Chemical Bonding
Chemical Bonding
Chemical Bonding
CHEMICAL BONDING
ALLEN
CAREER INSTITUTE
(POTENTIALENERGY CURVE)
Puk to Sucees
KOIA (RAJASTHAN
TRODUCTION OFCHEMICAL BONDING
IN energy is minimum ),
1. internuclear distance below.the optimum distance (where potential
On decreasing
there is steep increase in potentialenergy duc to
electrons and nucleus
(A)Increase in force of attraction between
(B)Increase in stability of bonded atoms
(C) Equal probaility of finding
bonding electrons near to either of nuclei
repulsions
(D) Increase in interelectronic and internuclear
HYDRATION ENERGY)
IONICBOND (LATTICE ENERGYAND
2. For latticeenergy the following statements are false :
(A) it increases with increase in charge on cation.
(B) it increases with increase in charge on anion.
ionic distance.
(C) it increases with decrease in inter
of cations & anions.
(D) it increases with increase in size
energies ?
represents the correct order of lattice
3. Whichof the following sequences KI
(A) Lii>LiBr<LiCI<LiF (B) KBr< KCl< KF <
(D)LiF > LiCl> LiBr> Lil
(C) NaF< Nacl <NaBr > Nal
decreasing lattice energy is :
4. The correct expected order of
(B) MgBr, > CaO > Csl
(A) CaO> MgBr, > Csl
(D) CsI> Ca0 > MgBr,
(C) Csl> MgBr,> CaO
ionicradius in H,0:
5. The CORRECT order of (D) Sct > K*> Caz
>Sc' (B) Ca?> Sct >K* (C) Sc3t > Ca?t> K
(A)K*> Ca?
order is CORRECT
6.
Which of thefollowing
(A)K*< Ca?<p-<S:Atomicsize
> Rb"(aq) > Cs(aq) : Electricalconductance
(B) Na»(aq)> K»(aq) size
AI³"(aq) > Mg(aq) > Na'(aq) : Hydrated
(C) mobility
<Br (aq) < CI (aq) <F (ag): lonic
(D) I (aq) solution is
sequence of ionic mobility in aqueous
7.
The (B) Na> K*> Rb > Cs
Rb*>K*>Cs*> Na
(A) (D) Cs > Rb'> K> Na
Na> Rbt > Cs
(C) K*>
1
8, electrical conductance in aqueous
ement-l Among the alkali metals lithium salts exhibit the least
solutions.
nee:Smaller the radius of the hydrated cation, lower is the electrical conductance in aqueous
solutions,
(A) Sutement-I is true, Statement-2 is true and Statement-2 is correct explanation for Statement- l
(B) Statement-I is true, Stateent-2 is true andStatement-2 is N T the correct explanation for Statement-l
(C) Statement-| is true, Statement-2 is false
(D)Statement-I is false,
)
Statement-2 is true
Which does not permit for the formation of ionic
compound:
(A)the ionization energy ofthe metal
atom should be low
(B) the lattice energy of the compound
formed must be low
(C) the electron aflinity of the
non-metal should be high
(D) the lattice energy of the compound
formed must be high
COVALENT BOND(COVALENCY AND LEWIS OCTET RULE)
|0, The maximumcovalency is equal to
(excluding Ist and 2nd period)
(A)the number of unpaired p-electrons
(B) the number of paired d-electrons
(C) the number of unpaired s and
p-electrons
(D) the actual number of s and
p-electrons in the outermost shell.
The possible structure(s)of
monothiocarbonate ion is :
2
14.
t()forms compounds ofthe formula XCI,. X,0, and Ca,X,, but does not form XC;, which of
the following is the
element X
(A) B (C) N (D) P
(B)AI
15. PCls exists but NCIs does not because :
(A) Nitrogen has no vacant d-orbitals
3
21. interaction of d-orbitals.
Statement-I :§-bonds are formed by four lobes
Statement-2 d,a orbitaldoes not have nodal plane.
ttement-T is true, statement-2 is true and statement-2 is correct explanation tor statenie
statemenl.
tement-l is truc, statement-2 is true and statement-2 is NOT the correct explanation for
(C) Statement- istrue, statement-2 is false.
(D) Statement-| is false, statement-2 is true.
COMPARISION OF oAND T-BOND
STRENGTH
wnen 2s-2s 2p-2p and 2p-2s orbitals overlap, the bond strength decreases in the order:
(A) p-p>s-s >p-s (B) p-p>p-s>S-s
(C) s-s>p-p>p-s (D) s-s >p-s >p-p
23. Which has higher bondenergy:
(A) F2 (B) Cl, (C) Br2 (D) 2
24. Which ofthe following bonds has the highest energy
(A)Se - Se (B) Te - Te (C)S- S (D) O -0
25. Statement-I: In case of pureatomic orbitalsoverlap having same internuclear distance therelative
strength
order is s-s> s -p>p-p.
Statement-2 : The radial distance of's-orbital is less compared to that
ofp-orbital for a particular value of
principalquantum number.
(A) Statement-I is true, Statement-2 is true and Statement-2 is correct explanation for
Statement-1
(B)Statement-I is true, Statement-2 is true and Statement-2 is NOTcorrect explanation for
Statement-1
(C) Statement-Iis true, Statement-2 is false
4
27
Thecorrect order of
acidic strength IS
(A) HF <HCI< HBr<HI (B) HCI<HBr< HF <HI
(C)HBr> HCl <HI<HF (D) HI < HBr< HCI<HF
28.
The most stable hydride is
(A) NH, (B)PH, (C) AsH (D)SbH,
DRDIZATIONAND MOLECULAR SHAPE OF COVALENT SPECIES
29.
Inwhich ofthe followine pairs hybridisation of the central atom is different
(A)CIF; .CIF,0 (B) CIF,0, CIF 0,
(C) [CIF,0] .(CF,O (D) [CIF,o. [XeOF)
30.
lnwhich ofthefollowing cycliccompound the nitrogen atom is sp° hybridised
NO,
H NH,
(B) I, II, III (C) II& IV (D) I, II & IV
(A) I& III
31. Which is the right structure of XeF,
F
(B) (C) (D)
(A)
F
state ?
32. Choose the molecules in which hybridisation occurs in the ground
(a) BCI, (b) NH, (c) PCI, (d) BeF,
Thecorrect answer is :
(B) a, b, c (C) b, c (D) c, d
(A)a, b, d
from the following:
33. Pick out the isoelectronic structure
H,0* II. NH, IV. CH,
I. *CH, II.
I and III (D) II, III and IV
Iand II (B) IIland IV (C)
(A)
atom?
number of lone pairs of electrons on the central
34. Which ofthe species has the the maximum
(B) IF, (C) XeF, (D) BrF3
(A)XeOF,
5
35.
BeCl, is not isostrutural with :
(A) ICI, (B) C,H, (D)GeCl,
36. (C) XeF,
Which ofthe following has aageometry different from the other three speciest(having the same geometry)?
(A) BF (B) so? (C) XeF4 (D) PH¿
37.
n which of the following
molecules / ions all the bonds are not of equal length.
(A)SiF, (B) SF,
38. (C) XeF, (D) BH,
In CIa, the
shape is square planar. The number of bond pair-lone
(A)6 pair repulsion at 90° are:
(B) 8 (C) 12
39. (D) 4
Among the following species, identify the
(A) [NF3.NO;] and isostructural pairs: NF3,NO3,BF3.H,0"HN3
[BF3,H0*] (B) (NF3.HNg] and [NO3,BF3l
(C) [NF3, H30*] and
40.
[NO3, BF3] (D) [(NF3. Hg0*] and [HN3, BF3]
C-C bond in CH; undergoes heterolytic fission, the
(A) sp² both hybridisation of two resulting carbon atoms is/are
(B) sp both (C) sp², sp³
41. The (D) sp, sp²
hybridisation and shape of BrFa molecules are :
(A) sp²d and bent T
shaped (B) sp²d² and tetragonal
(C)sp°d and bent
(D) none of these
42. The structure of XeF, involves
hybridization of the type :
(A) sp (B) dsp² (C) sp°d
43. In the
(D) sp°d
XeFs(solid), the Xe atom is in the
(A) sp²d-hybridized state
(B) sp²-hybridised state
(C) sp°d-hybridized state
(D) spa-hybridized state
44. Which of the following statements are not correct?
(A) Hybridization is the mixing of atomic orbitals
(B) sp² hybrid orbitals are formed
from twop- atomic orbitals and s- atomic
(C) dsp²- adjacent hybrid orbitals are at 90° to one another orbital of same shell
(D) ² sp³ - hybrid orbitals are directed
towards the corners of a regular octahedron
45. Which of the following has been arranged in
increasing order of size of the hybrid orbitals ?
(A) sp < sp² <sp (B) sp < sp <sp
(C) sp <sp < sp (D) sp <sp < sp
6
46.
The shapes of
(A) square planar.,
PCI: PCI, and AsCls arerespectively
tetrahedral and see-saw
(B)
(C)
tetrahedral,. see-saw and trigonalI bipyramidal
tetrahedral, square planar andI pentagonal bipyramidal
(D) trigonal bipyramidal. tetrahedral and
47. In the square pyramidal
context of carbon, which of the following is arrangedIin the correct order of electronegativity :
(A) sp >sp> sp (B) sp² >sp >sp (C) sp²> sp > sp (D)sp² > sp > sp
48.
The shapes of IF and IF, are
respectively :
(A)Distoted square pyramidal and
pentagonal bipyramidal
(B) octahedral and
pyramidal
(C) trigonal bipyramidal and square
antiprismatic
(D)distorted square planar and distorted octahedral
49.
Inwhich of the following pair. both species are isostructural but hybridization of central atoms are different:
(A) ICIz. XeF, (B) Bef,. CIF; (C) BrC. singlet CCi, (D) Xef;.TeFg
50,. Carbon atoms in C(CN)4 are :
(A) sp-hybridized (B) sp²-hybridized
(C) sp- and sp hybridized
(D) sp. sp? and sp'- hybridized
51. Molecular shapes of SF,. CF, and Xef, are:
(A)the same, with 2. 0 andl lone pair of electrons respectively
(B) the same, with 1, Iand I lone pair of electrons respcctively
(C) different with 0, 1and 2 lone pair of electrons respectively
(D)different with 1,0 and 2 lone pair of clectrons respectively
52. Inwhich of the following option, all bond lengths are not equal.
(A)BF, (B) NF; (C) XeF, (D)CIF3
53. How many bonded electron pairs are present in IF, molecule:
(A) 6 (B) 7 (C) 5 (D)8
54. Which molecule is Tshaped:
(A) BeF2 (B) BCl3 (C) NH3 (D) CIF3
55. phosphorus pentachloride dissociates in the vapour phase according to the equation
PCI, PCL, +Cr.The hybridisation of phosphorus in PCl, issp²d.
What is the hybridisation of Pin
PCI,
(A) sp°d (B)sp°d? (C) sp³ (D) dsp³
and one lone pair of
bond pairs of electrons
S6.
Which of the following molecule in itsvalenceshellhas three
electron
(D) CO,
(A)NH, (B) H,0 (C) BF
$7,
Which ofthe following fluorides of Xenon is impossible
(A) XeF, (C) XeF (D) XeF,
(B) XeF,
$S.
Among the following molecule
() XeO, (i) XeoF4 (ii) XeF,
Those having same number of lone pairs on Xe are
(A)() and () only (B)) and (iü) only (C) (i) and (ii) only (D) (). () and (m)
$9. Which of the following is planar
(A)XeF, (B)Xe0,F, () Xe0,F; (D) XeF,
RESONANCE |BOND ENERGY, BOND LENGTHAND BOND ORDER]
60.
Arrange the following in order of decreasing N-o bond length : NO|. NOZ, NO,
(A) NO^ > NO;>NO; (B) NO3 >NO; >NO; (C) NO; >NO, >NO, (D) NO; >NO,> NO;
61. In the series ethane. ethylene and acetylene, the c -H bond energy is:
(A) The same in all the three compounds (B) Greatest in ethane
(C) Greatest in ethylene (D) Greatest in acetylene
62. In the cyanide ion the negative charge is on
(A)C (B) N (C) Both Cand N (D)Resonate between Cand N
(A) SO> so> s0, >S0, (B) SO,> So,> s0, >So,
(C)SO,-> S0,> S0, >so, (D)S0,> S0> S0, >S0,
VSEPR-THEORY (COMPARISIONOF BOND ANGLE)
64. The correct order of increasing x-0-X bond angle is (X= H,F or C):
(A) H,0> Cl,0> F;0 (B) C7,0> H,0> F,0
(C) F0>C1,0> H,O (D) F,O> H,0>C,0
65. H-B-H bond angle in BH, is:
(A) 180° (B) 120° (C) 109° (D) 90°
8
66.
The bond
angle andIhybridization in ether (CH,0CH3) is:
(A) 106°51. sp (C) 110°, sp (D) None ofthese
67. (B) 104°31. sp
Match list I with list II and select the correct answer:
List I(species) List Il (0-N-O angle)
A.
NO, 180°
B.
NO, 2. 134°
C.
D.
NO 3 120
NO, 4. |15°
5 109°
A B A B D
D
(A) 4 3 2 (B) 5 2 4 3
1 4 3 2
(C) 2 4 (D)
68. The correct order of increasing bond angles in the following species is
(A) CIO; <CI,0< Cl0, (B)CI,0 <CI0,< CIO;
(D) CI,0 < CIO, <CIO,
(C)CIO, < CI,0<CIo;
angles CI-E-Cl for different Eare in the order
69. In compounds of type ECI,, where E = B, P. As or Bi. the
(B) B> P> As >Bi (C) B<P=As =Bi (D) B <P<As <Bi
(A) B> P= As = Bi
70. Bond angle is minimum for
(B) H,S (C)H,Se (D) H,Te
(A)H,0
71. Which of thefollowing compounds has the smallest bond angle in its molecule ?
(B) PH, (C) NH, (D) SO,
(A) SO,
the given molecules?
72. Which has the smallest bond angle (X S-X) in
(B)OSCI, (C) OSF, (D) OSMe,
(A) OSBr,
in CF, POF, and SO,F, is
73. Correct order of FXF bond angle (X = central atom)
(B) POF, <CF, <S0,F,
(A) SO,F, < POF, < CF,
(D) POF, <S0,F, <CF,
(C)CF, <sO,F, < POF;
substances :
74.
Consider the following
(2) CI,0 (3) Br,0
() OF,
correct sequence of X-0- X bond angle is
The (D) 1>3>2
(B)1>2>3 (C) 2>1>3
(A)3>2>1
75.
DIPOLE MOMENTT(POLARAND NONPOLARSSPECIES)
The dipole
moments of the given molecules are suchthat-
(A) BF,>NE,> NH, (B) NE, > BE, >NH,
(C) NH,> NE, BE, (D) NH, >BE,> NE,
76.
Which the following has the highest dipole
of
(A) NH, moment
(B) PH, (C) SblH, (D) AstH,
77.
Which has maximum dipole
moment?
CI CI
CI
.CT C Cl
(A)
(B) (C) (D)
CI CI
CI
78,
Which of the following has been arranged inorder of
decreasing dipole moment ?
(A) CH,CI> CH-F> CH,Br >CHl (B) CH,F >CH,Cl> CH,Br > CHl
(C) CH,Cl> CH,Br >CHl >CH3F (D) CHF >CH,Cl> CHl >CH,Br
79. Which of the following has the least dipole moment
(A) NE, (B) CO, (C) so, (D) NH,
80. Which of the following pairs has zero dipole moment ?
(A)CH,CI, and BF, (B) SiF, and BF
(C) PCl, and ClIF (D) BF,and NF;
81. Among the following compounds the one that is polar and has the central atom with sp hybridisation is
(A) H,CO, (B) Sif4 (C) BF; (D) HCIO,
STRUCTURE OF OX0-ACIDS / OXIDES / PSEDOHALIDE IONS /INTERHALOGEN COM
POUNDS /OTHER POLYATOMIC SPECIES
(A) N
oxidation states +I toTDS
(B) P (C) As (D)Sb
88. The molecular formula of
dithionic acid is
(A) H,S,0, (B) H,S,0, (D) H,S,0,
89. (C)H,S,0,
Sulphur in +3 oxidation state is present in
(A)Sulphurous acid (B) Pyrosulphuric acid(C) Dithionous acid (D) Thiosulfuric acid
90. There is no S-S bond in:
(A) S,0 (B) S,0, (C) S,0, (D) S,0,
91. Which of the following molecule does not have open book structure.
(A) O,F, (B) H,0, (C) S,Cl, (D) H,C,
92. The compound which does not possess a peroxide linkage is
(A) Na,O, (B) CrO, (C) H,SO, (D) PbO,
93. The number of P- 0-Pbonds in the structure of phosphorous pentoxide and phosphorous trioxide are
respectively
(A)6, 6 (B) 5, 5 (C) 5, 6 (D) 6, 5
94. Number ofP - Obonds in P,0,,is
(A)17 (B) 16 (C) 15 (D) 6
95. Which of the following contains P-0-P bond
(A)Hypophosphorous acid (B) Phosphorus acid
(C) Pyrophosphoric acid (D) Orthophosphoric acid
MOLECULAR FORCES AND IT'SAPPLICATION (H-BOND AND VANDER WAAL'S FORCES)
96. Pure phosphoric acid is very viscous. Because
(A) It is a strong acid
(B) It is tribasic acid
(C) It is hygroscopic
(D) It has PO,groups which are bonded by many hydrogen bonds
11
97,
Match List I1(Molecules) with List I(Boiling points) and select the correct answer.
List I List II
(A)
(B) NH, () 290 K
12
106.
Two ice cubes are
together: pressed over each other and
unite to ofom one cube. Which force is responsible for holdingthem
(A) Van der
(C) Waal's forces
The Hydrogen
(B) Covalent attraction
107. bond formation
pair of (D) Dipole-dipole attraction
molecules forming strongest hydrogen
(A)SiH, and SiF bonds al
(B) CH,--CH,and CHCI,
H (B) H
-CI
H
H
119.
lodine molecules are held in the solid lattice by
(A) london forces (B) dipole-dipole interactions
(C)covalent bonds (D)coulombic force
Other Miscellaneous Structure
120. Inorganic graphite is
(A)B,N,H, (B) (BN) (C) Sic (D) Fe(CO0),
121. White phosphorus (P,) does't contain
(A) Six P - P single bonds (B) FourP - P single bonds
ANSWERKEY
D 2 D 3 D 4. A 5. C 6. C 7. D
8 9. B 10. D |1. D 12. B 13. A 14.
15. A 16. 17. B 18. 19. A 20. C 21. B
22. B 23. B 24. C 25. D 26. A 27. A 28. A
29. 30. A 31. 32. 33. D 34. C 35. D
36. C 37. 38. B 39. C 40. C 41. A 42. C
43. D 44. A 45. A 46. B 47. A 48. A 49.
50. 51. D 52. D 53. B 54. D 55. 56. A
57. C 58. D 59. D 60. B 61. D 62. A 63.
64. B 65. 66. 67. 68. A 69. B 70. D
71. B 72. 73. A 74. A 75. C 76. A 77. A
78. A 79. B 80. B 81. A 82 A 83. B 84. D
85. C 86. A 87. A 88. 89. 90. D 91. D
92. D 93. A 94. B 95. C 96. D 97. B 98.
99. 100. 101. D 102. B 103. B 104. 105. D
106. C 107. C 108. A 109. A 110. B 1|. 112. A
113. C |14. D |15. A 116. A 117, D 118. C 119. A
120. B 121. B
14