1617 Level M Chemistry Brush-Up Make-Up Material PDF

Grade 11: Term 1 Final Booster Exam
Revision Sheet
1. A student carries out an experiment to test if at 25 the concentration of acid affects how fast it reacts
with a known mass of calcium. The student was given concentrated acid and water.
What pieces of apparatus does the student need to use?
The student needs the following apparatus:
1) a beaker:
as a container
2) a stop watch:
to measure how fast is the reaction
3) a thermometer:
to measure the temperature of the experiment
4) a measuring cylinder:
to measure to volume of the acid
2. Consider the following reaction, at 490C, (Keq = 45.9)
2HI(g)
H2(g)
+ I2(g)
At a certain instant in a reaction, the container is maintained at 490C, the following concentrations were
determined:
[HI] = 0.01 mole/dm3
[H2] = 0.005 mole/dm3
[I2] = 0.004 mole/dm3
a) Is the system at equilibrium? If not, which concentrations are increasing and which are decreasing?
b) If not, which concentrations are increasing and which are decreasing?
[HI]2
(0.01)2
Q=
=
= 5 system not at equilibrium since Q K
[H 2 ] [I 2 ] (0.005)(0.004)
Since Q < K, the reaction goes to the right, forming more HI thus reducing the concentration of H2
and I2.
3. Given: Fe+3(aq) + SCN(aq)
FeSCN+2(aq)
The reactants and products in the above reaction are at equilibrium. What would happen to the [SCN(aq)]
and [FeSCN+2(aq)] respectively if Fe+3(aq) is removed by adding phosphate ions?
Removing Fe3+ means decreasing the concentration of [Fe3+]. The system wants to increase the
[Fe3+]. To do so the equilibrium shifts to the left consuming the FeSCN2+ while producing Fe+3
and SCN-. Therefore, the [SCN-] increases and [FeSCN+2] decreases.
4. Calculate the [H+] and the [OH] in a solution of 1.60 g of NaOH dissolved in 20 cm3 of solution.
Find the number of moles of NaOH. Number of moles of NaOH =
Find the [NaOH].

Find the [OH-].
Find the [H+].
[NaOH] = = 2.0 M
[OH-] = 2.0 M
Kw = [H+] [OH-]
1 10 -14 = [H+] (2.0)
[H+] = 5.0 10-15 M
1
= 0.40 moles
5. A solution contains lead (II) and calcium ions. The anions could be nitrate or acetate.
6. What is [OH] in a solution whose pH is 8? Is the solution acidic or basic?
pH = - log [H+] = 8
[OH-] = 1.0 10-6 M
7.
[H+] = 1.0 10-8 M
[OH-] = 1.0 10-6 M basic
State what will be observed when the ions below are mixed with dilute sulfuric acid.
Ion
2+
Ba
Ca2+
Observable result with dilute sulfuric acid

White precipitate of BaSO4 is formed that does not dissolve in excess acid
White precipitate of CaSO4 is formed that does not dissolves in excess acid
8. Weather balloons are filled with helium, not hydrogen, because helium is unreactive while hydrogen
gas is highly flammable.
9. What fuels oxygen to produce energy?
What type of reaction releases energy?
Hydrogen and fossil fuels

An exothermic reaction
10. 50. What are the properties characteristic of a base?

1) It has a pH greater than 7
2) It reacts with an acid to form salt
3) It reacts with ammonium salts where ammonia is released
4) It turns universal indicator paper blue.
5) They turn phenolphthalein pink
6) They turn methyl orange yellow.
11. A certain liquid turns white anhydrous copper (II) sulfate blue and has a boiling point of 105.
What could this liquid be?
The liquid is any aqueous solution. It cannot be pure water as its boiling point is NOT 100.
12. Potassium is reacted with water. What tests and their results can be performed to identify the products?
The products of the reaction are hydrogen gas and potassium hydroxide solution.
The gas produced pops with a lit splint.
The solution produced, being a basic solution, turns red litmus paper blue.
13. Relate each air pollutant correctly with its source?
Air pollutant
Source
carbon monoxide
incomplete combustion of fuels
lead compounds
burning petrol in cars
sulfur dioxide
burning coal and other fossil fuels that contain sulfur
carbon dioxide
Complete combustion and respiration
nitrogen oxides
burning of fossil fuels
14. Some calcium iodide is dissolved in water. Aqueous silver nitrate is added to the solution till no more
precipitate forms. This precipitate, named W is filtered off. Dilute sulfuric acid is added to the filtrate
and another precipitate Z is formed. Identify precipitates W and Z and state their colors?
Precipitate W is silver iodide, AgI, that is yellow in color
Precipitate Z is calcium sulfate, CaSO4, that is white in color
15. The oxide of element Z was added to hydrochloric acid. A reaction occurred and salt and water are
formed. What type of element is Z? What was the pH of the solution initially?
The oxide reacted with the acid so it must be a basic oxide. This means Z is a metal. Most metal
oxides are basic, that react with acids producing salt and water. The pH of the solution initially
must be less than 7.
16. Name the pollutant found in car exhaust fumes that does not come from the fuel.
Oxides of nitrogen
17. Pink cobalt (II) chloride crystals + A blue cobalt (II) chloride crystals + B
Identify A to D. What does mean?
A is heat, B is steam or water
Pink cobalt (II) chloride is a hydrated salt, blue cobalt (II) chloride is an anhydrous salt.
means the reaction is reversible.
18. An aluminium rod is placed in a 1.0 M aluminium nitrate solution. A lead rod is placed in a 1.0 M lead
nitrate solution. The two half cells are connected internally by a salt bridge and externally by a voltmeter.
The voltmeter reads 1.53 V and it shows that lead is the positive terminal of the cell.
Answer the following questions
a) Direction of flow of current in the outside circuit
Pb to Al
b) Direction of flow of electrons in the outside circuit
Al to Pb
c) The anode is Al
d) Equation at anode is Al Al3+ + 3ee) Cathode is
Pb
f) Equation at cathode is Pb2+ + 2 e- Pb
g) How much energy is released by the cell when 5.00 C passes by any point in the circuit?
Energy = 1.53 5.00 = 7.65 J
18. A student carries out an experiment to investigate the rate of reaction between marble chips and
hydrochloric acid. The loss in mass of the reaction flask was measured.
The graph below shows the result of two experiments, X and Y.
19. Give a possible explanation for the difference in results.

Possible reasons why the rate in experiment Y was faster:
a. Hydrochloric acid is more concentrated in Y than in X
b. Temperature is higher in Y than in X
c. A catalyst is used in Y
d. Smaller marble chips or powdered carbonate is used in Y
20. A solution of halogen and potassium halide is mixed. Name mixtures that darken in color because a
reaction took place?
1) Chlorine and potassium iodide
2) Chlorine and potassium bromide
3) Bromine and potassium iodide
21. Give the colors of the following compounds
KMnO4
Purple
K2Cr2O7
orange
K2CrO4
yellow
CuSO4
Blue
CuCO3
Green
22. Z is a monatomic gas. What are the typical reactions of Z?
Being a monoatomic gas means Z is an inert gas. Z is unreactive.
23. What ion/s could be present in a solution if samples of it give a precipitate with Cl-(aq) but not with
SO42- (aq)?
Ag+ and Cu+. Both form AgCl and CuCl that are insoluble while Ag2SO4 and CuSO4 are soluble
24. Identify the gases that can be collected over water.
Gases that can be collected over water are the ones that are insoluble in water. Examples,
oxygen, O2 , hydrogen, H2 , and Nnitrogen, N2
25. List some common drying agent?
1) Anhydrous calcium chloride, CaCl2
2) Concentrated sulfuric acid, H2SO4
3) Calcium oxide, CaO
4
4) Silica gel
26. List some of the uses of hydrogen
1. In synthesis of ammonia
2. In synthesis of hydrochloric acid
3. In the hardening of unsaturated oils to make margarine.
4. In filling balloons
5. Producing fuel cells
27. What can be used to test if a solution is acidic?
1. Mg metal
2. Zinc metal
3. litmus paper
4. pH-meter
5. carbonate ion
6. phenolphthalein
7. Universal indicator
28. A hydrocarbon is 75 percent carbon by weight. Find its empirical (simplest) formula.
C
H
25
75
divide by atomic mass
1
12
6.25
25
divide by smallest number
6.25
6.25
1
4
The simplest formula of the hydrocarbon is: CH4
29. A salt is made by adding an excess of an insoluble metal carbonate to an acid. How is the excess metal
carbonate going to be removed? by filtration
30. A solution is prepared by mixing 50cm3 of 0.50M HCl solution with 150 cm3 of 0.10M NaOH solution.
Find the [H+] and [OH] left in the solution
nacid = (0.50)(50 10-3) = 2.5 10-2 mole
nbase = (0.10)(150 10-3) = 1.5 10-2 mole
Find number of moles of H+ and OH-:
+ = (0.50)(50 10-3) = 2.5 10-2 mole
= (0.10)(150 10-3) = 1.5 10-2 mole
Find which one is in excess:
H+ in excess, + left in excess = 2.5 10-2 - 1.5 10-2 = 0.010
mole
.
Find [ ] of one in excess:
[H+] = . = 0.050 M
Find number of moles of acid and base:
Find [ ] of other: Kw = [H+][OH-]
[OH-] = [+ ] =
= 2.0 10-13 M

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Grade 11: Term 1 Final Booster Exam

Find the number of moles of NaOH. Number of moles of NaOH =

Find the [NaOH].

[H+] = 1.0 10-8 M

[OH-] = 1.0 10-6 M basic

Observable result with dilute sulfuric acid

Hydrogen and fossil fuels

10. 50. What are the properties characteristic of a base?

19. Give a possible explanation for the difference in results.

Find [ ] of other: Kw = [H+][OH-]

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