Catalytic Infrared Dehydration of Onions: E: Food Engineering and Physical Properties
Catalytic Infrared Dehydration of Onions: E: Food Engineering and Physical Properties
Catalytic Infrared Dehydration of Onions: E: Food Engineering and Physical Properties
ABSTRACT: Dehydrated onions are commonly dried with convection heating, which is inefficient and costly. This
study compared the drying and quality characteristics of onion dried with catalytic infrared (CIR) heating and forced
air convection (FAC) heating. Sliced high-solids onions were dehydrated under 9 conditions: CIR heating with and
without air recirculation, and FAC each operated at 60, 70, and 80 ◦ C. In general, CIR both with and without air
recirculation had higher maximum drying rates, shorter drying times, and greater drying constants than FAC at
moisture contents greater than 50% (d.b.). Dried onion quality, measured as pungency degradation, was similar for
both the drying methods at 60 and 70 ◦ C. The color analysis showed better product color (whiter and less yellow) at
lower temperatures for CIR and higher temperatures for FAC. The browning could have been caused by the higher
surface heat flux of the CIR heating and longer process times of FAC drying. Aerobic plate counts and coliform counts
were not significantly different for either product from the CIR or FAC drying. However, samples dried by the CIR
had significantly lower yeast and mold counts than those dried by the FAC. It is recommended that CIR be used in
the early stages of onion drying.
Keywords: dehydration, drying, infrared, onion, pungency
Introduction water, which could result in rapid moisture removal. Because the CIR
Technologies LLC., Independence, Kans., U.S.A.) mounted from the perature. The ratio of emitter on and off time decreased with the
top of the chamber. The sample was placed on a drying tray (84 × increase of moisture removed and drying time. The emitter surface
53 cm), which consisted of a fine mesh aluminum screen stretched temperature decreased rapidly during the intermittent heating pe-
across a strip steel frame. At the product surface, IR intensity de- riod, which lasts about 20 to 30 min before the emitter temperature
creased away from the center of the drying tray. When the drying tray was stabilized at about 100 ◦ C. In the temperature control, when
was positioned 20 cm below the emitter, the intensity at the tray’s the emitter temperature was below 150 ◦ C, the natural gas may not
center was 4818 W/m2 . Average intensity at 15 points across the tray be effectively catalyzed and emitter temperature was maintained by
at this distance was 2226 W/m2 measured using an Ophir FL205A the electric heating unit in the emitter.
Thermal Excimer Absorber Head (Ophir Optronics Inc., Wilming- Thermocouples and balance inputs were processed by using a
ton, Mass., U.S.A.). An aluminum waveguide (48 × 30 cm, upper data acquisition system, which was developed at Univ. of California,
rim; 42 × 22 cm, base perimeter), used to achieve a uniform heating Davis and consisted of a personal computer with Test Point software
of the entire product, rested on top of the drying tray and surrounded (Capitol Equipment, Bedford, N.H., U.S.A.).
the product. A balance (Ohaus Adventurer Pro; 8 kg capacity, 0.1 g
accuracy) was placed beneath the drying tray and measured prod- FAC dryer setup
uct weight during drying. A 1/100 HP exhaust fan (Dayton Electric
The FAC dryer used in the tests was an electrically heated column
Mnfg.) was located on the top of the drying chamber for ventilation.
dryer with diameter of 33 cm. A fan powered by a 3/4 HP permanent
Two 1/10 HP fans (Dayton Electric Mnfg.) mounted on each side of
magnet DC motor (Dayton Electric Mnfg.) blew heated air through
the dryer were used to recirculate part of the warm air in the drying
an electric coil heater and then through the column. Product was
chamber. These fans pulled air from the top of the drying chamber
placed in a circular mesh tray near the bottom of the column and
and fed it back into the chamber through slits running the entire
suspended by wires to the Ohaus balance to record product weight
length of the drying chamber.
change during drying. The temperature of heated air was also con-
The CIR emitter was preheated by an electric element located
trolled by the same computer control system as the CIR dryer using
inside the emitter. The natural gas intake was regulated by a gas
a Type T thermocouple to measure the temperature of the air before
control valve controlled by a computer system. Two Type-T thermo-
it reached the product. The on and off cycles of the electric heating
couples (response time 0.15 s) were used to measure the product
coils were controlled automatically to maintain the set point tem-
temperature. Each thermocouple was placed inside the flesh of an
E: Food Engineering & Physical Properties
perature. The air velocity for all of the tests was maintained at 0.5
onion slice, which was placed within the innermost 10 cm2 of the
m/s.
onion bed. The average temperature was used as input to control
the product temperature by turning the emitter on or off, which was
achieved by opening and closing the gas supply valve of the emitter. Drying trials
For example, the temperature of the emitter surface was 752 ± 22 ◦ C Nine conditions were tested: CIR heating with and without air
in the early heating stage. It took 8, 11, and 13 min to heat the product recirculation, and FAC each operated at 60, 70, and 80 ◦ C. An onion
to the set temperatures of 60, 70, and 80 ◦ C, respectively, without air sample, 250 g for CIR and 150 g for FAC, of intact slices was arranged
circulation. A large amount of moisture had been removed during in a single layer on the drying tray at a loading rate of 2.5 kg/m2 . For
this drying period. After the product reached the set temperature, CIR the drying tray was placed in the preheated CIR drying cham-
the emitter was automatically turned off and the emitter tempera- ber and the thermocouples were positioned as described above. Dis-
ture started to decrease. Once the product temperature was below tance between the emitter and drying tray was 15 cm with maximum
the set temperature, the emitter was turned on again to maintain intensity of 4752 W/m2 . CIR drying tests with air recirculation had
the product temperature. During the intermittent heating period, both the recirculation fans on during the entire test. Average air ve-
because a large amount of moisture had been removed, a relatively locity was set at 0.5 m/s. Each weight point was averaged with the
small amount of energy was needed to maintain the product tem- 2 prior and 2 consecutive points to correct for noise. Weight data
were also corrected for lift created by air inside the dryers based on
the weights with and without air flow. Onion weight and temperature
were recorded every 60 s with the aforementioned data acquisition
3 4 and control system.
Targeted final moisture content (MC) of the dried onion was set
at 10% (d.b.) in this study. The final weight of dried onion sample
2 5 was determined based on the initial and final MC and initial sample
weight. The experiments were replicated 2 or more times.
1
Drying kinetics
Drying rate was calculated in grams of moisture loss per kilogram
of initial weight of onion sample per minute (g/kg initialweight min). The
6 exponential model was chosen to describe the drying process. Model
curves were fitted to the experimental data and the performance of
7 8 11 the model was determined by the correlation coefficient (R2 ).
10 The exponential model is as follows:
9
M − Me
MR = = exp [−kt] (1)
Figure 1 --- CIR dryer: 1 --- natural gas; 2 --- gas flow M0 − Me
control; 3 --- air exhaust; 4 --- blower; 5 --- CIR emitter;
6 --- recirculation warm air; 7 --- computer controller;
8 --- wave guide; 9 --- thermocouple, 10 --- onion sample; where MR is the moisture ratio; M is the moisture content (% d.b.) at
11 --- balance any given time during drying; M 0 is the initial moisture content; M e
E352 JOURNAL OF FOOD SCIENCE—Vol. 71, Nr. 9, 2006 URLs and E-mail addresses are active links at www.ift.org
Catalytic infrared dehydration . . .
is the equilibrium moisture content; k is the drying constant (h−1 ); Statistical analysis
and t is time in h. Data from the quality test experiments and drying times were sta-
Moisture ratio (MR) was determined using the moisture con- tistically evaluated in Excel using the t test with the assumption of
tent data collected in the drying experiments. The fixed 4% (d.b.) equal variances. The pungency values for FAC and CIR were com-
equilibrium moisture content (EMC) was estimated from findings pared at each time interval for each temperature. Any value that
in literature (Wang 2002). For each drying condition, MR data was statistically significant (P < 0.05) is indicated in Table 2. The
were plotted on semilogarithmic axis versus the time (h) and the measured color results were compared for all 3 drying methods and
slope of the fitting line was the constant k. Correlation coefficients, any method that was significantly different was indicated in Table 3.
means, and standard deviations were also calculated for all 9 drying
conditions. Results and Discussions
Quality tests Drying rates and kinetics
Pungency. The effect of drying on pungency was determined Drying rates. When the drying rates were calculated and plotted
with 4 trays each containing 40 g of sliced onions, which were dried against moisture content (Figure 2) for each of the 3 drying temper-
simultaneously. Trays were removed at 10, 20, 30, and 40 min for atures, the CIR tests showed much higher drying rates throughout
80 ◦ C experiments; 10, 20, 40, and 60 min for 70 ◦ C experiments; and the course of drying than the FAC drying before the MC reached
30, 60, 120, and 180 min for 60 ◦ C experiments. These times corre-
spond to the approximate times that were required to achieve a 10%
MC (d.b.) at each temperature. After removal, sample weight was
measured and corresponding MC was calculated. Deionized wa-
ter was added to the dried products until the total weight of water
plus product was 90 ± 1 g. After rehydrating for 5 min, the samples
were homogenized for 30 s at 7000 rpm and 30 s at 10000 rpm us-
ing a hand-held homogenizer (Bahmix Bio-Mixer, Bartlesville, Okla.,
U.S.A.). Slurries were held for 30 min at room temperature before
filtering through 2 layers of cheesecloth.
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Catalytic infrared dehydration . . .
50%. Below this moisture content the decreased drying rates for CIR
drying could be due to lower moisture transfer rate in the onion slices
for the CIR than the FAC. The air flow might help with the moisture 1
removal at the low moisture range. Increasing the drying temper- 0.9
(a) 60°C
ature in the CIR drying trials increased the drying rate. A minimal
0.8
increase in drying rate was noted for FAC drying as air temperature 60°C CIR- Recirculation
Moisture Ratio, MR
It is apparent that air recirculation in the CIR drying caused lower 0.6 60°C FAC
drying rates, especially for the 60 and 80 ◦ C trials although an slight 0.5
Predicted
which has been reported by Sandu (1986) and Paakkonen and others 0.2
(1999). 0.1
onions are hygroscopic and hygroscopic foods tend to quickly enter 0.9
(b) 70°C
the falling rate period (Rahman and Perera 1999). Additionally, sur-
0.8
face drying may occur more rapidly with CIR drying, which results 70°C CIR- Reciruclation
70°C CIR
in quicker entrance to the falling rate period due to slow water dif- 0.7
Moisture rat io, MR
70°C FAC
fusion to the surface of the onion. It is similar to many other foods 0.6
Predicted
that do not exhibit a constant rate-drying period due to the colloidal 0.5
period was not as profound as the other 2 temperatures. This might 0.2
be due to the lower heat flux, which resulted in a longer time to reach 0.1
the critical moisture content. Almost all of all tests showed linear
0
relationships between the drying rates and moisture contents for 0 10 20 30 40 50 60 70 80 90 100
Time, min
the period of moisture content from 50% to 225% (d.b.). 1
80°C CIR
onion. For existing drying facilities, IR drying could be considered 0.7
Moisture Rati o, MR
80°C FAC
by adding a unit at the front of current conventional drying systems 0.6
Predicted
to take advantage of the high drying rate of IR for improving the 0.5
imum drying rates of CIR were significantly higher (P < 0.05) than 0.2
difference (P > 0.05) was observed between the CIR drying with and
0
without air recirculation at each corresponding temperature. 0 10 20 30 40 50 60
Time, min
Drying modeling. Based on the modeling results, the exponen-
tial model fits well with the experimental data from CIR drying Figure 3 --- Predicted and measured moisture ratio at dif-
(Table 1 and Figure 3). The correlation coefficients (R2 ) were greater ferent drying time and temperatures: (a) 60 ◦ , (b) 70 ◦ , and
◦
than 0.988. It has been reported that the Page model can be used for (c) 80 C
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Catalytic infrared dehydration . . .
Table 2 --- Pungency changes during drying at different drying temperatures (percent pyruvate of fresh sample). Mois-
ture content is percent dry basis (d.b.).
Minutes of heating
30 60 120 180
60 C ◦
CIR 89.1 ± 15.7 79.1 ± 3.2 62.4 ± 7.9 59.3 ± 1.0
Moisture content (%) 142.4 69.2 22.5 14.4
FAC 80.7 ± 8.5 70.2 ± 3.7 63.9 ± 7.0 65.1 ± 0.4a
Moisture content (%) 106.2 39.3 20.1 15.6
Unheated sample at 180 min: 99.2 ± 7.2
10 20 40 60
70 ◦ C CIR 86.1 ± 5.4 80.7 ± 19.4 73.6 ± 1.9 83.6 ± 4.9
Moisture content (%) 135.7 69.5 19.6 15.7
FAC 115.2 ± 11.2a 70.0 ± 17.0 74.9 ± 0.2 74.2 ± 18.2
Moisture content (%) 148.6 69.3 21 9.7
Unheated sample at 60 min: 104.0 ± 2.3
10 20 30 40
80 ◦ C CIR 93.7 ± 32.5 69.9 ± 25.0 73.0 ± 6.2 61.3 ± 4.6
Moisture content (%) 81 30.5 21.1 11.2
FAC 89.9 ± 20.4 96.2 ± 18.8 97.3 ± 14.8a 94.0 ± 3.8a
Moisture content (%) 151.3 73.4 41.6 24.6
Unheated sample at 40 min: 89.4 ± 2.8
a
Significantly greater value (P < 0.05) for same time interval and temperature.
modeling the drying characteristics of onions under infrared heating inactivation and/or precursor degradation (Brewster and Rabinow-
(Wang 2002; Sharma and others 2005). After examining the fitness itch 1990). Significant color changes were also noted during this time
of the Page model for the CIR drying, it was found that the drying ex- (Table 3).
ponents of the Page models were close to 1 and the improvement in The large variability of measured pungency results could be
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Catalytic infrared dehydration . . .
Table 4 --- Microbial data for aerobic plate counts, coliform counts, and yeast and mold counts of CIR and FAC dried
samples (reported as log CFU/10 g dried sample)
Trial 1 Trial 2 Average 3
Fresh 5.24 Fresh 5.54 Fresh 5.39 ± 0.22
Aerobic plate counts CIR FAC CIR FAC CIR FAC
60 ◦ C 4.21 4.08 60 ◦ C 3.23 3.41 60 ◦ C 3.72 ± 0.70 3.75 ± 0.47
70 ◦ C 3.98 4.05 70 ◦ C 3.71 3.36 70 ◦ C 3.85 ± 0.19 3.71 ± 0.49
80 ◦ C 3.97 4.03 80 ◦ C 3.37 3.39 80 ◦ C 3.67 ± 0.42 3.71 ± 0.45
Fresh 5.27 Fresh 5.51 Fresh 5.39 ± 0.17
Coliform counts CIR FAC CIR FAC CIR FAC
60 ◦ C 3.04 3.95 60 ◦ C 2.40 2.40 60 ◦ C 2.72 ± 0.45 3.18 ± 1.10
70 ◦ C 2.18 3.93 70 ◦ C 2.40 2.18 70 ◦ C 2.29 ± 0.16 3.05 ± 1.24
80 ◦ C 1.70 3.00 80 ◦ C 1.00 1.00 80 ◦ C 1.35 ± 0.49 2.00 ± 1.41
Fresh 4.56 Fresh 4.84 Fresh 4.70 ± 0.20
Yeast and mold counts CIR FAC CIR FAC CIR FAC
60 C◦
4.16 4.72 ◦
60 C 4.12 4.81 ◦
60 C 4.14 ± 0.03 4.77 ± 0.07
70 ◦ C 3.83 4.69 70 ◦ C 4.00 4.31 70 ◦ C 3.92 ± 0.12 4.50 ± 0.27
80 ◦ C 3.44 4.10 80 ◦ C 3.44 4.00 80 ◦ C 3.44 ± 0.00 4.05 ± 0.07
A higher b value indicates a higher degree of browning and in samples dried in the CIR dryer, which may have been a result of
other color developments caused by enzymatic and nonenzymatic greater heat fluxes from the CIR emitter. The reduction of yeast and
browning reactions. Thus there was more color development in the mold in the dried samples with either drying method was no greater
CIR dried samples at higher temperatures due to the aforemen- than 1.4 log.
tioned reasons. Likewise, FAC drying has less browning at higher
temperatures due to a shorter drying time. The higher b values of
samples dried at 60 and 70 ◦ C with CIR plus air recirculation could be Conclusions
T hese experiment results indicate that CIR heating is an effec-
E: Food Engineering & Physical Properties
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