Gta220 GBR Eng1 PDF

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The document describes a safety data sheet for a thinner and equipment cleaner product called International Thinner-Eqpt Cleaner. It provides information on the product ingredients, hazards, first aid measures, firefighting, accidental releases, handling and storage, exposure controls, stability and reactivity, toxicological information, ecological information, disposal considerations, transport information, regulatory information and other details.

The product being described is International Thinner-Eqpt Cleaner, which is a thinner and equipment cleaner for professional use.

The product is flammable and harmful if inhaled, in contact with skin or swallowed. It can cause serious eye damage and is irritating to the respiratory system and skin. It is also toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.

International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

1. Identification of the preparation and company

Preparation/Product Name International Thinner-Eqpt Cleaner


Product Code GTA220
Reg Number
Intended use See Technical Data Sheet.
For professional use only.
Application Method See Technical Data Sheet.
Company Name International Paint
Stoneygate Lane
Felling
Gateshead
Tyne and Wear NE10 OJY
UK
Telephone No. +44 (0)191 469 6111
Fax No. +44 (0)191 438 3711
24 hour Emergency Telephone No. +44 (0)191 469 6111
Official Advisory Body Telephone No. +44 (0)870 600 6266 For Advice to Doctors & Hospitals only
Email sds@internationalpaint.com

2. Hazard identification of the product

Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Risk of serious damage to eyes.
Irritating to respiratory system and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: May cause lung damage if swallowed.

Further information is given in section 11.


Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 1
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

3. Composition/information on ingredients

If the product contains substances that present a health hazard within the meaning of the Dangerous Substances Directive
67/548/EC, or have occupational exposure limits detailed in EH40, these substances are listed below.
Ingredient EINECS Concentration Symbol(s) Risk phrases (*)
1,2,4-trimethylbenzene 202-436-9 10 - < 25 Xn,N R10,R20,R36/37/38,R51-53
1,3,5-trimethylbenzene 203-604-4 2.5 - < 10 Xi,N R10, R37, R51-53
Butan-1-ol 200-751-6 25 - < 50 Xn R10,R22,R37/38,R41,R67
Ethylbenzene 202-849-4 2.5 - < 10 F,Xn R11, R20
Solvent naphtha (petroleum), light aromatic 265-199-0 10 - < 25 Xn,N R51-53, R65
Xylene 215-535-7 25 - < 50 Xn R10,R20/21,R38
* The full texts of the phrases are shown in section 16.

4. First aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious
place in the recovery position and obtain immediate medical attention. Give nothing by mouth.

Eye Contact
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical attention.

Skin Contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin cleanser. Do NOT use
solvents or thinners.

Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 2
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

5. Fire-fighting measures

Recommended extinguishing media; alcohol resistant foam, CO². powder, water spray.

Do not use; water jet.

Note; Fire will produce dense black smoke. Decomposition products may be hazardous to health. Avoid exposure and use
breathing apparatus as appropriate.

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire
fighting to enter drains or water courses.

6. Accidental release measures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or spillage
in a confined space evacuate the area and check that solvent vapour levels are below the Lower Explosive Limit before re-
entering.
Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containers outside
buildings and dispose of according to the Waste Regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents.

Do not allow spills to enter drains or watercourses.

If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the case of
contamination of rivers, streams or lakes the Environmental Protection Agency should also be informed.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 3
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

7. Handling and storage

Handling
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive
mixtures with air. Areas of storage, preparation and application should be ventilated to prevent the creation of flammable or
explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits.

In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical
equipment are protected to the appropriate standard.

In Use
Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Use personal protection
as shown in section 8.

Smoking, eating and drinking should be prohibited in all preparation and application areas.

Never use pressure to empty a container; containers are not pressure vessels.
All sources of ignition (hot surfaces, sparks, open flames etc) should be excluded from areas of preparation and application. All
electrical equipment (including torches) should be protected (Ex) to the appropriate standard.

The product may charge electrostatically. Always use earthing leads when pouring solvents and transferring product.
Operators should wear clothing which does not generate static (at least 60% natural fibre) and antistatic footwear; floors should
be of conducting type.

Storage
Store in a well ventilated, dry place away from sources of heat and direct sunlight.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack more than 3 pallets
high.

Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Keep in the original container or one of the same material.

Prevent unauthorised access.


The requirements of the Highly Flammable Liquids and Liquified Petroleum Gases Regulations apply if the flashpoint is
between 21°C and 32°C.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 4
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

8. Exposure controls and personal protection

Engineering Measures
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and
good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapour below
occupational exposure limits suitable respiratory protection must be worn.

Exposure Limits
The following workplace exposure limits have been established by the Health and Safety Executive as published in EH40.

Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m³ ppm mg/m³
1,2,4-trimethylbenzene 25 125
1,3,5-trimethylbenzene 25 125
Butan-1-ol 50 154 - - +
Ethylbenzene 125 552 100 441 +

Xylene 100 441 50 220 +

For Key to entries in 'Comments' column see Section 16

Personal Protection

Respiratory Protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. When
spraying this product use a respiratory mask with charcoal and dust filters (as filter combination A2-P2). In confined spaces
use compressed air or fresh air respiratory equipment.

Eye Protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids. Eyewear should comply
with British Standard 2092.

Hand Protection
Nitrile rubber gloves should be worn during mixing and application.

Skin Protection
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams may help to protect
areas which are difficult to cover such as the face and neck. They should however not be applied once exposure has occurred.
Petroleum jelly based types such as Vaseline should not be used. All parts of the body should be washed after contact.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 5
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

9. Physical and chemical properties

Physical State Liquid


Flash Point (deg C) 25
Viscosity (cSt) 1
Specific Gravity 0.852
Vapour Density Heavier than air.
Lower Explosive Limit .8
Solubility in Water Immiscible
R.A.Q. to ventilate to 10% of the LEL (m ³/l) 247

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7). When exposed to high temperatures may
produce hazardous decomposition products such as carbon monoxide, carbon dioxide, oxides of nitrogen and smoke.

Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible exothermic reactions.

11. Toxicological information

There are no data available on the preparation itself. The preparation has been assessed following the conventional method of
the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Sections 2 and 15
for details.
Exposure to solvent vapour concentrations from the component solvents in excess of the stated occupational exposure limits
may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the
eyes may cause irritation and soreness with possible reversible damage.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 6
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

12. Ecological information

There are no data available on the product itself.

The product should not be allowed to enter drains or water courses.


The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details

13. Disposal considerations

Do not allow into drains or water courses. Wastes and emptied containers should be disposed of in accordance with
regulations made under the Control of Pollution Act and the Environmental Protection Act.

Using information provided in this data sheet advice should be obtained from the Waste Regulation Authority, whether the
special waste regulations apply.

The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11 Waste paint and varnish
containing organic solvents or other dangerous substances. If mixed with other wastes this code may no longer apply and the
appropriate code should be assigned. For further information contact your local waste authority.

14. Transport information

Transport only in accordance with the following regulations:


ADR/RID UN1263 Paint related material, 3, III

IMDG Class 3 Subsidiary Class


Proper Shipping Name PAINT RELATED MATERIAL
UN No 1263
Ems F-E,S-E
Packaging Group III
Marine Pollutant Yes

PAINT RELATED
ICAO/IATA Shipping Name
MATERIAL
Class 3 Subsidiary Class
UN No 1263
Packaging Group III
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 7
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

15. Regulatory information

In accordance with EC Directive 88/379/EEC and the Chemicals (Hazard Information and Packaging for Supply) Regulations
SI /3247/1994 this product is labelled as follows:

Symbol(s)
Harmful
Dangerous for the environment

Contains;
Butan-1-ol
Xylene

R. Phrases;
Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Risk of serious damage to eyes.
Irritating to respiratory system and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: May cause lung damage if swallowed.

S. Phrases;
Do not breathe vapour/spray.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
Use only in well-ventilated areas.

P. Phrases;
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 8
International Paint

Safety Data Sheet


GTA220
International Thinner-Eqpt Cleaner
Version No. 17 Date Last Revised 21/07/08

16. Other information

The information in this Health & Safety Data Sheet is required pursuant to Directive 91/155/EEC and the Chemicals (Hazard
Information & Packaging for Supply) Regulations 1994.

Key to 'Comments' column in Section 8.


(+) There is a risk of absorption through unbroken skin.
(C) Capable of causing cancer and/or heritable genetic damage
(R) Suppliers recommended limit
(S) Capable of causing occupational asthma

The full text of the R phrases appearing in section 3 is:


R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51-53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness

Registered in England Company No. 63604. Registered office 26th Floor, Portland House, Bressenden Place, London,
SW1E 5BG
and all product names mentioned in this publication are trademarks of, or licensed to,
Akzo Nobel.
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data Sheet and the package labelling
comprise an integral information system about this product. Copies of the Product Data Sheet are available from International Paint on
request or from our Internet sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 9

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