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Sulphur and Its Compounds A

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30 views

Sulphur and Its Compounds A

Uploaded by

timothykiprono913
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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SULPHUR AND ITS COMPOUNDS

MARKING SCHEME

1. Barium carbonate reacts with dilute sulphuric (VI) acid to form the insoluble Barium
sulphate (BaSO4) which covers the reactant Barium carbonate preventing any contact
between the acid and the carbonate salt.  1
Hence, the reaction is slow and stops after a very short time.
BaCO3(s) + H2SO4(aq) BaSO4(s) + CO2(g) + H2O)(l)
Insoluble

2. The dye is oxidized to a new product with chlorine (1mk) but oxygen is removed to form an
unstable product which gradually gets re-oxidized by atmospheric oxygen on exposure for
sometime to air (1mk) in the case of Sulphur (IV) oxide.

3. (a) Dehydrating agent (1mk)


(b) Oxidizing agent (1mk)

4. 1 – Compressed hot air, in


2 – Molten froth of Sulphur water mixture, out
3 – Superheated water – in

5. a) i) Dehydration (½)
ii) Oxidation (½)
b) Cu(s) + 2H2SO4(l) CuSo4(aq) + SO2(g) + 2H2O(l) (1)

6. (a) Mass of acid = 75


1.84  1000 = 1380g in 1000cm
3

100
Morality =1380 = 14 .08m  ½
98

(b)Moles of dilute acid = 0.25 x 1 = 0.25x 1 ½ = 0.25 moles.


½ ½
0.25
Volume =  1000 ½ = 17. 756cm3 ½
14.08
Penalize ½ for wrong units
1
PEAK SUCCESS EDUCATION
7. It reacts with ammonia  ½ gas to form ammonium sulphate. ½
(b) Quick time / Ca O
8. (a) To avoid poisoning the catalyst  1

(b) SO3 ( g )  H 2 SO4 (l ) H 2S 2O7 (l ) 1


(c) Vanadium (v) Oxide V2 O5 1

9. a) 3H2S(g) + H2SO4(l) 4H2O(l) + 4S(s) 

b) H2S  ½reducing agent ; Sulphur in H2S oxidized from


-2 to 0 (zero
c) Pb(C2H3O2 )2(aq) + H2S(g) PbS(s) + 2C2H4O2(aq)

9. a) Hydrogen chloride1
Sulphur (IV) oxide1
b)

25. a) Frasch process1


b) Hot compressed air1
c) Monoclinic / prismatic sulphur / beta sulphur½
Rhombic / octahedral sulphur / alpha sulphur½

2
PEAK SUCCESS EDUCATION

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