23.09.24 Sankalp25-E, I Paper
23.09.24 Sankalp25-E, I Paper
23.09.24 Sankalp25-E, I Paper
0 SET – A
PHASE-8 (JEEA-18)
Time : 3 hours SANKALP25-e,i Maximum Marks: 240
INSTRUCTIONS
A. Questions paper format :
i) This question paper consists of 3 sections (Section 1 – Physics, Section 2 – Chemistry &
Section 3 - Maths) Each Section has 2 parts: PART – A, PART – C
ii) PART – A contains 10 multiple choice questions. Each question has 4 choices a, b, c and d, out of
which one or more than one choice is correct answer.
iii) PART – C contains 10 questions. The answer to each of the questions is a single digit integer, ranging
from 0 to 9. (The answer will have to be appropriately bubbled in the ORS).
B. Marking scheme :
i) For each question in PART- A, you will be awarded 4 Marks if you darken all but only the bubble(s)
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus
one (-1) mark will be awarded.
ii) For each question in PART- C, you will be awarded 4 marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. There is no negative
mark for incorrect answer(s) for this section.
IMPORTANT DATA
-31 -19
Mass of an electron (m) = 9.1 x 10 kg Charge of an electron (e) = 1.6 x 10 coulombs
23 -34
Avogadro’s Number (Na) = 6.023 x 10 Planck’s constant (h) = 6.626 x 10 Js
1 Faraday = 96500 Coulomb 1 Calorie = 4.2 joule
Atomic Masses: Cr = 52, Mn = 55, Fe = 56, Co = 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Kr = 83.8, Ag = 108, Sn=118.6,I = 127,Xe = 131, Ba = 137,Au= 197, Pb = 207, U=238
Enrollment No. :
Batch : _______________________________________________________________________________
Name : _______________________________________________________________________________
JEEA-18 SANKALP-e,i Ph-8 SET - A Date 23-09-24
SECTION – 1
Physics
PART - A
ONE OR MORE THAN ONE ANSWER CORRECT:
1. A uniform magnetic field of 30 mT exists in the positive X direction. A particle of
charge e and mass 1.67 1027 kg is projected through the field in the positive Y
direction with a speed of 4.8 106 m/s , then ( e 1.6 109 C )
a) force on the charged particle is 230.4 10 16 along negative Z direction
b) If the particle were negatively charged then the force on the particle is 230.4 106
along positive Z direction
c) path followed by the particle in both the cases of a positive charge and negative
charge is a circle
d) path followed by the particle in both the cases of a positive charge and negative
charge is helical
2. A proton and a deutron both having the same kinetic energy, enter perpendicularly into
a uniform magnetic field B. For motion of proton and deutron on circular path of radius
Rp and Rd respectively, the correct statement is
a) Rd 2 Rp b) Rd Rp / 2 c) Rd R p d) Rd 2 R p
3. A charged particle of mass m and charge q enters in a region of uniform magnetic field
B normally with a speed V. If it comes out of the magnetic field region after deflecting
through 30o , then
mv
a) width of the magnetic field region is
qB
mv
b) distance traveled by the particle in magnetic field is
6 qB
m
c) time spend by the particle inside the magnetic field is
3 qB
d) acceleration of the particle is zero as speed of the particle remains constant
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6. Two cells of e.m.f. E1 and E2 ( E2 E1 ) are connected in series in the secondary circuit
of a potentiometer experiment for determination of e.m.f. The balancing length is found
to be 825 cm. Now when the terminals of cell E1 are reversed, then the balancing
length is found to be 225 cm. The ratio of E1 and E2 is
a) 2 : 3 b) 4 : 7 c) 7 : 4 d) none of these
7. The maximum power drawn out of the cell from a source of e.m.f. E is given by (where
r is internal resistance)
E2 E2 E2 E2
a) b) c) d)
2r 4r r 3r
8. Proton, deuteron and alpha particles of same kinetic energy are moving in circular
trajectories in a constant magnetic field. The radii of proton, deuteron and alpha particle
are respectively rp , rd and r . Which one of the following relation is correct?
a) r rp rd b) r rp rd c) r rd rp d) r rd rp
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a) 32 b) 47 c) 68 d) 147
10. In a meter bridge experiment, the null point is obtained at 20 cm from one end of the
wire when resistance X is balanced against another resistance Y. If X < Y, then where
will be the new position of the null point from the same end, if one decides to balance a
resistance of 4X against Y?
a) 50 cm b) 80 cm c) 40 cm d) 70 cm
PART - C
INTEGER ANSWER TYPE:
2. Two ions having same mass have charges in the ratio 1 : 2. They are projected normally
in a uniform magnetic field with their speeds in the ratio 2 : 3. The ratio of their radii of
circular trajectories is x : 3 , the value of x is
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3. A beam of protons with speed 4 105 m/s enters a uniform magnetic field of 0.3 T at
an angle of 60o to the magnetic field. The pitch of the resulting helical path of protons
is close to _____ cm (mass of the proton 1.67 1027 kg , charge of proton
1.69 1019 c )
5. In a potentio meter experiment the balancing with a cell is at length 240 cm. On
shunting the cell with resistance of 2 the balancing length becomes 120 cm. The
internal resistance of the cell is
3
8. In the circuit shown in figure, a meter bridge is in its X C
balance state. The meter bridge wire has a resistance of
1 cm 1 . Calculate the value of the unknown resistance G
6V
E K
10. A proton and an particle (with their masses in the ratio of 1 : 4 and charges in the
ratio of 1 : 2) are accelerated from rest through a potential difference V. If a uniform
magnetic field B is set up perpendicular to their velocities, the ratio of the radii r : r of
the circular paths described by them is 1: x . The value of x is
SECTION – 2
Chemistry
PART - A
ONE OR MORE THAN ONE ANSWER CORRECT:
1. Which of the following statement(s) is (are) correct?
a) The coordination number of each type of ions in CsCl crystal is 8.
b) A metal that crystallizes in BCC structure has a coordination number of 12.
c) A unit cell of an ionic crystal shares some of its ions with other unit cells.
d) The length of the unit cell in NaCl is 552 pm. rNa + = 95 pm, rCl = 181 pm .
2. Which of the following statement(s) is/ are correct with respect to zinc blende
structure?
a) Zn 2+ ions are present at the corners and at the centres of each face.
b) Only alternate tetrahedral holes are occupied by Zn 2+ ions.
c) The coordination number of Zn 2+ and S2 is 4 each.
d) The number of ZnS units in a unit cell is 4.
6. Which one of the following chemical reactions depicts the oxidising behaviour
of H 2SO 4?
a) 2HI + H 2SO 4
I 2 + SO 2 + 2H 2O
b) Ca OH 2 + H 2SO 4
CaSO 4 + 2H 2O
c) NaCl + H 2SO 4
NaHSO 4 + HCl
d) 2PCl5 + H 2SO 4
2POCl3 + 2HCl + SO 2Cl 2
7. Which of the following statements are true about sodium thisoulphate, Na 2S2 O3?
a) It contains ionic, covalent and coordinate covalent bonds.
b) It is used to remove the unexposed AgBr from photographic films.
c) It can give a black precipitate with AgNO3 .
d) It is used in the estimation of iodine.
8. With respect to hypochlorite, chlorate and perchlorate ions, choose the correct
statement(s).
a) The hypochlorite ion is the strongest conjugate base.
b) The molecular shape of only chlorate ion is influenced by the lone pair of electrons
of Cl.
c) The hypochlorite and chlorate ions disproportionate to give rise to identical set of
ions.
d) The hypochlorite ion oxidizes the sulphite ion.
9. Select the correct statement(s) regarding the fluorides of xenon.
a) All three fluorides are volatile, readily subliming at room temperature(298 K).
b) XeF4 and XeF6 can act as fluoride ion acceptors as well as fluoride ion donors.
c) All three fluorides are powerful oxidizing agents.
d) All three fluorides are decomposed by water, XeF2 slowly and, XeF4 and XeF6
rapidly.
10. Select the correct statements about the contact process for the manufacture of H 2SO 4
a) Low temperature for the conversion of SO 2 to SO3 is required, as the reaction is
exothermic (720 K)
b) High pressure (2 atm) is required for the conversion of SO 2 and SO3 which
decreases in volume.
c) In contact process, SO3 is not absorbed directly in H 2 O to form H 2SO 4 because the
reaction is highly exothermic, acid mist is formed. Hence the reaction becomes difficult
to handle.
d) A catalyst (Pt or V2 O5 ) is required to increase the yield of the reaction.
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PART - C
INTEGER ANSWER TYPE:
1. Under ambient conditions, the total number of gases released products in the final step
of the reaction scheme shown below is
Complete Hydrolysis
XeF6 P + Other product
OH / H 2O
slow disproportionation in OH / H 2O
Products
2. Ozone with ClO 2 produces an oxide of chlorine. The average oxidation state of chlorine
in this oxide is_______
4. By passing a certain amount of charge through NaCl solution, 9.08 L of chlorine gas
were liberated at STP. When the same amount of charge is passed through a nitrate
solution of metal M, 52.8 g of the metal was deposited. If the specific heat of metal is
0.032 Cal/ 0 C-g , the valency of metal is
5. By passing a certain amount of charge through NaCl solution, 9.08 L of chlorine gas
were liberated at STP. When the same amount of charge is passed through a nitrate
solution of metal M, 52.8 g of the metal was deposited. If the specific heat of metal is
0.032 Cal/°C-g, the valency of metal is
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6. Ferrous oxide (FeO) crystal has a cubic structure and each edge of the unit cell is
0
5.0 A. Taking density of the oxide as 4.0 g cm 3 . The number of Fe 2+ and O 2 ions
present in each unit cell is
0
7. A metallic element has a cubic lattice each edge of the unit cell is 2.88 A. The density
of the metals is 7.20 g cm 3 . Then number of unit cells will be present in 100g of the
metal is x 1023. Find the value of x . (Round off to nearest integer)
8. The same quantity of electricity that liberated 2.158 g Ag was passed through a gold
salt, and 1.314 g gold was deposited. The equivalent mass of Ag is 107.9. Calculate
oxidation state of Au in the salt. (At. mass of Au = 197)
10. An aqueous solution of Na 2SO 4 was electrolysed for 10min. 82 ml of a gas was
produced at anode and collected over water at 27 0 C at a total pressure of 580 torr.
Determine the current that was used in amp. Given: Vapour pressure of H 2 O at 27 0 C
= 10 torr, R = 0.082 atm L/mol-K (Round off to nearest integer)
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SECTION – 3
Mathematics
PART - A
ONE OR MORE THAN ONE ANSWER CORRECT:
2
z
1 i 2
1. If a 0 and , has magnitude , then z is equal to
a i 5
1 3i 3 i 1 3i 1 3i
a) b) c) d)
5 5 5 5 5 5 5 5
ln x 1 x 2 dx equals:
2. The value of x 1 x2
x 2 x
a) 1 x 2 ln x 1 x 2 x C b)
2
ln x 1 x 2
1 x2
C
x 2 x
c)
2
ln x 1 x 2
1 x2
C
d) 1 x 2 ln x 1 x 2 x C
1
3. Let x sin x sec
3
x dx
2
x f x g x k , then:
a) f x 1, 1 b) g x sin x has 6 solution for x , 2
c) g ' x f x , x R d) f x g x has no solution
ex e x
4. Let I dx , J e 4 x e 2 x 1 dx . Then, for an arbitrary constant C , the
e4 x e2 x 1
value of J I equals
1 e 4 x e 2 x 1 1 e2 x e x 1
a) log 4 x 2 x C b) log 2 x x C
2 e e 1 2 e e 1
1 e2 x e x 1 1 e4 x e2 x 1
c) log 2 x x C d) log 4 x 2 x C
2 e e 1 2 e e 1
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x 7 / 6
x5 / 6 z3 z p z q
dx ln z 1 k ,
5. If x 1/ 2 1/ 3
1/ 3
x x 1
2
x1/ 2 x 2 x 1 3 2 r
1/ 6
1
where z x 1 , then
x
a) 6 b) 1 c) p q 3 d) q r 1
1 x2 m
6. If x4
dx A x 1 x2 c , for a suitable chosen integer m and a function
m
A x , where c is a constant of integration, then A x
1 1 1 1
a) b) c) d)
27x 9 3x 3 27x 6 9x 4
1 1
8. If a 2 2 2 2
dx tan 1 3 tan x constant , then
sin x b cos x 12
a
a) 3 b) ab 12
b
a 4
c) d) the maximum value of a sin x b cos x is 40
b 3
2021 2021 1
9. Let f x x i dx and f 0 0 then
i 1 i 1 x i
a) number of zeros at the end of f 2022 is 503
b) f 2022 f 2023 f 1
2022
c) f i 2021!
i 1
dx 2
10. Let f x , x . If f 0 0 and
3 4x 2
4 3x 2
3
1
f 1 tan 1 , , 0 , then
2 2
a) 28 b) 2 8 c) 2 2 21 d) 2 5
PART - C
INTEGER ANSWER TYPE:
3
1 x iy
1. Let 2 i
3 27
i 1 , where x and y are real numbers, then y x 85
3x 2 2 x
3. If x 6 2 x5 x 4 2 x3 2 x 2 5 dx I x , then the value of I 1 I 0 , where .
represents GIF.
3 2
4. If e x x 1
3x 4
2 x3 2 x dx h x c , then h 1 h 1
5. In ABC , line joining the circumcentre and orthocenter is parallel to side AC, then the
value of tan A tan C is
2 2 y x2
6. If y x y 2 x 0 , x, y 0 and x 2 y y 2 x dx f y C , where C
1
is an arbitrary constant then the value of at x 1 is
5 f ' y
x
6 x 2 sin 2 3/ 2
2 x sin x
7. If f x 3x dx and f 2 16 3 , then the
x sin x x
f
value of is ([.] is GINT)
31
8. If f x
x 2
sin 2 x
sec2 x dx and f 0 0 then f 1
tan k then k
2
1 x 4
10. Let z x iy be a complex number where x and y are integers then the area of the
3 3 k
rectangle whose vertices are the roots of the equation z z z z 350 is k then
12
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