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FeSO4

The document details a systematic qualitative analysis of a crystalline salt, identifying its acidic and basic radicals. The analysis concludes that the acidic radical is sulfate (SO4) and the basic radical is iron (Fe). Various dry and wet tests were conducted to confirm the presence or absence of specific radicals.

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6 views3 pages

FeSO4

The document details a systematic qualitative analysis of a crystalline salt, identifying its acidic and basic radicals. The analysis concludes that the acidic radical is sulfate (SO4) and the basic radical is iron (Fe). Various dry and wet tests were conducted to confirm the presence or absence of specific radicals.

Uploaded by

ajaykumargoalagoala
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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AIM OF THE ANALYSIS

SYSTEMATIC QUALITATIVE ANALYSIS


AND
IDENTIFICATION OF ACIDIC AND BASIC RADICAL

Preliminary Investigation

1. Physical Appearance : Crystalline

2. Colour : Light Green

3. Solubility : Soluble in water

DRY TEST FOR ACIDIC RADICAL

Experiment Observation Inference


1. Small amount of the salt is  No characteristic observation 2- -2- 2-
 CO3 , S , NO2 , SO3 may
taken in a dry test tube to it dil be absent.
H2SO4 & is added and is
warmed.

2. Small amount of the salt is  No characteristic observation - - -


 Cl , Br , I may be absent.
taken in a dry test tube, to it conc
H2SO4 is added & heated
strongly.

3. Small amount of the salt is  No characteristic observation -


 NO3 may be absent.
taken in a dry test tube, to it few
pieces of Cu-turning is added. It is
than strongly heated with conc
H2SO4.

WET TEST FOR ACID RADICAL

Experiment Observation Inference


1. Small amount of salt solution is taken  No characteristic purple or deep 2-
 S is absent.
in a test tube. It is made alkaline with violet.
NaOH, to it freshly prepared sodium
nitropruside solution is added.
2. Small amount of salt solution is taken  No characteristic observation - -
 Cl , Br , I is absent.
-

in a test tube, to it dil HNO3 is added. To


this solution AgNO3 is added slowly.
3. Small amount of salt solution is taken  White precipitate is formed 2-
 SO4 confirmed.
in a test tube & is acidified with dil HCI. which remain insoluble in dil
To this BaCl2 solution is added. H2SO4.

Page | 1
4. Ring test for NO-2:  No characteristic brown ring. -
NO 2 is absent.
Small amount of salt solution is taken in
a test tube & is made acidify by
CH3COOH. To this freshly prepared
FeSO4 solution is added solution is added
along the side of the test tube.
5. Ring test for NO -3:  No characteristic brown ring. -
 NO3 is absent.
To the salt solution freshly prepared
FeSO4 solution is added. The test tube is
held under tap water to maintain cold
condition. To this solution conc H2SO4 is
added to the side of the test tube in the
inclined condition slowly.

DRY TEST FOR BASIC RADICAL

Experiment Observations Inference


1. Heating in a dry test tube:  Red to Black when hot and ● Fe
2+
may be present
A little salt is taken in a dry test brown when cold.
tube and is heated strongly in the
bunsen flame.

2. Flame Test:  No characteristic observation +


● Na , K ,Sr
+ 2+
may be absent.
The tip of the platinum wire is
moistened with conc HCI, a little
salt is taken in the tip and finally
ignited in the non-luminous flame.
3. Sodalime Test:  No characteristic observation 2+
● Hg , As
3+ +
, NH4 may be
A small amount of salt is mixed absent.
with two parts of soda lime
(NaOH + CaO) & the mixture is
heated strongly in a dry test tube.
4. Ammonium Radical Test:  No characteristic observation +
● NH4 may be absent.
The salt is boiled with NaOH
solution.

WET TEST FOR BASIC RADICAL


(Systematic Group Analysis)

Experiment Observation Inference

1. To the salt solution dil HCI is No Precipitate Group – I absent.


added & heated gently.

2. The above filtrate/solution is No Precipitate Group – II absent.


heated gently & through this solution
H2S gas is passed.
3. The above filtrate/solution is
heated strongly to remove H2S gas Precipitate obtained Group – III A present.
completely, to this NH4Cl & NH4OH
solution is added till it become
alkaline.

Page | 2
4. The above filtrate/solution is No Precipitate Group – III B absent.
slightly warmed & through this H2S
gas is passed.

5. The above filtrate/solution is No Precipitate Group – IV absent.


heated strongly to remove H2S & to
this NH4Cl, NH4OH & (NH4)2CO3
solution is added.

6. To this above filtrate/solution No Precipitate Group – V absent.


Disodium Hydrogen Phosphate is
added (Na2HPO4) & the inner wall of
the tube is scratched with glass rod.

ANALYSIS OF GROUP – III A PRECIPITATE

The Precipitate obtained in this group is treated with NaOH and H2O2. The mixture is boiled and filtered.

Residue Filtrate
The residue is divided into two parts. To the filtrate Solid NH4Cl is added and the mixture is
heated to boil.
The first part is dissolved in dil HCI and to it Potassium
Ferrocyanide solution is added. No precipitate
● Deep Blue colored precipitate obtained. 3+
Al absent
2+
● Fe confirmed

The second part is dissolved into dil HNO3 and to it


pinch of sodium Bismuthate is added and shacked
vigorously.
No violet colouration.
2+
Mn absent.

Conclusion Of The Analysis


The given salt contain
2-
Acidic Radical : SO4
2+
Basic Radical : Fe

Page | 3

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