16-06-2025

2302CJA101032250002 JA

PART-A-PHYSICS

SECTION-I(i)

1)

A balloon starts rising from ground with some initial velocity. A stone is dropped from balloon. This
stone always reaches ground with same speed no matter from what height it was dropped. Mark the
correct statement (Assume acceleration due to gravity does not vary with height)

Balloon decelerates with a value

(A)

(B) Balloon decelerates with a value g

(C) Balloon decelerates with a value 2g
(D) Balloon accelerates with a value g

2) A toy plane is flying horizontally at 10 m/s at height 80 m above the ground towards a man on the
ground as shown. When plane is 60m away horizontally from man, a ball is dropped by the plane.
Find speed of man (assumed uniform) so that he is able to catch the ball just before it strikes the

ground (g = 10 / s2) :-

(A) 10 m/s
(B) 15 m/s
(C) 5 m/s
(D) 7.5 m/s

3) A ball is projected horizontally from the top of high tower at 12 m/s. Wind is blowing horizontally
as indicated in figure, which causes acceleration 6 m/s2 horizontally. Displacement of the ball, when

it strikes the tower, will be (g = 10 m/s2) :-

(A) 20 m
(B) 60 m
(C) 80 m
(D) 40 m

4)

Which of the following vectors, when added, may give a zero resultant?

(A) 2 N, 3 N, 6 N
(B) 1 N, 2 N, 3 N
(C) 2 N, 3 N, 7 N
2 N, 3 N,
(D)

5) The velocity of the particle is given as .

Calculate the net force acting on the body at time t = 1 sec, if the mass of the body is 10 kg.

(A) 15 N
(B) 20 N
(C) 25 N
(D) 50 N

SECTION-I(ii)

1) If vectors and represent two sides of a triangle,

then the third side can have length equal to :

(A) 3m
(B) 5m
(C) 6m
(D) 2m

2) Let us consider a system of units in which mass and angular momentum are dimensionless. If
length has dimension of L, which of the following statement (s) is/are correct ?

(A) The dimension of force is L–3

(B) The dimension of energy is L–2
(C) The dimension of power is L–5
(D) The dimension of linear momentum is L–1

3) An object starts moving from rest with an acceleration of 2 m/s2 at t = 0. Which of the following is
correct?

(A) Velocity of the object at t = 2 seconds is 4 m/s

(B) Velocity of the object at t = 2 seconds is 6 m/s
(C) Displacement of the object in 2 seconds is 6 m
(D) Displacement of the object in 2 seconds is 4 m

4) Two particles are thrown from same point in same vertical plane as shown in figure

simultaneously. Then indicate the correct statement(s).

(A) Time of flight of B is less than that of A.

(B) Projection speed of B is greater than that of A.
(C) Horizontal component of velocity of B is greater than that of A.
(D) Vertical components of velocities of A and B are always equal through out the flight of A and B.

SECTION-I(iii)

Common Content for Question No. 1 to 2

During a cycle race, two persons happen to cross a point x simultaneously with speeds 16 m/sec and
12 m/sec respectively. In order to win the race they increase their speeds at the rate 1 m/s2 and 2
m/s2 respectively. Unfortunately both reach the final point y at the same instant of time.

1)

If the time required to cover the distance xy is t then :

(A) t = 4 sec
(B) t = 6 sec
(C) t = 8 sec
(D) t = 10 sec

2)

Find the distance xy :-

(A) xy = 120 m
(B) xy = 160 m
(C) xy = 100 m
(D) xy = 80 m

Common Content for Question No. 3 to 4

A student forgot newton’s formula for speed of sound but he knows there were speed (v) pressure
(p) and density (d) in the formula. He then start using dimensional analysis method to find the actual
relation. v = k px dy, where k is a dimensionless constant on the basis of above passage answer the
following questions.
3) The value of x is :-

(A) 1

(B)

(C)

(D) 2

4) If the density will increase the speed of sound will :-

(A) increase
(B) decrease
(C) unchanged
(D) None of these

SECTION-III

1)

Two bodies were thrown simultaneously from the same point : one, straight up, and the other, at an
angle of θ = 30° to the horizontal. The initial velocity of each body is equal to v0 = 9 m/s. Neglecting
the air drag, find the distance between the bodies t = 1 sec later.

2) A particle is projected up an inclined plane of inclination β to be horizontal as shown. The angle of

projection of particle with horizontal is α . If the particle strikes the plane horizontally, then

, find the value of x.

3) A particle moves in rectilinear motion. Given the a-s curve shown in figure. Initial velocity of the
particle is 10m/s. Velocity of the particle after the particle has traveled 30m is X m/s. The value of
X/10 is

4) The surface of water in a water tank of cross section area 750 cm2 on the top of a house is h m.
above the tap level. The speed of water coming out through the tap of cross section area 500 mm2 is

30 cm/s. At that instant, is x × 10–3 m/s. The value of x will be_____.

SECTION-IV

1) The velocity time graph for a particle moving along a straight line is given in each situation of
column-I. In the time interval t > 0, match the graph in column-I with corresponding statements in
column-II.

Columns I Column II

(
(A) pspeed of particle is continuously decreasing.
)

(
(B) qmagnitude of acceleration of particle is decreasing with time.
)
 (
(C) r direction of acceleration of particle does not change.
)

(
(D) smagnitude of acceleration of particle is increasing with time.
)

(
t magnitude of acceleration of particle does not change.
)

PART-B-CHEMISTRY

SECTION-I(i)

1) When CrI3 oxidies to Cr2O72– and IO4– equivalent mass of CrI3 will be

(A)

(B)

(C)

(D)

2) Which of the following groups of molecules act both as oxidising agent as well as reducing agent?

(A) KMnO4, O3, SO3

(B) HClO4, HNO2, H2O2
(C) HNO2, SO2, H2O2
(D) HNO3, SO2, H2SO4

3) Oxidation state of K in K2O, K2O2 , KO2 :-

(A) +1, +1, +1

(B) +1, +2, +1
(C) +1, +2, +2
(D) +1, +4, +2

4) Equivalent mass of Na2S2O3 during conversion into Na2S4O6 is same as :- (Atomic masses : K = 39,
Mn = 55, Na = 23)

(A) Equivalent mass of KMnO4 as oxidant in acidic medium

(B) Equivalent mass of KMnO4 as oxidant in basic medium
(C) Equivalent mass of KMnO4 as oxidant in neutral medium
(D) None of these

5) 25 ml of a 0.1 M solution of a cation of transition metal Z reacts exactly with 25 ml of 0.04 M

acidified KMnO4 solution. Which of the following is most likely to represent the change in oxidation
state of Z ?

(A) Z+ → Z2+
(B) Z2+ → Z3+
(C) Z3+ → Z4+
(D) Z2+ → Z4+

SECTION-I(ii)

1) In which of these options do both constituents of the pair have the same magnetic moment -

(A) Zn2+ and Cu+

(B) Co2+ and Ni2+
(C) Mn4+ and Co2+
(D) Mg2+ and Sc+

2) If the wave number of 1st line of Balmer series of H-atom is ‘x’ then:

wave number of 1st line of lyman series of the He+ ion will be
(A)

wave number of 1st line of lyman series of the He+ ion will be
(B)

(C)
the wave length of 2nd line of lyman series of H-atom is

(D)
the wave length of 2nd line of lyman series of H-atom is

3) Empirical formula of a chloride of titanium is TiClX and it's 0.01 mol on treatment with excess of
AgNO3 gives 5.74g of AgCl (molar mass of AgCl = 143.5g). Which of the following statement
regarding TiClx is/are true ? (Molar mass of Ti = 48)

(A) It's empirical formula is TiCl3

(B) It's empirical formula is TiCl4
(C) TiClx has 25.26% Ti by weight
(D) TiClx has 31% Ti by weight
4) Which of the following have same mass -

(A) 0.1 mole of O2 gas

(B) 0.1 mole of SO2 gas
22
(C) 6.023 × 10 molecules of SO2 gas
23
(D) 1.204 × 10 molecules of O2 gas

SECTION-I(iii)

Common Content for Question No. 1 to 2

A solution of 0.2 g of a compound containing Cu2+ and C2O42– ion on titration with 0.02 M KMnO4 in
the presence of H2SO4 consume 30 ml of oxidant. The resulting solution was titrated with excess of
KI. The liberated I2 required 15 ml of 0.05 M Na2S2O3 for complete reduction. (Atomic mass of Cu =
64)

1) Mole ratio of Cu2+ and C2O42– in solution is :

(A) 1 : 1
(B) 1 : 2
(C) 2 : 1
(D) 3

2) Mass percentage of Cu2+ in solution is :

(A) 6
(B) 18
(C) 24
(D) 30

Common Content for Question No. 3 to 4

A mixture is prepared by mixing 20 g SO3 in 30 g H2SO4.

3) Find mole fraction of SO3 .

(A) 0.2
(B) 0.45
(C) 0.6
(D) 0.8

4) Determine % labelling of oleum solution.

(A) 104.5
(B) 106
(C) 109
(D) 110
 SECTION-III

1) 0.1 N K2C2O4. 3H2C2O4.4H2O solution reacts completely with 20 ml 0.05 M of KMnO4 solution in
acidic medium. Another sample of same solution of K2C2O4. 3H2C2O4.4H2O, having same volume is

titrated with M NaOH solution, then volume of NaOH solution is [Give your answer as sum of digit
and Fill OMR sheet]

2) Calculate molarity of final solution obtained by mixing I and II HNO3 solution.

3) Find total number of species having magnetic moment value B.M. among following species
Fe+2, Cr, Cr+3, Ti+2, Mn+2, V+3

4) A proton and a Li3+ nucleus are accelerated by the same potential. If λLi and λP denote the de

Broglie wavelengths of Li3+ and proton respectively, then the value of is x × 10–1. The value of x
is ________.
(Rounded off to the nearest integer) (Mass of Li3+ = 8.3 mass of proton)

SECTION-IV

1) Column I & Column II contain data on Schrondinger Wave-Mechanical model, where symbols
have their usual meanings. Match the columns :-

Column I Column II (Type of orbital)

(A) (p) 4s

(B) (q) 5px

Ψ (θ,ϕ) = K (independent of θ &

(C) (r) 3s
ϕ)
 atleast one angular node is
(D) (s) 6dxy
present

PART-C-MATHEMATICS

SECTION-I(i)

1)

Let S be the set of all real roots of the equation, 3x(3x – 1) + 2 = |3x – 1| + |3x – 2|. Then S :

(A) is an empty set

(B) contains at least four elements
(C) contains exactly two elements
(D) is a singleton

2)

The value of is equal to :

(A)
(B)
(C)
(D)

3) The value of expression is equal to

-

(A) 0
(B) 2
(C) 3
(D) 5

4) If n arithmetic means are inserted between a and 100 such that the ratio of the first mean to the
last mean is 1 : 7 and a + n = 33, then the value of n is

(A) 21
(B) 22
(C) 23
(D) 24
5) If the sum

is equal to where , then the value of 'n' is:

(A) 2009
(B) 2010
(C) 2011
(D) 2012

SECTION-I(ii)

1) Let a1, a2, a3,........ and b1, b2, b3,........ be arithmetic progression such that a1 = 25, b1 = 75 and a100
+ b100 = 100, then -

The common difference in progression 'ai' is equal in magnitude but opposite in sign to the
(A)
common difference in progression 'bj'.
(B) an + bn = 100 for any n.
(C) (a1 + b1), (a2 + b2), (a3 + b3), ....... are in A.P.

(D)

2) Consider the series:

Now, which of the following statements are correct:

(A) a = 99
(B) b = 100
(C) b = 99
(D) a = 100

3) Let . Then Sn can take value(s)

(A) 1056
(B) 1088
(C) 1120
(D) 1332

4) If . Then “x’ is divisible by

(A) 128
(B) 1024
(C) 4096
(D) 8192

SECTION-I(iii)

Common Content for Question No. 1 to 2

In inequalities of the form
|x| > a & |x| < a where a is positive. The solution can be represented directly as
x ∈ (–∞, –a) ∪ (a, ∞) & x ∈ (–a, a), respectively.

1) For the inequation ||| x | –2 | –1 | < 3, set of all possible values of x is :

(A) (–6, –2) ∪ (2, 6)

(B) (–6, 2)
(C) (3, 6)
(D) (–6, 6)

2) Number of integers satisfying the inequality |||x| – 1| –2 | ≤ 1

(A) 7
(B) 6
(C) 5
(D) 4

Common Content for Question No. 3 to 4

Consider four positive numbers a,b,c and d. Let a,b,c form a decreasing G.P., b,c,d form an A.P.
and a + d = 66, b + c = 60.

3) Sum to infinite terms of the G.P. given by a,b,c......... is -

(A) 144
(B) 150
(C) 162
(D) 170

4) Value of a – d is -

(A) 24
(B) 36
(C) 42
(D) 63

SECTION-III

1) If a > 0, such that minimum value of is equal to k, then is

equal to (where [.] represents greatest integer function)
2) If the sum of the infinity of the series, 1 + 4x + 7x2 + 10x3 + ......., is , where |x| < 1, then
'10x' equals to :

3) If the value of is l, then l2 is equal to

________.

4) Find the value of

SECTION-IV

1) Match the Column

Following questions contains statements given in two columns, which have to be matched. The
statements in Column-I are labelled as A, B, C and D while the statements in Column-II are
labelled as p, q, r and s. Any given statement in Column-I can have correct matching with one
statement in Column-II.
Match the following column-I with Column-II

Column-I Column-II

If ai's are in A.P. and a1 + a3 + a4 + a5 + a7 =

(A) (P) 21
20, a4 is equal to

Sum of an infinite G.P. is 6 and it's first term

(B) is 3. then harmonic mean of first and third (Q) 4
terms of G.P. is

If roots of the equation x3 – ax2 + bx + 27= 0,

(C) are in G.P. with common ratio 2, then a + b is (R) 24
equal to

If the roots of x4 – 8x3 + ax2 + bx + 16 = 0 are

(D) (S)
positive real numbers then a is
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5
A. B C C B D

SECTION-I(ii)

Q. 6 7 8 9
A. A,B A,B,D A,D B,C,D

SECTION-I(iii)

Q. 10 11 12 13
A. C B B B

SECTION-III

Q. 14 15 16 17
A. 9 2 2 2

SECTION-IV

Q. 18
A. A->rt,B->rt,C->pqr,D->pqr

PART-B-CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23
A. B C A B D

SECTION-I(ii)

Q. 24 25 26 27
A. A,C A,C B,C B,C,D

SECTION-I(iii)

Q. 28 29 30 31
A. B C B C

SECTION-III

Q. 32 33 34 35
A. 3 2 2 2
 SECTION-IV

Q. 36
A. A->P,B->PQS,C->PR,D->QS

PART-C-MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41
A. D A C C C

SECTION-I(ii)

Q. 42 43 44 45
A. A,B,C,D A,B A,D A,B

SECTION-I(iii)

Q. 46 47 48 49
A. D A C C

SECTION-III

Q. 50 51 52 53
A. 6 2 3 4

SECTION-IV

Q. 54
A. A->Q,B->S,C->P,D->R
 SOLUTIONS

PART-A-PHYSICS

1)

Let initial velocity of ballon is v0 and acceleration is 'a' then velocity at height h

Velocity of stone at ground

vg2 = v2 + 2gh = v02 + 2ah + 2gh
it will be indepnedent from height if (a = –g)

2)

80 = ⇒ t = 4 sec
10 × 4 + v × 4 = 60 ⇒ v = 5 m/s

3)

Ball strikes tower ⇒ Sx = 0

∴ ⇒ t = 4 sec
So displacement in y-direction in 4 sec

4)

5)

v = t2 + 2t
a = 2t + 2 + 1/t2
at t = 1, a = 5 m/s2
F = ma = 50 N

6)

Possible lengths would be or

7)
 1 = [Angular momentum] = [mvr] = [v].L
⇒ [v] = L–1

⇒ [time] = L2
1 = [Angular momentum] = [pr]
⇒ [momentum] = L–1

[energy] = [force × displacement] = L–2

[power] = L–4

8) v = at

s = ut + at2

9)

Component of velocity in vertical direction in same (Hmax is same)

....(1)

(A) Time period

TA = TB

(B)

RB > RA
from eqn – 1

since Hmax is same

10)

11)
= 128 + 32 = 160 m

12)
⇒

13) v = k

14)

Relative acceleration of two bodies = 0

Relative velocity of two bodies = = 2× 9 sin

Distance between the bodies after 1s = 9 × 1 = 9m

15) As the particle strikes the plane horizontally so its velocity is parallel to the horizontal axis
and vertical velocity is zero.

16) = [area under a-s graph]

 vf = 20 m/s

17) A1V1 = A2 V2
750 × 10–4 V1 = 500 × 10–6 × 0.3

= 2 × 10–3 m/s

18) Slope of velocity time graph gives acceleration.

PART-B-CHEMISTRY

19)
n-factor ⇒ Cr = (+ 3 to + 6) = 3e– loss
I = (– 1 to + 7) × 3 = 24 e– loss

n-factor = 27 ∴ E =

20)

Compounds where oxidation state of central

atom ⇒ O.S. between min. & max.
⇓
Act as both
Oxidant, Reductant

21) Oxidation state of o in superoxide is (–1/2) & in peroxide is (–1).

22)
n-factor (e– transfer per mole)
= (+ 2 to + 2.5) × 2 "S atom = 1

n-factor = (+ 7 to + 6) × 1 "Mn" atom

23) (N1 × V1)metal = (N2 × V2)KMnO4
0.1 M × (n - factor) × 25 ml
= 0.04 M × 5 × 25 ml
n-factor of metal = 2
only true for Z+2 → Z+4

24)

Spin only magnetic moment

where n = no. of unpaired e–.

25)

Use

26) For TiClx and AgCl, POAC on Cl

(0.01) x = ;x=4
so formula of compound will be = TiCl4

% by weight of Ti = %

27)

mass of 0.1 mol O2 will be = 0.1 × 32 = 3.2 gm

mass of 0.1 mol 5O2 will be = 0.1 × 64 = 6.4 gm
mass of 6.023 × 1022 molelcules of SO2 gas will be = 0.1 × 64 = 6.4 gm
mass of 1.204 × 1023 molelcules of O2 gas will be = 0.2 × 32 = 6.4 gm

28) C2O42– + KMnO4 → CO2 + Mn2+

Mole ratio of Cu2+ and C2O42– =

29) Cu2+ + KI → Cu+ + I2

I2 + Na2S2O3 → NaI + Na2S4O6

= 7.5 × 10–4
(A) Mass percentage of Cu2+ = = 24

30)

moles of SO3 =

moles of H2SO4 =

31)

% Label = 50 gm oleum contains 20 gm SO3.

= 100 gm oleum contains 40 gm SO3.

80 ______18
40 ______9 gm
so % 109%

32)

Redox titration
Eq. of K2C2O4.3H2C2O4.4H2O = Eq. of KMnO4

n factor of K2C2O4.3H2C2O4.4H2O
for redox titration = 8
for acid base titration = 6

for acid base titration normality of

Eq. of acid = Eq. of base

Vml = 30 ml

33) Molarity of I solution

Molarity of II solution
 34)
⇒ 2 unpaired e–

35)

36) It is for 4s. It is for 4s, 5p,

6d. Ψ (θ, ϕ) = K (independent of θ & ϕ) ⇒ valid for s orbital which have spherical symmetry.
No. of angular node =

PART-C-MATHEMATICS

37)

Let 3x = t ; t > 0
t(t – 1) + 2 = |t – 1| + |t – 2|
t2 – t + 2 = |t – 1| + |t – 2|
Case-I : t < 1
t2 – t + 2 = 1 – t + 2 – t
t2 + 2 = 3 – t
t2 + t – 1 = 0

is only acceptable
Case-II : 1 ≤ t < 2
t2 – t + 2 = t – 1 + 2 – t
t2 – t + 1 = 0
D < 0 no real solution
Case-III : t ≥ 2
t2 – t + 2 = t – 1 + t – 2
t2 – 3t 5 = 0 ⇒ D < 0 no real solution
(4) Option
38)

So,

⇒
⇒ (4x + 1) (x – 3) = x
⇒ 4x2 – 12x + x – 3 = x
⇒ 4x2 – 12x – 3 = 0

But only positive value is accepted

So, x = 1.5 +

39) The value of expression

=2+3–2=3

40)

Hints and solutions

A1 = a + d
An = 100 – d

⇒ 7a + 8d = 100

⇒ ...(1)
∵ a + n = 33 ...(2)
Now, by Eq. (1) and (2)
7n2 – 132n – 667 = 0

n = 23 and reject.

41)
 upto (2010 terms)

42)

a100 + b100 = 100

25 + 99d1 + 75 + 99d2 = 100
99d1 + 99d2 = 0
d1 + d2 = 0
d1 = –d2
(A) Correct
(B) an + bn = a1 + (n – 1)d1 + b1 + (n – 1)d2
= a1 + b1 = 100 (Correct)
(C) Correct (as sum of corresponding terms of two AP's also form an AP)
(D) (a1 + b1) + (a2 + b2) + ..... + (a100 + b100)
= 100 × 100 = 104

43) ............... (1)

.............. (2)

So,

44)

Sn = –12 – 22 + 32 + 42 – 52 – 62 + 72 + 82 .........
Sn = (32 – 12) + (42 – 22) + ............

Sn = 2(1 + 2 + 3 +........ + 4n)

Sn = 4n(4n + 1) = 1056 is possible when n = 8

4n (4n + 1) = 1088 not possible
4n(4n + 1) = 1120 not possible
4n(4n + 1) = 1332 possible when n = 9.

45)
Multiply and divided by 2–1

=
4x =

46) ||| x | –2 | –1 | < 3

⇒ –3 < ||x|– 2|–1 < 3
⇒ –2 < ||x|– 2| < 4
||x|–2| > –2 always
⇒ ||x|–2| < 4
⇒ – 4 < |x| – 2 < 4
⇒ – 2 < |x| < 6
|x| > –2 always
|x| < 6 ⇒ x ∈ (–6, 6)

47) Critical points

x = 0 and |x|–1 = 0 ⇒ x = ± 1
||x| – 1| = 2 ⇒ |x| –1 = 2, –2
|x| = 3
|x| = ± 3

seven integers x ∈ {–4, –3, –2, 0, 2, 3, 4}

48) Let a,b,c,d are a,ar,ar2,2ar2 – ar

∵ a + 2ar2 – ar = 66 ; ar + ar2 = 60

⇒ (reject)
⇒ a = 54
∴ GP : 54,36,24........
AP : 36,24,12,0..........

sum of G.P.
49)

= 42

50) Apply A.M ≥ G.M.

(∵ equality holds at a = 1)

51) S = 1 + 4x + 7x2 + 10x3 + ..........

x.S = x + 4x2 + 7x3 + ..................
Subtract
S (1 – x) = 1 + 3x + 3x2 + 3x3 + ........

S (1 – x) = 1 + 3x |x| < 1

S=

Given
⇒ 16 + 32x = 35 + 35x2 – 70x ⇒ (5x – 1) (7x – 19) = 0

⇒ x=

But |x| < 1 ∴ x=

52)

– – – –
________________________

Now
 2
⇒ =3

53) Let

54)

(A) a1 + a1 + 2d + a1 + 3d + a1 + 4d + a1 + 6d = 20
5a1 + 15d = 20
a1 + 3d = 4
a4 = 4

(B) ;

T1 = 3,

H.M.
(C) Let roots are

; α3 = – 27 ⇒ α = –3

Then Roots

⇒
(D) x4 – 8x3 + ax2 + bx + 16 = 0
Roots are positive real numbers α, β, γ, δ.
α+β+γ+δ =8
αβγδ = 16

Now ;
⇒ A.M. = G.M.
⇒ α, β, γ, δ are equal.
⇒ α=β=γ=δ=2

α = 24