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Particles in Motion
Kinetic Molecular Theory
O All matter is made of particles. O Particles are in constant, random motion. O Particles constantly collide with each other and with the walls of their container. Particle Motion O Place colored drops of food coloring in a beaker of ice cold water and a beaker of warm water. Observe the movement of the food coloring. O Why is there a difference between the beakers? Temperature O Temperature is the measure of the average kinetic energy of the particles in a material. O We call high average kinetic energy hot, and low average kinetic energy cold. O The SI unit for temperature is the Kelvin (K). O Scientists often use Celsius (◦C) temperature scale. Temperature O A cup of boiling water may have a higher temperature than a bathtub of warm water because the average kinetic energy of the particles in higher. However, if you were to sum up the kinetic energy of all the water molecules in the tub, it would have a higher total thermal energy. Temperature Example O Imagine a room full of people with candy in their pockets, temperature is like counting the candy that one person in the room has in his or her pocket. O Total thermal energy is like counting all the candy that everyone in the room has and adding it all up. O Heat transfer is like the flow of candy from a candy store to people who fill their pockets. Thermal Expansion O As the temperature of a material increases, particles begin to move faster. O They collide with each other more often and push each other farther apart. O Thermal expansion is the increase in volume of a material due to temperature increase. Thermal Contraction O Thermal Contraction is when the temperature of a material decreases, its volume decreases.
O Water is an exception to the rule. Water
expands when it freezes because of its molecular shape. Thermal Energy O The amount of thermal energy something has is the sum of the kinetic energy of all the particles. O Example: A bathtub full of warm water at 30◦C has more thermal energy than a sink of water when the water is the same temperature in both. Brain Break O Place your hand or a bare foot on the floor. O How does it feel? O Where is the region of high temperature? O Where is the region of low temperature? O In what direction is the energy flowing?
O Can cold flow?
Heat O Heat is the movement of thermal energy from a region of higher temperature to a region of lower temperature. O Equilibrium occurs when the temperature of two objects in contact are the same. Heat Transfer O Heat transfer always occurs from the place where there is higher temperature to the place where it is cooler. O Example: Heat transfer in a bathtub occurs from the hot water to the cooler air, the cooler floor, to the cooler tub sides, and the cooler person in the water. Heat Transfer O Conduction is the transfer of thermal energy by collisions between particles in matter. It can be direct contact between solids, or between a solid and a fluid. O Radiation is the transfer of thermal energy by electromagnetic waves. Visible light and infrared light are both forms of radiation that transfer heat. Convection O Convection is the transfer of thermal energy by the movement of the particles from one part of a material to another. O Convection occurs when fluids (gases or liquids) sink or rise because the cooler fluid is denser and sinks. When this happens, the cooler fluid pushes up the warmer fluid and it rises. Heat and Changes of State O Melting is the change of state from solid to a liquid. O Freezing is the change of state from liquid to solid. Vaporization O Vaporization is the change of state from liquid to gas. O Vaporization occurs two ways: O Boiling is vaporization that occurs within a liquid. O Evaporation occurs at the surface of a liquid. O The gaseous state of a substance that is normally a liquid or solid at room temperature is called a vapor. Condensation, Sublimation, and Deposition O Condensation is a change of state from a gas to a liquid. O Sublimation is the change of state that occurs when a solid changes to a gas without passing through the liquid state. O Deposition is the change of state from a gas directly to a solid without passing through the liquid state. (Frost) Condensation O Fill a metal can with ice and water. O What forms on the outside of the can? O Where did it come from? O What are the phase changes? Conductors and Insulators O A thermal conductor is a material in which thermal energy moves quickly. The material increases the rate of heat transfer. (Metal)
O A thermal insulator is a material in which
thermal energy moves slowly. The material reduces the rate of heat transfer. (Plastic) Conductors and Insulators O Place a metal spoon, a plastic spoon, glass stirring rod, and a wooden stick in a beaker of hot water. O Which materials are insulators? Which materials are conductors? How do you know?