ = 0 ….(ii)     3

For limiting case, force applied is minimum. (iii) The particle is at rest when it is at its right
μ(F – mg cosθ ) = mg sinθ 
extreme, i.e. at phase angle 2 =
mg sin  2
F= + mg cos 
 T  
( 2 − 1 ) =  − 
T
There, t =
 sin   2 2  2 3 
F = mg  + cos  
   T 
= =
12 6
 sin 37 
F = 100  + cos37 
 1/ 2  amax 2 A A
(iv) a =  2 x =  x=
 3 4 2 2 2
F = 100  2  +  = 200 N So, the fist time this will happen after t = 0 is
 5 5
A
when the particle is at x = . Since at t = 0
2. (4) 2
U  nT  PV the particle is at x =
3
A, the fist time that it
Initially V1 = V2 2
P1 > P2 U 01  U02 A 
will be at x = is at phase angle 2 =
U 01 P1 2 6
and =
U 02 P2 Therefore,
T 5  
( 2 − 1 ) =  −  = =
Finally T T
t =
P = Same 2 2  6 3  4 2
V = same
U = same 4. (3)
U f1 = U f2 I. Motion under the gravity when object at it’s
highest point.
3. (2) II. Circular motion
2
Time period of the given SHM, T =

In general, to find the interval between two events
during an SHM, first find the phase angles
associated with those two events, say ϕ1 and ϕ2.
Then, the time interval between the events will be: a a
 a = a  =
T t t
t = ( 2 − 1 )
2 da
 = w a
  dt
So, for the SHM x ( t ) = A sin  t +  , the
 3 III. When acceralion along the dirn of velocity

particle is at phase angle 1 = at t = 0 i.e. at 5. (3)
3
Weight of sphere in air,
3
x=
2
A and going towards the right extreme (x  4 3
WA =  ( 2 ) ( 3 ) +
 3 3
(
4 3
) 
5 − 23 ( 0.5 )  (10 )

= +A)
4
(i) The particle will be at its mean for the first = ( 825 )
time when it is phase angle ϕ2 = π Therefore, 3
 T 2
( 2 − 1 ) =   −  = =
T T Let the fraction of the volume of the sphere that is
t = immersed in water be x
2 2  3  3 3
[2]
 Buoyant force acting on the sphere, TC
 = 1 − 15
  4 3   4 TH
B =  x  ( 5 )   (1)(10 ) = (1250 ) x
  3  3
10. (2)
4 4
In equilibrium, WA = B  ( 825) = (1250 ) x P(x, t) = μ (Aω)2 Vwave cos2(kx – ωt)
3 3
( )
2
 x = 0.66 T vp 20 2
40  10−3 = =  vp
Vwave 20
6. (2) 4
= v 2p  0.2 m/s = v p = 20cm/s
dH 100
= AT 4
dt
dH 11. (1)
= 5.67  10−8  ( 400 )
4
dt / A
= 5.67  16  16 > 1000 W/m2

7. (1)
At constant pressure, Q = nCPT
vx = v
 5R 
 Q1 = n   (120 − 20 ) vrelx = 2v
 2 
vy
At constant volume, Q = nCv T = tan 45
2v
 3R 
 Q 2 = n   ( 220 − 120 ) vy = 2v
 2 
v 2y 2v 2
Q2 3 Rmax = =
So, = 2g g
Q1 5
3
 Q2 = ( Q1 ) = 60 kJ 12. (2)
5 v v
fb = −
4 4( + x)
8. (2)
At some distance from centre inside core v1 1  v +x− 
=  − =  
 4 3 
 G 3 r ( 3 ) m 
4 ( + x )  4  ( + x ) 
F = −  vx
 r2  ( x  )
  4 2
ma = –4πGmr
13. (3)
a = –4πGr
Let the area of cross-section of the blocks be A0
2
so  = 4G = Let the temperature at the interface be T
T Since the rate of heat flow through the blocks
or T = 2 
1
=
 KA0 (TA − T ) ( 3K ) A0 (T − TB )
4G G
must be equals, =
L 2L
1  1
Solving, we get T = ( 2TA + 3TB )
Now time for A to B
2 G 5

9. (4) 14. (3)

A 1 P 1 q 2r s
L = + + +3
Time period of a simple pendulum, T = 2 A 2 P 2 q r s
g
= 0.5 + 1.5 + 1 + 1 = 4%
LC L
So, TC = 2 and TH = 2 H
g g 15. (1)
Also, LH = LC (1 +  ( 35 − 5) )
Let the side length of the triangle be a
For equilibrium,
 LH = LC (1 + 30 ) Clockwise torque due to F1 – Anti-clockwise
1/2 torque due to F2
T L  1
Therefore, C =  C  =  a  a
TH  LH  (1 + 30 )1/2  F1   = F2  2   2 F1 = 3F2
 3  
[3]
16. (2) 20. (2)
For constant pressure process.
Work done (W) = nRT.
 25 
 T =  
 nR 
Now, for above process f = 6,
 f 
So C p 1 +  R = 4 R The axis of rotation passes through the centres of
 2
two of the spheres, A and B, and the axis is at a
 Heat absorbed = nCP T
distance 3R from the centre of the third sphere, C.
25
= n  4R  = 100 J So, using parallel axis theorem for the third
nR
sphere, the total moment of inertia,
2  2
( )
2 21 2
17. (2) I = 2   mR 2  +  mR 2 + m 3R  = mR
5  5  5
MX − m1 x1 a ( 0 ) − b ( c )
2 2
X cm = =
M − m1 a 2 − b2 21. (2)
−cb 2 2  10
X cm = t = = 2sec
( a 2 − b2 ) 10

22. (84)
18. (1) We can use the result for speed as a function of
2 position,
( 4 )2   
1
2 R 2  20  = 0.02 m v ( y ) =  A2 − y 2
h = =
2g 20
Therefore,  A2 − ( −1) = 24 and
2

19. (3)  A2 − 52 = 12 2
Time taken by the particle to reach the ground, Diving the equations and squaring,
2h A2 − 1
T= = 2  A = 7 cm
g
A2 − 25
Distance of the point of landing from the foot of 24
Therefore,  = = 12 rad/s
2h 72 − 1
the building, R = vT = v
g
So, the maximum acceleration,
amax = 2 A = (12 )( 7 ) = 84 cm/s2
Let us take the point of projection as the origin,
the +X direction towards right and the +Y
direction upwards
23. (8)
Then, velocity of the particle just before landing,
Stress F
v = viˆ − 2 gh ˆj Young’s Modulus = and Stress =
Strain  d 2 
And position of the particle just before landing,  
 4 
2h ˆ ˆ
r =v i − hj YP  Strain Q   2d   0.02 
2
g =   =  ( 4) = 8
YQ  Strain P   d   0.01 
Therefore, just before landing, the angular
momentum of the particle about the point of
24. (2)
projection,
 2h  Resultant momentum = ( 2 )2 + ( 2 )2 =2 2
L = r  ( mv ) = m  v
g
(
iˆ − hjˆ   viˆ − 2 gh ˆj )
  Momentum 2 2
Mass = = = 2 kg
= mvh kˆ Velocity 2

[4]
25. (16) Now, the mass m will itself be proportional to a2
We do not need the exact formula for the moment (because the mass will proportional to the area of
of inertia of a triangular plates about one of its the triangle)
sides to find the answer to this question. So, the moment of inertia is proportional to a4
If the side length of the triangle is a and the mass
of the triangle is m, then the moment of inertia
will be proportional to ma2.
SECTION-II (CHEMISTRY)
26. (4) Ring is most activated in this case due to
Meq of K 2 Cr2 O7 is greater than all the other maximum number of hyperconjugable hydrogens
given species. among all.

27. (4)
36. (1)
Only in n = 2 → n = 1 (one single type of photon
is emitted) Due to intermolecular H-bonding in gauche form,
it is the most stable conformer of ethylene glycol.
28. (2)
N3− , I3− , NO2+ are linear. 37. (1)

29. (1)
G = −TSuniverse
Solvent is polar, 2° carbocation will be formed
first. Then methyl and hydride shift occur.
30. (3)
Stability Order:
Conjugated > Isolated > Cumulative and (y) is 38. (2)
Anti aromatic. n factor of An– = 3
HOH 
1 Hence, final O.S. = 3 – n
Stability of Alkene
39. (1)
31. (4) pH of solution does not change on dilution
Cl2  F2  O2  N 2
( 3p − 3p ) 2p − 2p B.O = 2 B.O = 3
40. (4)
32. (2) For CO, x = 2
C3 H8 + 5O2 → 3CO2 + 4H 2O For I2O5 , x =10
H = −6 ( C = O ) + 8 ( OH ) + 2 ( C − C ) + 8 ( C − H ) + 5 ( O = O )
41. (3)
= 8a1 + 5a 2 + 2a 5 − 6a 3 − 8a 4

33. (2) There are no enolisable H in

Correct order : Na+ > Li+  Mg2+ > Be2+

34. (3)
pH = 6
[H+] = 10–6 42. (3)
Upon dilution 100 times
[H+] = 10–8
New pH = 6.97
sp2 hybridised N-atom (more electronegative than
35. (4) sp3 hybridised N-atom) is less basic.
CH2CH2 N(Me)3 Due to aromaticity, Pyrole is least basic.

43. (3)
5p has 3 radial nodes.

[5]
 49. (50)
44. (1) CaCO3 → CaO + CO2
1 CO2 + H2O → H2CO3
H2O2 → H2O + O2
2 H2CO3 + 2NaOH → Na2CO3 + 2H2O
n H 2O2 = 1 m mole of NaOH = 0.2 × 500 = 100
 100 
 m mole of H2CO3 =   = 50
45. (2)  2 
On the basis of electronic configuration m mole of CaCO3 = 50
Mg2+– s0, Si2+ – s2, Al2+– s1, P2+– s2p1 Mole of CaCO3 = 50 × 10–3
Mass of CaCO3 = 50 × 10–3 × 100 = 5 g
46. (12) 5 
% purity of CaCO3 =   100  = 50%
KSP = 4s3 = 4 10−12  10 
s = 10–4 molar
= 10–4 × 120 g/L 50. (3)
= 1.2 × 10–2 g/L n(n + 2) = 2.83
 n=2
47. (11)
V+3 → [Ar] 4s0 3d2
gm equivalent wt. of
75  2 + 32  3
As 2S3 = 11.18
22

48. (2)
Heat gain by Neon = Heat loss by Helium
 n1Cv (500 – 400) = 0.1 × Cv (700 – 500)
 n1 × 100 = 0.1 × 200
n1 = 0.2

SECTION-III (MATHEMATICS)
51. (1) 1
2p p−4
 ax 2 + bx + c = ( 2 x − 1)2
x2 − x+ =0 2
p −5 p −5 1
 ax 2 + bx + c = 2 x 2 − 2 x +
2
1
 a = 2, b = −2, c =
2

( x − 2 )( x + 2 )  x −
f (0) > 0, f (2) < 0, f (3) > 0 1
p−4 
f ( 0)  0  0 ….(1)  lim  2
= 4
3
=6
p −5 x →2 x−2 2
p − 24
f ( 2)  0  0 ….(2)
p −5 54. (4)
4 p − 49 n1 = 10, n2 = 10
f ( 3)  0   0 ….(3)
p −5 average m1 = 60, m2 = 40
 49  1 = 4, 2 = 6
Intersection of (1) (2) and (3) gives  , 24 
 4  Standard deviation of combined series

n112 + n2 22 n1n2 ( m1 − m2 )

2
52. (2) = +
As altitude from A is fixed and orthocentre lies n1 + n2 ( n1 + n2 )2
on altitude hence x + y = 3 is required locus.
10  16 + 10  36 10  10 ( 60 − 40 )
2
53. (4) = +
ax 2 + bx + c 1
10 + 10 (10 + 10 )2
lim =
x→
1
2
( 2 x − 1) 2 2 = 8 + 18 + 100 = 126 = 11.2

[6]
55. (3)

 k = 1   solution
Equation of any line through P (4, 5) with slope k < 1  No solution
m will be k > 2  2 solution
y – 5 = m (x – 4)  mx – y = 4m – 5
 4m − 5  61. (4)
Clearly A  ,0  and (0, 5 – 4m)  C (h, k)
 m 
k −k
Now = −m  m =
h h
 −k 
 k = 5 –4m = = 5 − 4  
 h 
4y 4 5
 Locus of C (h, k) is y = 5 +  + =1 7
x x y  r=
32
Foot of perpendicular from (2, 2) on the line 4x +
56. (3)
16 (cos 2A – cos 3A) 5 5
4y = 5 is  , 
16 (cos2 A – 1 – 4 cos3 A + 3cos A) 8 8
2 2
 9 27 3  3   5  5 7
16  2  − 1 − 4  +   Required circle is  x −  +  y −  =
 16 64 4   8  8 32
18 – 16 – 27 + 36
38 – 27 = 11 62. (4)
Given, x 2 − 3 x + 1 = 0
57. (4)
y2 = 8x, focus S (2, 0) 3  3− 4 3i  
 x= = = cos  i sin
P (4, 6), PS = 40 2 2 6 6
n n
 x n = cos  i sin and
58. (3) 6 6
xy = 2sint cos t 1 n n
n
= cos  i sin
x sin t x 6 6
=
y cos t 1 n
2 2 2 2
 xn − n
= 2i sin
x = 2sin t, y = 2cos t x 6
x 2 + y2 = 2 2
 n 1  2 n
  x − n  = −4sin 6
 x 
59. (1)
2
n(T  C) = 10 24
 1 
n (T) + n(C) – n(T  C) = 10
Hence,   xn − xn 
n =1
n (T) = 4, n(C) = 8   2 24 
= −4 sin 2 + sin 2 + .... + sin 2
 6 6 6 
60. (2)
−4 (12 ) = −48

63. (1)
(1 – 2x + 5x2 – 10x3) (1 + x)n = 1 + a1x + a2x2 +
…

[7]
 a1 = coeff of x = nC1 – 2 = n – 2
a2 = coeff of x2 = nC2 – 2nC1 + 5 69. (3)
 n2 − n  E = log  3 
n 2 − 4n + 4 = 2  − 2n + 5   1−cos 4 
 2  1
 
   
41−cos  
2 
 4  
n=6
 1 
1+ 2   2 +1
64. (2) = log 1   = log 2  
1  
2  2 2 
4( )
CAR A, O, E, C, S, S, N, N    2 −1
41− 
6! 7 6! 7!  2 
 C3  3! =   3!
2! 2! 2!2! 4!3!  2 +1
= log 2 +1 
  =1
65 2 2 
=  7  6  5! = 15  21  5! 2 2
4
65. (2)
70. (3)
We have, x2 + x – 1 = 0
4sin 9 sin 21 sin 39 sin 51 sin 69 sin 81
 α + β = –1; αβ = –1
sin 54
4 (  + 1) +  4 (  + 1)
4 4
4sin 9 cos9  sin 39 cos39 sin 21 cos 21
=
 + ++
2 2
sin 54
+ 1 sin18  sin 78 sin 42
= =− =
2sin 54
(  +  )2 − 2 +  +  2
sin18 ( cos36 + cos 60 ) 1
= =
4 sin 54 8
66. (4)
Total number of triangle =

( ))
71. (11)
12
C3 − ( 3
C3 + 4C3 + 5C3 Ax2 – 4x + 1 = 0 (α, γ)
x2 – 4x + A = 0 (1/α, 1/γ)
2a + 2d = 4  a + d = 2
Bx2 – 6x + 1 = 0 (β, δ)
x2 – 6x + B = 0 (1/β, 1 / γ)
= 220 – (1 + 4 + 10) = 205 α, β, γ, δ – H.P.
1 1 1 1
, , , − A.P.
67. (2)    
1 + i cos 
=
(1 + i cos  )(1 + 2i cos  ) B = 8, A = 3, A + B = 11
1 − 2i cos  (1 − 2i cos  )(1 + 2i cos  )
72. (4)
1 − 2cos 2  + 3i cos 
= Co-ordinate of B will be point of intersection of
1 + 4cos 2  7x – 10y + 1 = 0, 3x – 2y + 5 = 0, B (–3, –2)
3cos  Image of A in angle bisector of B lies on line BC.
is a real number only if =0
1 + 4cos 2 
i.e. if cosθ = 0

i.e. if  =
( 2n + 1)  , n  I
2

Line joining B (–3, –2) and (–4, 3) is

68. (2)
BC  5 x + y = –17
a c
2  + b + 2  2 2 1/5
2  2    a bc 
 4  73. (23)
5  2 
3072 = 210  3
24 35  a2 bc2

[8]
 8! 75. (52)
4  4  4  4  4  3 11 → = 8C5  3
5! 2! (x + 1) [50C0 50C1 x + …….+50C50 x50]
8! = A0 + A1x + A2x2 + ….. + Ax51
4  4  4  4  2  2  3 1 → = 8C5  5  3
4! 2!
8!
4 4 4 2 2 2 23 →
3!  4!

= 8C5  5 = 23. 8C5

74. (720)
Girls together 3! And boys together 5!
Number of Ways = 3! × 5! = 720

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