Recycle With Chemical Reaction of Material Balance

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ATK (Asas Teknik Kimia)

Recycle with Chemical


Reaction of Material Balance
Annissa Risky Amalia
1331410079/ 1E

12.23 Himmelblau
Sulfur dioxide may be converted to SO3, which has
many uses including the production of H2SO4 and
sulphonation of detergent. As gas stream having the
composition shown in Figure P12.23 is to passed
through a two-stage converted. The fraction conversion
of SO2 to SO3(one pass though) in the first stage is 0.75
and in the second stage is 0.65. To boost the overall
conversion to 0.95, some of the exit gas from stage 2 is
recycled back to inlet of stage 2.
Question:
How much must be recycled per 100 mole of inlet gas
(stream F)? Ignore the effect of temperature on the
conversion

Flow sheet (Figure P12.23 )


100 lbmol
SO2 10 %
O2 9 %
N2 81 %

I
75 %

Reaction:

SO2 + O2 SO3

II
65 %

SO3
SO2
O2
N2

Mole in F

Basis = 100 lbmol F

Composition in A
SO2F SO3A is converted 75 %
SO3 = 7.5 lbmol
100 lbmol
SO2 10 lbmol
O2 9 lbmol
N2 81 lbmol

I
75 %

SO2 to be SO3 = 0.75 x 10 lbmol = 7.5 lbmol


SO2 in A = (10-7.5)lbmol = 2.5 lbmol
O2 in the reaction
SO2 + O2 SO3

O2 in A = (9-3.75)lbmol = 5.25 lbmol


N2 = 81 lbmol (tetap)

SO2 = 2.5 lbmol


O2

= 5.25 lbmol

N2

= 81 lbmol

Overall
SO2SO3 is converted 95 %
So the composition in P are. . .
SO2 + O2 SO3

SO2

= (10-9.5) lbmol = 0.5 lbmol

O2 (P) = (9-4.75)lbmol = 4.25 lb mole


N2 = 81 lbmol

SO3 = 9.5 lbmol


SO2 = 0.5 lbmol
O2 = 4.25 lbmol
N2 = 81 lbmol
95.25 lbmol

XSO3 = 0.0997
XSO2 = 0.0052
XO2 = 0.0447
XN2 = 0.8504
1.00

SO2 10 lbmol
O2 9 lbmol
N2 81 lbmol

95 %
SO3 = 9.5 lbmol
SO2 = 0.5 lbmol
O2

= 4.25 lbmol

N2

= 81 lbmol

SO3 = 7.5 lbmol


SO2 = 2.5 lbmol
O2 = 5.25 lbmol
N2 = 81 lbmol
100 lb mol
SO2 10 %
O2 9 %
N2 81 %

I
75 %

The concentration
of R is like in P

II
65 %

SO3
SO2
O2
N2

SO3 9.5 lbmol 9.97 %


SO2 0.5 lbmol 0.52 %
O2 4.25 lbmol 4.47 %
N2 81 lbmol 85.04 %

9.97 %
0.52 %
4.47 %
85.04 %

(A+R)0.65=B
(nSO2SO3A +n SO2SO3R) 0.65
dariA)
( 2.5 + 0.0052 R ) 0.65
1.625 + 0.00338 R
0.00338 R

= (n SO2SO3 sisa

R
Question:
Answer

= (9.5 7.5)
=2
= 0.375
= 110.9467 lbmol

How much must be recycled per 100 mole of inlet gas (stream F)?

: It must be recycled 110.9467 lbmol per 100 lbmol of inlet gas

Thank you

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