myPAT JEE MAIN PT-3 Held On 01-12-2019

myPAT Test Series-3_1
FIITJEE
Applicable for Class – XI (PINNACLE)
PHASE – 3
BATCHES: DWIT91A01 & DWITN91A04
DATE: 01/12/2019
PART – I : PHYSICS
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. When n fluids of masses m1, m2, …mn and densities 1, 2, …. n respectively are mixed together,
then resultant density of mixture is
n n
m
i 1
i m 
i 1
i i
(A) n
(B) n

i 1
i m
i 1
i
m
i 1
i
(C) n
(D) infinity
mi

i 1 i
2. A liquid of density  is completely filled in a rectangular closed L

box. The box is accelerating horizontally with acceleration a.
S P
What should be the gauge pressure at four point P, Q, R, S? a
h 
(A) PP  0, PQ  0, PR  gh, PS  0
(B) PP  gh, PQ  0, PR  ga, PS  aL R Q
(C) PP  0, PQ  gh, PR  gh  aL, PS  aL
(D) PP  gh, PQ  0, PR  gh  aL, PS  gL
3. An open vessel containing water is given a constant acceleration a in the horizontal direction.
Then the free surface of water gets sloped with the horizontal at an angle  given by
a  g
(A)   tan1   (B)   tan1  
 g a
a  g
(C)   sin1   (D)   cos1  
 g a
Rough work
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4. In which one of the following cases will the liquid flow in a pipe be most streamlined?
(A) Liquid of high viscosity and high density flowing through a pipe of small radius
(B) Liquid of high viscosity and low density flowing through a pipe of small radius
(C) Liquid of low viscosity and low density flowing through a pipe of large radius
(D) Liquid of low viscosity and high density flowing through a pipe of large radius
5. A tank is filled with water upto a height H. Water is allowed to

come out of a hole P in one of the walls at a depth D below the
D
surface of water. The horizontal distance x in terms of H and D
P
is
H
D(H  D)
(A) x  D(H  D) (B) x 
2
x
(C) x  2 D(H  D) (D) x  4 D(H  D)
6. There are two identical small holes on the opposite sides of a tank
containing a liquid. The tank is open at the top. The difference in height of
the two holes is h as shown in the figure. As the liquid comes out of the two
holes, the tank will experience a net horizontal force proportional to:
1/2
(A) h
(B) h
3/2
(C) h
2
(D) h
7. An L-shaped glass tube is just immersed in flowing water

such that its opening is pointing against flowing water. If the
speed of water current is v, then: h
v2
(A) the water in the tube rises to height
2g
g v
(B) the water in the tube rises to height
2v 2
(C) the water in the tube does not rise at all
(D) none of the above
8. The angle of contact of a liquid surface with a solid surface is 90° when
F F
(A) FA  C (B) FA  C
2 2
FC
(C) FA  (D) FA  FC
2
Rough work
9. A soap bubble of radius r1 is placed on another soap bubble of radius r 2(r1 < r2). The radius R of
the soapy film separating the two bubbles is
(A) r1  r2 (B) r12  r22
  r2r1
1/ 3
(C) r13  r23 (D)
r2  r1
10. Liquid reaches an equilibrium as shown, in a capillary tube of internal P

radius r. If the surface tension of the liquid is T, the angle of contact  and
density of liquid , then the pressure difference between P and Q is Q
 2T  T
(A)   cos  (B) 
 r  r cos 
2T  4T 
(C) (D)   cos 
r cos   r 
11. A capillary tube (A) is dipped in water. Another identical tube (B) is dipped in a soap-water
solution. Which of the following shows the relative nature of the liquid columns in the two tubes?
A B A B
(A) (B)
A B A B
(C) (D)
12. The reading of centigrade thermometer coincides with that of Fahrenheit thermometer in a liquid.
The temperature of the liquid is
(A) –40°C (B) 0°C
(C) 100°C (D) 300°C
13. A faulty thermometer has its fixed points marked as 5° and 95°. This thermometer reads the
temperature of a body as 59°. Then the correct temperature of the body on the Celsius scale is
(A) 59° (B) 61°
(C) 48.6° (D) 58°
Rough work
14. The graph shows the variation of temperature (T) of one kilogram of a material with the heat (H)
supplied to it. At O, the substance is in the solid state. From the graph, we can conclude that
T
C(H3 ,T2 ) 
 D(H4 ,T2 )
A(H1,T1 )
 B(H2 ,T1 )
O H
(A) T2 is the melting point of the solid

(B) BC represents the change of state from solid to liquid
(C) (H2 – H1) represent the latent heat of fusion of the substance
(D) (H3 – H1) represents the latent heat of vaporization of the liquid
15. How much heat is required to convert 2 gm of ice 0°C to steam at 100°C? (Cwater = 1 cal/g-°C,
(A) 144 cal (B) 1440 cal
(C) 108 cal (D) 1080 cal
16. A jar is filled with two non-mixing liquids 1 and 2 having densities 1 and
2, respectively. A solid ball, made of a material of density 3, is dropped
in the jar. It comes to equilibrium in the position shown in the figure.
Which of the following is true for 1, 2 and 3?
(A) 1 > 3 > 2
(B) 1 < 2 < 3
(C) 1 < 3 < 2
(D) 3 < 1 < 2
17. Spherical balls of radius ‘R’ are falling in a viscous fluid of viscosity ‘’ with a velocity ‘v’. The
retarding viscous force acting on the spherical ball is –
(A) inversely proportional to both radius ‘R’ and velocity ‘v’
(B) directly proportional to both radius ‘R’ and velocity ‘v’
(C) directly proportional to ‘R’ but inversely proportional to ‘v’
(D) inversely proportional to ‘R’ but directly proportional to velocity ‘v’
Rough work
18. Minimum amount of steam of 100ºC required to melt 12gm ice completely, will be
(a) 1.5 gm (b) 1 gm
(c) 2 gm (d) 5 gm
19. A 2gm bullet moving with a velocity of 200 m/s is brought to a sudden stoppage by an obstacle.
The total heat produced goes to the bullet. If the specific heat of the bullet is
0
0.03 cal/gm- C, the rise in its temperature will be
0 0
(a) 158.0 C (b) 15.80 C
0 0
(c) 1.58 C (d) 0.1580 C
20. The standard fixed point for temperature measurements in use today is
(A) melting point of ice at one atmospheric pressure
(B) of pure ice and pure water in equilibrium at one atmosphere pressure
(C) at which ice, liquid, water and water vapour co-exist
(D) none of the above
SECTION – B
(Integer Answer Type)
This section contains 2 questions. The answer to each question is a single-digit integer, ranging from 0
to 9. The correct digit below the question number in the ORS is to be bubbled.
21. 10 gm of ice at –20°C is added to 10 g of water at 50°C. Specific heat of water = 1 cal/g-°C,
specific heat of ice = 0.5 cal/g-°C. Latent heat of ice = 80 cal/g. Then resulting temperature is
22. A small metal sphere of radius r and density  falls from rest in a viscous liquid of density  and
coefficient of viscosity . Due to friction heat is produced. The rate of production of heat the
sphere has acquired the terminal velocity is proportional to P  r k , where value of k = ?
Rough work
SECTION – C
(Numerical Answer Type)
This section contains 3 questions. The answer to each question is of the form XXXXX.XX. The correct
digit below the question number in the ORS is to be bubbled.
23. In a car lift compressed air exerts a force F1 on a small piston having a radius of 5 cm. This
pressure is transmitted to a second piston of radius 15 cm. If the mass of the car to be lifted is
1350 kg; required force is
F1 = xx.xx  10 N. Where the value of xx.xx [Take g = 9.8 m/s ]
4 2
24. Figure shows a siphon in action. The liquid flowing B C

through the siphon has a density of 1.5 g/cc. The
pressure difference between points B and C h1  20 cm
N A
(Neglecting air density) is xx.xx  103 2 . The value h2  200 cm
m
2
of xx.xx? (g = 9.8 m/s )
25. A air bubble of radius 0.1 mm is formed 10 cm below the water (surface tension of water
–3
= 73  10 N/m) surface on a day when the atmospheric pressure is 1  10 Pa. Then total
5
pressure inside the bubble is xx.xx  10 , where xx.xx ?

6
Rough work
PART – II : CHEMISTRY
1. Thermal stability of BaCO3, CaCO3 and MgCO3 is

(A) CaCO3  MgCO3  BaCO3 (B) MgCO3  CaCO3  BaCO3
(C) BaCO3  MgCO3  CaCO3 (D) BaCO3  CaCO3  MgCO3
2. In which of the following bonds does H carry a partial negative charge?

(A) F–H (B) B–H
(C) N–H (D) O–H
3. In which compound is the bonding largely covalent?

(A) BeH2 (B) NaH
(C) CsH (D) BaH2
4. In a Fcc lattice find the distance between the octahedral & tetrahedral voids, assuming edge
length is 4 3 pm.
(A) 3 (B) 4 3
(C) 5 (D) 5 3
5. Formic acid is 4.5% dissociated in a 0.1 M solution at 25C. The ionisation constant of formic acid
is
(A) 2.6  105 (B) 3.68  104
5
(C) 4.38  10 (D) 2.025  104
6. Inorganic benzene is
(A) BN (B) BF4
(C) B2H6 (D) B3N3H6
7. K sp of AgCl is 1.8  1010 at 25ºC. Solubility of AgCl in water can be increased by?
(A) Adding NH3 in solution (B) Adding NaCl in solution
(C) Adding AgNO3 in solution (D) Adding more water in solution
Rough work
8. In the following reaction, 2SO2(g) + O2(g) 2SO3(g)

H = - ve, the yield of SO3 is favoured by
(A) increasing the pressure and the temperature
(B) Increasing the pressure and decreasing the temperature
(C) Decreasing the pressure and increasing the temperature
(D) Decreasing the both pressure and the temperature
The solubility product of sparingly soluble salt Ag2CrO4 is 4  10 . The molar solubility of the
-12
9.
salt is
(A) 1  10 mol L (B) 2  10 mol L
-4 -1 -6 -1
(C) 1  10 mol L (D) 2  10 mol L

-5 -1 -12 -1
10. A weak acid HX (Ka = 1  105) on reaction with NaOH gives NaX. For 0.1 M aqueous solution of
NaX, the degree of hydrolysis is
(A) 0.001% (B) 0.01%
(C) 0.15% (D) 1%
Solubility product constant (Ksp) of salts of types MX, MX2, M3X at temperature T are 4  10 ,
-8
11.
3.2  10 and 2.7  10 respectively. Solubility (mol dm ) of the salts at temperature T are in
-14 -15 -3
the order:
(A) MX > MX2 > M3X (B) M3X > MX2 > MX
(C) MX2 > M3X > MX (D) MX > M3X > MX2
12. The main factor responsible for weak acidic nature of BF 3 is

(A) large electronegativity of fluorine (B) three centred two electron bonds in BF3
(C) p-d back bonding (D) p- p back bonding
+
13. NH4 ion in aqueous solution will behave as
(A) a base (B) an acid
(C) neutral (D) amphiprotic
14. The addition of HCl will not suppress the ionisation of

(A) acetic acid (B) sulphuric acid
(C) H2S (D) benzoic acid
Rough work
15. For the following equilibrium

NH HS(s) NH (g) + H S(g) ; partial pressure of NH will increase
4 3 2 3
(A) If NH is added after equilibrium is established
3
(B) if H S is added after equilibrium is established
2
(C) NH4HS is added into the container
(D) volume of the flask is decreased
16. To 100 mL of 0.1 M AgNO3 solution solid K2SO4 is added. The concentration of K2SO4 that shows
the precipitation is? [Ksp for Ag2SO4 = 6.4  10 M]
-5
(B) 6.4  10 M
-3
(A) 0.1 M
(C) 5.4  10 M (D) 6.4  10 M
-7 -5
17. Degree of ionisation of 1 M HCOOH is decreased to a maximum extent in presence of :

(A) 1 M HCHO (B) 1 M NaOH
(C) 1 M HCOONa (D) equally in all
18. Buck ball or buckminister fullerene is

(A) an allotrope of carbon
(B) referred to as C-60
2
(C) C is sp hybridized in nature and resembles a soccer ball
(D) All of the above
19. Equal volume of 0.02M AgNO3 and 0.02 M HCN are mixed. What is the value of  Ag  in
the solution
Given Ka HCN  9  1010 and K sp  AgCN  4  1016
(A) 4.2  103 M (B) 6.67  105 M
(C) 2.2  103 M (D) 5.4  104 M
20. On the basis of following graph (P –V graph),

choose the incorrect statement
(A) Total work done W = q
(B) The entropy change for the overall process is zero
(C) For the overall process, H  U
(D) Total work done = –620.77 J
Rough work
SECTION – C
This section contains 2 questions. The answer to each question is a Integer type answer with answer
(0 to 9).
21. A reversible reaction is carried out at 500 K, where its equilibrium constant is unity. If H at 500
K is 4kJ, the value of Sº is equal to
22. Find sum of triangular BO3 units and BO4 tetrahedral unit in borax
SECTION – C
23. N2O4 is dissociated to 33% and 40% at total pressure P 1 and P2 atm respectively. Then the ratio
P1 P2 is
24. The pH of a solution obtained by mixing 10 ml of 0.45 M HCl and 40 ml of 0.05 M NaOH is
25. One mole of an ideal gas at 300 K in thermal contact with surrounding expands isothermally from

1 L to 2 L against a constant pressure of 3 atm. In this process, Ssurr in J k 1 is 
Rough work
PART – III : MATHEMATICS

x2 y2
1. The distance between the directrices of the ellipse   1 is
4 9
9 24 18
(A) (B) (C) (D) None of these
5 5 5
If in a ABC, cos(A - C)cosB + cos2B = 0, then a , b , c are in

2 2 2
2.
(A) A.P. (B) G.P. (C) H. P. (D) none of these
2 2
3. The distance of the center of the ellipse x +2y – 2 = 0 to those tangents of the ellipse which are
equally inclined to both the axes is
3 3 2 3
(A) (B) (C) (D)
2 2 3 2
x2 y2
4. If a tangent of slope ‘m’ at a point of the ellipse  = 1 passes through (2a, 0) and if ‘e’
a2 b2
denotes the eccentricity of the ellipse then
2 2 2 2 2 2
(A) m + e = 1 (B) 2m + e = 1 (C) 3m + e = 1 (D) none of these
2 2
5. The eccentricity of the ellipse 9x + 5y – 30y = 0 is
(A) 1/3 (B) 2/3 (C) 3/4 (D) 1/2
x2 y2
6. The equation + = 1 represents an ellipse with major axis along x–axis if
6a 2a
(A) a < 6 (B) 2 < a < 6 (C) a > 2 (D) a < 2
7. If a  3, b 
1
 6  2 , and c  2, then find A.
2
  
(A) (B) (C) (D) None of these
2 3 4
Rough work
If y = mx + c is a tangent to the hyperbola x  3y = 1, then

2 2
8.
2 2 2 2 2 2 2 2
(A) c = m (B) c = m + 1 (C) c > m (D) c < m
9. The angle between the asymptotes of a hyperbola is 30°. The eccentricity of the hyperbola may
be
(A) 3  1 (B) 3 + 1 (C) 6  2 (D) None of these
2 2
10. The eccentricity of the hyperbola 5x – 4y + 20 = 0 is
3 5 3 2
(A) (B) 3 5 (C) (D)
5 2 3
2 2 2 2 2 2
11. The line lx + my + n = 0 will be a normal to the hyperbola b x – a y = a b if
(A)
a2 b2
 =

a2  b2 2
(B)
a2 b2
 =

a2  b2 
2
l 2 m2 n2 l 2 m2 n2
a2 b2
(C) 2  2 =
a2  b2  2
(D) None of these

l m n2
2 2
12. The chords lx + my – 1 = 0 (l, m being parameters) of the curve x – 3y + 3xy + 3x = 0,
subtending a right angle at the origin, are concurrent at the point
 3  3  1 
(A)   , 0 (B)  , 0  (C)  , 0  (D) None of these
 2  2  2 
13. If points corresponding to the complex numbers z1, z2, z3 and z4 are the vertices of a
rhombus, taken in order, then for a non-zero real number k
(A) z1 – z3 = i k( z2 –z4) (B) z1 – z2 = i k( z3 –z4)
(C) z1 + z3 = k( z2 +z4) (D) z1 + z2 = k( z3 +z4)
14. For a complex number z , | z-1| + |z +1| =2. Then z lies on a

(A) parabola (B) line segment (C) circle (D) none of these
15. The cube roots of unity lie on a circle

(A) |z| = 1 (B) |z – 1| = 1 (C) |z + 1| = 1 (D) |z – | = 1
Rough work
1 n 1
16. If x + = 2cos, then x + n is equal to
x x
(A) 2 cosn (B) 2sinn (C) cosn (D) sinn
2
17. sinx + cos x = y – y +a has no value of x for any y if ‘a’ belongs to
(A) (0, 3) (B) (- 3 , 0 ) (C) (- , - 3 ) (D) ( 3 , )
18. If sinx + siny + sinz = 3, x, y, z  [ 0, 2], then

(B) x + y + z =  /3
2 2 2 3 3 3 3
(A) x + y + z – xy – yz – zx = 0
3 3 3
(C) x + y + z = 0 (D) x + y + z = 0
sinx -sinx
19. The equation e +e = 2sinx will have
(A) no solution (B) one solution (C) two solution (D) none of these
2 2
20. If 3 sin A + 2sin B = 1 and 3 sin2A – 2 sin2B = 0, where A and B are acute angles, then
A + 2B is equal to
(A) /3 (B) /4 (C) /2 (D) none of these.
SECTION – C
This section contains 2 questions. The answer to each question is a Integer type answer with answer
(0 to 9).
x2 y2
21. If P is a point on the ellipse  =1 whose foci are S and S. Then PS + PS is
16 20
22. If twice the square of the diameter of a circle is equal to the sum of the squares of the sides of
2 2 2
the inscribed triangle ABC, then sin A + sin B + sin C is equal to

This section contains 3 questions. The answer to each question is a numerical answer type with
answer (XXXXX.XX).
2
23. Number of solutions of Re (z ) = 0 and |Z| = a2, where z is a complex number and a > 0, is
x2 y2
24. The number of normals to the hyperbola  = 1 from an external point is
a2 b2
25. If in a triangle ABC, b = 3c and C – B = 90º, then find the value of tan B.
Rough work
FIITJEE
JEE MAIN (PHASE–3)
[11th Pinnacle]
DATE: 01/12/2019
ANSWERS KEY
PHYSICS
1. C 8. B 15. B 22. 5
2. C 9. D 16. C 23. 14.70
3. A 10. A 17. B 24. 26.46
4. B 11. C 18. C 25. 10.24
5. C 12. A 19. A
6. B 13. B 20. C
7. A 14. C 21. 0
CHEMISTRY
1. D 8. B 15. A 22. 4
2. B 9. A 16. B 23. 1.56
3. A 10. B 17. C 24. 1.3
4. A 11. D 18. D 25. 1.01
5. D 12. D 19. B
6. D 13. B 20. C
7. A 14. B 21. 8
MATHEMATICS
1. C 8. D 15. A 22. 2
2. A 9. C 16. A 23. 4.00
3. D 10. A 17. D 24. 4.00
4. C 11. C 18. A 25 3.00
5. B 12. B 19. A
6. D 13. A 20. C
7. B 14. B 21. 8
HINTS & SOLUTIONS

PHYSICS
1. C
mass of mixture
Density of mixture =
volume of mixture
m1  m2  ...  mn

m1 m2 m
  ....  n
1 2 n
n
m i
 i 1
n
mi

i 1 i
2. C
At point, P, PP = 0
At point Q, PQ = PP + gh = gh
At point R, PR = PQ + aL = gh + aL
At point S, PS = PR – gh = aL
3. A
Consider a small portion of mass m of the liquid, mg is the weight acting downward and ma is the
fictitious force acting against the direction of motion. The resultant of these two forces will make
the surface of liquid inclined in such a way that the resultant is normal to the surface for which
ma a
tan   
mg g
  tan1(a / g)
4. B
r
For streamline flow, Reynold’s number NR  should be less. For less value of NR, radius and

density should be small and viscosity should be high.
5. C
The pressure at the free surface of the liquid and also at outside of point P is atmospheric
pressure. Hence there will be no effect of atmospheric pressure on the flow of liquid from hole P.
The liquid on the free surface has no kinetic energy but only potential energy. On the other hand
the liquid coming out of the hole has both kinetic and potential energies. Let v be the velocity of
efflux of the liquid coming out from the hole. According to Bernoulli’s theorem,
1
P  0  gH  P  g(H  D)  v 2
2
v  2gD …(1)
After coming from the hole the liquid adopts a parabolic path. If it takes t sec in falling through a
vertical distance (H – D), then
1
(H  D)  gt 2 or t  [2(H  D) / g ….(2)
2
From equations (1) and (2),
x  vt  2 [D(H  D)]
6. B
7. A
8. B
F
When  = 90°, the surface of liquid is plane and FA  C .
2
9. D
Two soap bubbles of radii r1 and r2 (r1 < r2) come together to form a double bubble. Let T
represents the surface tension of the liquid and P the atmospheric pressure.
4T
Pressure inside the smaller bubble = P 
r1
4T
Pressure inside the larger bubble = P 
r2
1 1
Pressure difference  4T   
 r1 r2 
Now pressure on the concave side of the soapy film separating the two bubbles is greater than
that on the convex side by 4T/R.
4T 1 1
  4T   
R  r1 r2 
1 r2  r1
 
R r1r2
r1r2
or R
r2  r1
10. A
Radius of curvature at meniscus R  (r / cos )
2T
Pressure difference across meniscus 
R
2T cos 
 Pressure difference 
r
11. C
Soap solution has lower surface tension as compared to pure water so h is less for soap solution.
12. A
If the temperature is  at which the readings of two scalars coincide, then from
TC  0 TF  32

100 180
   32
 i.e.,  = –40°C
100 180
13. B
14. C
Since in the region AB, temperature is constant, therefore at this temperature phase of the
material changes from solid to liquid and (H2 – H1) heat will be absorbed by the material. This
heat is known as the heat of melting of the solid.
Similarly, in the region CD temperature is constant, therefore at this temperature phase of the
material changes from liquid to gas and (H 4 – H3) heat will be absorbed by the material. This heat
is known as the heat of vaporization of the liquid.
15. B
Q  Qmelt  Q0100  Qvapour  mLf  msw (100  0)  mLv
16. C
17. B
18. C
Heat required = Heat supplied
12 × 80 = m[540  1 100]
12  80
m  1.5 gm
640
19. A
20. C
21. 0
Let resulting temperature = 0°C
 Q1 = heat given by water if it was to cool upto 0°C
= 10  1  (50 – 0) = 500 cal
and Q2 = heat required by ice to convert totally water at 0°C
= heat required to raise the temperature of ice from –20°C to 0°C + heat required to
melt 10 gm of ice at 0°C into water at 0°C
= 10  0.5  20 + 10  80
= 100 + 800 = 900 cal
As Q1 < Q2 hence whole of the ice cannot melt. Initially, 100 cal of heat will be used up in raising
the temperature of ice 0°C and the rest 400 cal will be available for melting of ice. If it melts mg
of ice, then
m  80 = 400, i.e., m = 5 gm
Hence, only 5 g of ice will melt and the remaining 5g of ice will remain in the mixture as ice at
0°C. The amount of water in the mixture
= 10 g + 5 g = 15 g
Final temperature of mixture = 0°C
22. 5
2 (  ) 2
vt  r g …(1)
9 
 Rate of heat production of heat (or power dissipated) is
P  Fv Vt
 (6rv t )v t
 6rv t
2
…(2)
Equation (1) and (2) Pr 5
k=5
23. 14.70
F1 F A r 2
 2  F1  1 F2  12  F2
A1 A 2 A2 r2
2
 5 
F1     1350  9.81  14.70  102 N
 15 
24. 26.46
 PA  PD
 PB  PC  (PA  h1g)  (PD  h2g)
 (h2  h1 )g
 26.46  103 N/ m2
25. 10.24
2T
Pin  Patm  hdg 
r
73  103
 1 105  10  102  103  2 
0.1
= 10.24  10 Pa
6
HINTS & SOLUTIONS

CHEMISTRY
1. D
Sol. As size difference between cation and anion increases, thermal stability decreases.
2. B
Sol. Boron is less EN than H
3. A
Sol. Least electronegativity difference between Be and H
4. A
3
Sol. Distance is a
4
3
4 3  3
4
5. D
Sol. 
 
 HCOO 
HCOOH  H
0.1 0 0
0.1  0.1 0.1 0.1
4.5
  0.045
100
C2
 0.1 0.045 
2
Ka 
1 
= 2.02  104
6. D
Sol. Structure of Borazine B3N3H6  resemble benzene  C6H6 
7. A
Sol. 
 
 Ag  Cl
AgCl  

  Ag NH3 2 


Ag  2NH3 
8. B
Sol. Le Chatlier principle
9. A
2
Sol. 
 
 2Ag  CrO4
Ag2CrO4 
K sp  4  1012 4s3
S = 104 mol L1
10. B
Sol. 

X  H2O 
 HX  OH

Kw
 K h  Ch2
Ka
1014
 109  0.4  h2
105
h  104
% h  104  100  102%
11. D
Sol. 
 
 M  X
MX  
S S
S2  4  108
S  2  104
MX2 M2  2X
S 2S
4S  3.2  10  32  1015
3 14
S  2  105

M3    
 3M  X
3
3S S
27S  2.7  10  27  1016
4 15
S  104
MX  M3   MX2
12. D
Sol. Fact
13. B
Sol. It can donate H
14. B
Sol. Common ion effect affects only weak component dissociation
15. A
Sol. Fact
16. B
2
Sol.  Ag  SO4 2    6.4  10 5
 
 0.1 SO4   6.4  105
2
2
SO4 2    6.4  103

 
17. C
Sol. Common ion effect
18. D
Sol. Fact
19. B
AgNO3  HCN 
 AgCN  HNO3
0.02 0.02M
1L 1L
AgCN  Ag  CN .........(1)
S S

HNO3  H  NO3
0.02
0.01 0.01
2


H  CN 
 HCN
.........(2)
0.01 S O
0.01  S O S
On adding (1) & (2), we get



AgCN H  
 Ag  HCN
 S
 Ag  HCN
 1010  4  1016  
1
K eq 
9 H 
2
 Ag 
 106   2
4
9 10
4 2
 108   Ag 
9
2
 104   Ag 
3
20. C
Sol. O  U  q  w
(a) q  w
Magnitude of q  w
(b) S is a state function
(c) H  S  O
(d) A  B W  1 40  20   20  atm
B 
C W  O
V2
 A W = 2.303  PV log
C 
V1
21. 8
Sol. Gº  2.303  8.314  500 log 1  0
Hº  TSº
4000
Sº  8
500
22. 4
OH
B
O O
B B
Sol. O
O O
B
OH
23. 1.56
Sol. N2O4 


 2NO
1 O
1  2
kp 
n  NO2 P 
1
n 
nN2O4  
 2  0.33 
2
 P 
For 33% dissociation, kp   1.33 
0.67  
 2  0.40 
2
 P 
For 40% dissociation, kp   1.40 
0.60  
P1
 1.56
P2
24. 1.3
0.45  10  40  0.05 4.5  2
Sol. H   
50 50
2.5
=  0.05
50
pH = – log (0.05) = 1.3
25. 1.01
qsurr qsys w surr
Sol. Ssurr   
T T T
Pext  V2  V1  3  2  1
Ssurr  
T 300
= 1.01 J k 1
HINTS & SOLUTIONS

MATHEMATICS
1. C
4 = 9 (1-e )
2
 e  5 /3
2b 2  3  3 18
Distance between the directrices =   Ans.
e 5 5
2. A
Given equation becomes
2
– cos(A – C) cos(A + C) +1 – 2sin B = 0
 1 – 2sin B – cos A + sin C = 0
2 2 2
 sin A + sin C = 2sin B

2 2 2
 a + c = 2b
2 2 2
 a , b , c are in A. P.
2 2 2
3. D
x2 y2
Equation of ellipse is   1 . General tangent to the ellipse of slope m is y = mx 
2 1
2m 2  1 , since this is equally inclined to axes, so m =  1. Thus tangents are
y=x 2  1  x  3
3
Distance of any tangent from origin is then equal to .
2
4. C
Any tangent of slope m is y = mx  a 2m 2  b 2 , if it passes through (2a, 0), then 3a2m2 = b2
b2
 3m =
2
 1  e 2  3m2 + e2 = 1.
a2
5. B
2 2
The ellipse is 9x + 5(y – 3) = 45
x 2 y  3 
2
  =1
5 9
 5 = 9(1 – e )
2
 e = 2/3.
6. D
(6 – a) > (2 – a) for all real a.
But we also require 6 – a > 0 and 2 – a > 0
 a < 6 and a < 2
 a < 2.
7. B
b2  c 2  a2
cos A =
2bc
 1 
  8  4 3  2 3 1 3
 4
1
 
12  4 2 1  3  2

or A 
3
8. D
Any tangent of slope m to the hyperbola x  3y = 1 is
2 2
1 1
y = mx  m2  c =m 
2 2
3 3
9. C
b
The asymptotes are y =  x
a
b b

 tan30° = a a  2ab  1
b2 a2  b2 3
1 2
a
 a – b =  23 ab.
2 2
2 2 2 2
Also a + b = a e
 e – 16e + 16 = 0
4 2
 e = 8  43
2
 e = 6  2.
10. A
y2 x2

 5
The hyperbola is =1
2
22
Its transverse axis is along y–axis.
4 3 3 5
e= 1 = = .
5 5 5
11. C
2 2
Normal to hyperbola will be ax cos + by cot = a + b
If this is same as lx + my + n = 0, comparing the coefficients,
a cos  b cot  a2  b2
 =
l m n
an  bn
sec = –
l a b
2
2

, tan =
m a2  b2  
sec  – tan  = 1
2 2
a2 b2
 2  2 
a2  b2   2
.
l m n2
12. B
2 2
The pair of lines x – 3y + 3xy + 3x (lx + my) = 0 are perpendicular to each other.
2
 1 – 3 + 3l = 0  l =
3
3 
Hence the chords are 2x – 3 + 3my = 0, which pass through the fixed point  , 0  .
2 
13. A
z1  z 3 
Since diagonals are perpendicular to each other arg =
z2  z4 2
 z1 –z3 = ik( z2 – z4).
14. B
z lies on the line segment joining the complex numbers –1 and 1 .
15. A
The modulus of all the roots of unity will be 1.
16. A
2
Multiply by x throughout, x – 2cos.x + 1 = 0
Solving, x = cos  i sin
x = cosn  i sin
n
-n
x = cosn  i sinn
1
x +
n
= 2cosn.
xn
17. D
2
 1 1
y –y + a =  y   a
2
.
 2 4
Since - 2  sin x + cos x  2 , given equation will have no real value of x for any y
1
if a  > 2
4
 1 
i.e. a   2  ,    a  ( 3 , ) ( as 2 + 1/4 < 3 )
 4 
18. A
sinx + siny + sinz = 3, x, y , z  [ 0, 2 ]
  
x = , y= ,z= .
2 2 2
19. A
sinx -sinx
e +e = 2 sinx
 2 and 2 sinx  2
sinx -sinx
clearly e +e
Thus the equation cannot have a solution.
20. C
3
sin2A and 3 sin A = 1 – 2sin B  3sin A = cos2B.
2 2 2
sin2B =
2
Now, cos(A + 2B) = cosA cos2B − sinAsin2B
2 3
= cosA(3sin A) − sinA( sin2A) = 0
2

 A + 2B = .
2
21. 8
The sum of the focal distances of P = major axis .
22. 2
2  (2R) = a + b + c
2 2 2 2
 8R = 4R (sin A + sin B + sin C)

2 2 2 2 2
 sin A + sin B + sin C= 2

2 2 2
23. 4.00
2
Let z = x + iy, then Re (z ) = 0
x =y
2 2
and |z| = a 2 (1)

 x + y = 2a
2 2 2
(2)
Solving (1) and (2) we get x =  a, y = a. So there are four solutions
24. 4.00
By definition of equation of normal, we can have 4 normals from a point as per the equation of the
normal from a point. These 4 points are called as co-normal points.
25. 3.00
b c sinB b
Since  , we have 
sinB sinC sinC c
sinB b b
or  or tanB   3
sin  90º B  c c

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myPAT Test Series-3_1

2. A liquid of density  is completely filled in a rectangular closed L

5. A tank is filled with water upto a height H. Water is allowed to

7. An L-shaped glass tube is just immersed in flowing water

10. Liquid reaches an equilibrium as shown, in a capillary tube of internal P

(A) T2 is the melting point of the solid

24. Figure shows a siphon in action. The liquid flowing B C

pressure inside the bubble is xx.xx  10 , where xx.xx ?

1. Thermal stability of BaCO3, CaCO3 and MgCO3 is

2. In which of the following bonds does H carry a partial negative charge?

3. In which compound is the bonding largely covalent?

8. In the following reaction, 2SO2(g) + O2(g) 2SO3(g)

(C) 1  10 mol L (D) 2  10 mol L

12. The main factor responsible for weak acidic nature of BF 3 is

14. The addition of HCl will not suppress the ionisation of

15. For the following equilibrium

17. Degree of ionisation of 1 M HCOOH is decreased to a maximum extent in presence of :

18. Buck ball or buckminister fullerene is

20. On the basis of following graph (P –V graph),

PART – III : MATHEMATICS

If in a ABC, cos(A - C)cosB + cos2B = 0, then a , b , c are in

If y = mx + c is a tangent to the hyperbola x  3y = 1, then

(D) None of these

14. For a complex number z , | z-1| + |z +1| =2. Then z lies on a

15. The cube roots of unity lie on a circle

18. If sinx + siny + sinz = 3, x, y, z  [ 0, 2], then

(Numerical Answer Type)

HINTS & SOLUTIONS

HINTS & SOLUTIONS

SO4 2    6.4  103

On adding (1) & (2), we get

HINTS & SOLUTIONS

 sin A + sin C = 2sin B

 8R = 4R (sin A + sin B + sin C)

 sin A + sin B + sin C= 2

and |z| = a 2 (1)

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