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    Adsorption: Dynamic Equilibrium (Langmuir Theory) For Homogenous Surfaces

    Uploaded by

    Umesh Kumar Sharma Ramamoorthi
    The document discusses various theories for adsorption including Langmuir theory, Dubinin theory, and Polanyi theory. Langmuir theory describes adsorption on homogeneous surfaces using equations relating rate of adsorption and desorption to surface coverage and concentration. Dubinin theory models adsorption potential and energy for heterogeneous surfaces. Polanyi theory uses a variable describing adsorption work for modeling adsorption on heterogeneous surfaces.

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    Attribution Non-Commercial (BY-NC)
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    Adsorption: Dynamic Equilibrium (Langmuir Theory) For Homogenous Surfaces

    Uploaded by

    Umesh Kumar Sharma Ramamoorthi
    62 views6 pages
    The document discusses various theories for adsorption including Langmuir theory, Dubinin theory, and Polanyi theory. Langmuir theory describes adsorption on homogeneous surfaces using equations relating rate of adsorption and desorption to surface coverage and concentration. Dubinin theory models adsorption potential and energy for heterogeneous surfaces. Polanyi theory uses a variable describing adsorption work for modeling adsorption on heterogeneous surfaces.

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    Original Title

    Formula Rs

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    The document discusses various theories for adsorption including Langmuir theory, Dubinin theory, and Polanyi theory. Langmuir theory describes adsorption on homogeneous surfaces using equations relating rate of adsorption and desorption to surface coverage and concentration. Dubinin theory models adsorption potential and energy for heterogeneous surfaces. Polanyi theory uses a variable describing adsorption work for modeling adsorption on heterogeneous surfaces.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    62 views6 pages

    Adsorption: Dynamic Equilibrium (Langmuir Theory) For Homogenous Surfaces

    Uploaded by

    Umesh Kumar Sharma Ramamoorthi
    The document discusses various theories for adsorption including Langmuir theory, Dubinin theory, and Polanyi theory. Langmuir theory describes adsorption on homogeneous surfaces using equations relating rate of adsorption and desorption to surface coverage and concentration. Dubinin theory models adsorption potential and energy for heterogeneous surfaces. Polanyi theory uses a variable describing adsorption work for modeling adsorption on heterogeneous surfaces.

    Copyright:

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    Adsorption

    Dynamic equilibrium (langmuir theory) for homogenous surfaces:


    Rate of adsorption:
    [ ] ( ) 1 A k r
    ads ads
    2
    nd
    order reaction
    Rate of desorption:

    des des
    k r
    1
    st
    order reaction
    Equilibrium if rate desorption = rate adsorption
    [ ] ( ) 1 A k k
    ads des
    des
    ads
    L
    k
    k
    t tan cons _ langmuir K
    ] A K 1
    ] A K
    L
    L
    +


    ma!
    "
    "

    Langmuir Eqaution:
    1
    st
    set#up:
    ] 1
    ]
    ma!
    A K
    A K
    Q Q
    L
    L
    +


    2
    nd
    set#up:
    [ ] A
    "
    K
    1
    " "
    L
    ma!

    2
    nd
    set#up is t$e linearised form of langmuir equation: % = b & m ' !
    Multi component system with langmuir:
    [ ]
    [ ]

    1 n
    n n ( L
    i i ( L i ma!(
    i
    A K 1
    A K "
    "
    t$erefore:
    [ ]
    [ ] [ ]
    b b ( L a a ( L
    a a ( L a ma!(
    a
    A K A K 1
    A K "
    "
    + +

    )olume filling t$eor%:


    b "
    *
    "
    )
    ma!
    ads
    ma!
    ma! ( ads

    +it$
    ,
    *
    )
    -
    1
    1
    )olume
    cr

    Adsorption for heterogeneous surfaces:
    .otential t$eor% /.olan%i0:
    Variable What it is
    r Rate of sorption
    k Rate constant
    [A] Concentration in opposing phase
    Degree of covered places
    KL Langmuir constant
    Q Load on surface

    '

    ,
    _


    n
    o
    ads
    E
    V V

    e!p
    A1$okola
    2aitama
    1
    st
    set#up:

    '

    ,
    _


    n
    o
    ads
    E
    V V

    e!p
    t$erefore:
    2 2
    1
    1
    ln ln
    ,
    _


    ,
    _



    E
    V V
    o
    ads
    2
    nd
    set#up is t$e linearised form of dubinin equation: % = b & m ' !
    Variable What it is Units
    Vads Load in volume
    V
    0
    ore volume
    Compression !ork
    ["]
    E Adsorption energ# ["]
    n $mpirical num%er
    T R n V p
    x p p
    T p

    ,
    _


    ref
    p
    p
    T R ln
    2

    ,
    _


    E
    ads
    e V V

    Q
    V
    ads

    2
    2
    1
    0 ln/ 0 ln/

    ,
    _


    E
    V V
    Linearised
    ads
    ( )
    1 3
    3 3
    1 3
    / 0
    Interpolation
    f f
    f x f x x
    x x

    ma!
    ma!
    _
    ]
    1 ]
    1
    ]
    ]
    1
    L
    L
    L
    L
    Langmuir Isotherm
    K A
    Q Q
    K A
    Q
    Q Q
    K A
    A P
    slope
    K


    ma!
    ma!
    _
    e!p
    ln ln
    .
    ln
    1
    n
    n
    Ref
    n
    ads
    ads
    ads
    Dubinin Isotherm
    V V
    E
    V V
    E
    R T
    P
    slope
    E
    Q
    V


    _

    ' ;

    ,


    _


    ,
    _


    ,

    T R
    V p
    n
    4

    T R
    p
    V
    n
    4

    Molar Mass
    & !aste gas 0'0() kg*mol
    & +,( 0'0-. kg*mol
    & /(, 0'00) kg*mol
    & C,( 0'0.. kg*mol
    & ethanol 0'0.- kg*mol
    & C/. 0'00- kg*mol
    & 1/2 0'003 kg*mol
    & C(/- 0'02 kg*mol
    AB!"#$%!&
    5apour partial total
    p 6 !
    *
    p p %
    *

    total
    5apour
    p
    p
    K
    =7 8on ideal case
    i
    i
    inert
    l
    inert
    g
    x
    y
    Y
    Y
    !
    !

    +
    +

    0 1 /
    0 1 /
    p
    p
    K
    total
    5apour

    =7 9deal case
    "apour i
    p #
    out i(
    gas
    inert out i(
    liquid
    inert in i(
    gas
    inert in i(
    liquid
    inert
    : 8 ; 8 : 8 ; 8 + +

    1 2
    2 1
    1 2
    < p
    < p
    ) )


    =ur >mrec$nung des )olumens 5on i484 ?ur aktuellen <emperatur
    1atm = 1(3-2@bar = 13-2@3.a = AB3<orr = AB3mm Cg = 1D(BEB lbFinc$
    2
    { } [ ]
    in in in
    out in
    K K Y Y
    Y Y $
    L
    +


    0 1 /
    0 /
    min
    = Ger minimale Hliquid flo+I
    Jalls keine Keladung am JlLssigkeitseintritt K $ L
    min


    :
    out g
    gas inert
    g
    solute
    !
    !
    _

    ;
    in
    :
    in g
    gas inert
    g
    solute
    !
    !
    _

    ;
    out
    l
    sol"ent
    g
    solute
    !
    !

    x
    x

    1
    *
    oder umgeke$rt

    x
    *
    1
    *
    +

    y
    y
    Y

    1
    *
    auc$ $ier gilt
    Y
    Y
    y
    *
    1
    *
    +

    ( ) ( ) K 1 K :
    :
    ;
    in
    in
    out
    +

    August Equation
    T
    %
    A p ln
    & R % #
    V

    A K
    T & R
    h
    '
    T & R
    h
    p
    " "
    1 1
    ln
    int


    AB!"#$%!& '!!L%&(
    sol"ent tot sol"ent
    x ( (

    agent mix solute agent solute sol"ent
    x ( x ( x ( +

    " agent
    r ( Q

    ent?ogene MNrme = 2assenfluO ' )erdampfungsent$alpie
    5on $eat transfer kennen +ir auc$
    ln

    ) A Q

    aus der Antoine eq4

    ,
    _

    ' T
    %
    A
    partial
    e p
    er$Nlt man durc$ die folgende >mformung die
    <emperatur:
    T '
    A p
    %
    partial

    ln

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