Heat, The Mechanical Universe

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HEAT

Notes from “THE MECHANICAL UNIVERSE”, Dr. Goodstein

PAGE 1 OF 2

TEMPRATURE AND GAS LAWS  As the gas warms, its volume increase in proportion
to temperature.
Temperature
 Lacks physical dimension According to Joseph Louis Gay-Lussac (1778 –1850),
 Difficult to measure directly the lowest possible temperature where gas molecules
 Could be measured in terms of its effects have no heat is -273C. (After interpolation)

HEAT – the energy of random motion of atoms and Lord Kelvin:


molecules.
TV
N
P K But twice as much gas must occupy twice the volume.
V Therefore V must also be proportional to the number of
molecules of gas.
N, is the number of gas molecules
V, volume of the gas V  NT
K, average KE of the molecules
Boyle’s Law – at any constant temperature, PV =
By applying Newton’s Law to individual gas molecules, constant. If T changes, the constant must also change.
they found that the constant of proportionality is 2/3.
PV  kNT
2 N
P K
3 V 23 J
k  1.38  10
K
Boyle’s Law – Robert Boyle (1627 – 1691): As long as
the temperature remains unchanged, This definition determines the size of 1K and with it, fixes
the whole Kelvin temperature scale.
PV = constant
Charles and Gay-Lussac experiments suggest that since
Therefore, gas can be compressed, gases must be composed of
discrete particles separated by a void.
2
constant = NK Applying the Laws of Mechanics to these invisible
3 molecules leads to the Kinetic Theory of Gases which
says, the KE of a gas, i.e. the collective effects of
This Kinetic Energy (K) is in the form of HEAT. collision, is what gives the gas its pressure and volume.
Jacques Charles (1746 – 1823), balloon enthusiast.
2
 Found out that all gases expand by the same amount PV  NK
with a given rise in temperature. 3
 At a given pressure, the volume of any gas changes
by the same fraction for each degree rise in Butt PV is also related to the absolute temperature
temperature.
PV  kNT

 This means that there could be a temperature so low Thus there is a direct relationship between
where there is no volume at all. TEMPERATURE and HEAT.
NOTES ON HEAT FROM THE “MECHANICAL UNIVERSE” PAGE 2 OF 2

2
kT  K
3

T, absolute temperature
K, mean average KE of one molecule of gas

And of course, heat in gas is just the average kinetic


energy of its molecules.

In other words, heat and temperature can be related to a


mechanical property, the KE of individual molecules of
gas.

PV  kNT is called the Ideal Gas Law.

Not all gases are ideal but the law accurately describes
how numerous real gases behave.

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