Lembar Perhitungan: N GR MR × V ×valensi GR × ×1

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 16

LEMBAR PERHITUNGAN

A. PERHITUNGAN REAGEN
Larutan NaOH 0,75 N sebanyak 15 Liter
gr 1000
N=

Valensi
Mr
V
0,75=

gr 1000

1
40 15000

gr=459,18 gramNaOH

Larutan HCl 0,5 N


VHCl=

0,5 36,5 100 ml


1,15 0,25 1000

VHCl=6,35 ml

B. PERHITUNGAN FRAKSI RUANG KOSONG


Vvoid=116,4 cm3
D=3,3 cm ; H=30,3 cm
Vt=

D2 H
4

(3,14 3,32 30,3) 4


259,02 cm3

Vvoid
Vt

116,4 cm 3
259,02 cm 3

0,449

C. OPERASI ABSORBSI
Variabel Tetap
Z1= 0,7 cm= 0,007m
Z2= 0,9 cm= 0,009 m
Z3= 1 cm= 0,01 m
P CO2= 5,5 bar
N NaOH = 0,75 N dalam 15 Liter
Variabel Berubah
Q1= 3ml/detik= 0,18L/menit
Q2= 6 ml/detik=0,36 L/menit
Q3= 9 ml/detik= 0,54 L/menit
D. PERHITUNGAN LAJU ALIR
1

Perhitungan Laju Alir


raksa = 13595 kg/m3
CO2 = 1,977 kg/m3 (273,15 K, 1 atm)
udara = 1,293 kg/m3 (273,15 K, 1 atm)
Z1= 0,7 cm= 0,007m
Z2= 0,9 cm= 0,009 m
Z3= 1 cm= 0,01 m
Din = 2,1 cm = 0,021 m
Dout = 1,5 cm = 0,015 m
Sin =

1
4

x x D1 =

Sout =

1
4

x x D2 2 =

1
4

x 3,14 x 0,0212 = 3,461.10-4 m2


1
4

x 3,14 x 0,0152 = 1,766.10-4 m2

a. Laju Alir CO2


- Variabel 1 (Q= 3 ml/detik (0,18 L/menit)
-P = Z ( raksa CO2) x

-P = 0,007 (13,534 1,977) x


-P= 0,793

g
gc
9.8
1

V CO2 =

P
F)
CO 2
s1
( 1)
s2

2 a x gc x (

0,793
)0
1,9777

0,0003641
(
1)
0,0001766

2x 1x 1x(
V CO2 =

V CO2 = 0,87 m/s


Laju alir CO2 = V CO2 x S2
= 0,87 m/s x 1,766. 10-4 m2 =1,536.10-4 L/s

- Variabel 2 (Q= 6 ml/detik (0,36L/menit)


-P = Z ( raksa CO2) x

-P = 0,009 (13,534 1,977) x

g
gc
9.8
1

-P= 1,019

V CO2 =

P
F)
CO 2
s1
( 1)
s2

2 a x gc x (

1,019
)0
1,9777

0,0003641
(
1)
0,0001766

2x 1x 1x(
V CO2 =

V CO2 = 0,985 m/s


Laju alir CO2 = V CO2 x S2
= 0,985 m/s x 1,766. 10-4 m2 =1,739.10-4 L/s

-Variabel 3 ( Q= 9 ml/detik (0,54 L/menit)


-P = Z ( raksa CO2) x

g
gc

-P = 0,01 (13,534 1,977) x

9.8
1

-P= 1,132

V CO2 =

P
F)
CO 2
s1
( 1)
s2

2 a x gc x (

1,132
)0
1,9777

0,0003641
(
1)
0,0001766

2x 1x 1x(
V CO2 =

V CO2 = 1,038 m/s


Laju alir CO2 = V CO2 x S2
= 1,038 m/s x 1,766. 10-4 m2 =1,833.10-4 m3/s
a. Laju Alir Udara
-Variabel 1
g
-P = zudara . ( raksa udara). gc
= 0,007 m x (13595 1,2)kg/m3 x 9,8 m/s2
= 932,534 kg/m.s2

(Q) raksa+udara

P
F )
( udara
sin
( Sout
)1

2 . gc .

932,534
)0
1.2
0,0003641
0,0001766
()1

2.1.1 .(

= 38,26 m/s
Laju alir (Q) udara = (Q raksa + Qudara) x S2
= 38,26 m/s x 1,766. 10-4 m2
= 0,00676 m3/s
-Variabel 2
g
-P = zudara . ( raksa udara). gc
= 0,009 m x (13595 1,2)kg/m3 x 9,8 m/s2
= 1198,97 kg/m.s2

(Q) raksa+udara

P
F )
( udara
sin
( Sout
)1

2 . gc .

1198,97
)0
1.2
0,0003641
0,0001766
()1

2.1.1 .(

= 43,38 m/s
Laju alir (Q) udara = (Q raksa + Qudara) x S2
= 43,38 m/s x 1,766. 10-4 m2
= 0,00766 m3/s
-Variabel 3

-P = zudara . ( raksa udara).

g
gc

= 0,01 m x (13595 1,2)kg/m3 x 9,8 m/s2


= 1332,1924 kg/m.s2

(Q) raksa+udara

P
F )
( udara
sin
( Sout
)1

2 . gc .

1332,1924
)0
1.2
0,0003641
0,0001766
()1

2.1.1 .(

= 45,58 m/s
Laju alir (Q) udara = (Q raksa + Qudara) x S2
= 45,58 m/s x 1,766. 10-4 m2
= 0,008049 m3/s

2 Penentuan Kadar CO2 mula-mula


Udara Q2
C2
CO2
Q1
C1

Q3 = Q1 + Q2

C1 = P V = n R T =

n
V

P
RT

83,14 cm 3 . K .303,15 K
mol

5,5

2,183.10-4 mol/cm3= 218.2203 mol/m3


Q2 Variabel 1 = 0,00676 m3/s
Q2 Variabel 2= 0,00766 m3/s
Q2 Variabel 3= 0,008049 m3/s
C2 =

8.591 x 103

mol
m3

-Variabel 1
y 3=

Q1 y 1 +Q2 y 2
Q3

Q3=Q1 +Q2
Q3=1,536 x 10

m
m
m
+ 6,67 x 103 =6,8236 x 103
s
s
s

3
3
m3
mol
mol
4 m
3 m
y 3 x 6,8236 x 10
=1,536 x 10
x 218.2203 3 +6,67 x 10
x 8.591 x 103 3
s
s
s
m
m
3

mol
s
mol
y 3=
=5,2396 3
3
m
m
6,8236 x 103
s
2

3,3575 x 10

-Variabel 2
Q y +Q y
y 3= 1 1 2 2
Q3
Q3=Q1 +Q2
Q3=1,739 x 104

m3
m3
m3
+7,66 x 103 =7,8339 x 103
s
s
s

y 3 x 7,8339 x 103

m3
m3
mol
m3
mol
=1,739 x 104
x 218.2203 3 +7,66 x 103
x 8.591 x 103 3
s
s
s
m
m

mol
s
mol
y 3=
=4,852 3
3
m
m
7,8339 x 103
s
3,8014 x 102

Variabel 3
y 3=

Q1 y 1 +Q2 y 2
Q3

Q3=Q1 +Q2
Q3=1,833 x 104

m3
m3
m3
+8,049 x 103 =9,882 x 103
s
s
s

y 3 x 9,8820 x 103

m3
m3
mol
m3
mol
=1,833 x 104
x 218.2203 3 + 8,049 x 103
x 8.591 x 103 3
s
s
s
m
m

mol
s
mol
y 3=
=4,0538 3
3
m
m
9,8820 x 103
s
4,006 x 102

Perhitungan Absorpsi CO2


Saat a > b maka persamaan yang digunakan:
2. b x N HCL
N Na2 CO3 =
valensi Na2 CO 3 x V sampel
N NaH CO3 =
-

( ab ) x N HCL
valensi NaH CO 3 x V sampel

Laju alir NaOH 3 x 10-6 m3/s


t = 0 menit
a = 9,4 x 10-6 m3
b = 1,6 x 10-6 m3
6

2 x 1,6 x 10 m x 0.5
N Na2 CO3 =

2 x 10 m

mol
3
m

=0.16

mol
3
m

( 9,4 x 106 m31,6 x 106 m3 ) x 0.5 mol3


N NaH CO3 =

1 x 10 m

N CO 2 Terserap=N Na2 CO 3 + N NaH CO3

=0.39

mol
m3

N CO 2 Terserap=0.16

mol
mol
mol
+0.39 3 =0.55 3
3
m
m
m

n CO2 =N CO 2 x Q NaOH
n CO2 =0.55

t
0
1
2
3
4
5
6
7
8
9
10
4

3
mol
6 m
6 mol
x
3
x
10
=1,65 x 10
3
s
s
m

Tabel 1.Hasil percobaan dengan laju alir NaOH 3 x 10-6 m3/s


Na2CO NaHCO
A
b
3
3
N CO2 nCO2
0.000009 0.000001
0.0000014
4
6
0.08
0.39
0.47
1
0.000010
1 0.000001
0.05
0.455
0.505 1.515E-06
0.000010 0.000000
0.0000015
6
4
0.02
0.51
0.53
9
0.000011 0.000000
0.0000017
6
5
0.025
0.555
0.58
4
0.000010 0.000000
9
2
0.01
0.535
0.545 1.635E-06
0.000011 0.000000
1
1
0.005
0.55
0.555 1.665E-06
0.000010 0.000000
0.0000015
6
1
0.005
0.525
0.53
9
0.000010 0.000000
5
6
0.03
0.495
0.525 1.575E-06
0.000010 0.000000
5
5
0.025
0.5
0.525 1.575E-06
0.000011 0.000000
0.0000017
6
6
0.03
0.55
0.58
4
0.000011 0.000000
0.0000016
2
6
0.03
0.53
0.56
8
Perhitungan Harga KGA
RUMUS
mol CO 2 terserap
kGa=
A Z P
dimana :

1
1
A= x D2 x =3.14 x 3,32 x =8,55 c m2=8,55 104 m2
4
4

= tinggi packing = 0.303 m

= fraksi ruang kosong = 0.449

P=P gauge+1 atm

6,51325 6,51325 x 105 Pa

P=5,5 +1,01325
a. Variabel 1 dengan laju alir 3 x 10-6 m3/s
mol CO 2 terserap
kGa=
A Z P
KGa=

1.61045 x 106 mol /s


mol
8
=9,149 x 10
4 2
5
8,55 10 m x 0.303 m x 0.449 x 1,51325 x 10 Pa
Pa . m3 . s

b. Variabel 2 dengan laju alir 6 x 10-6 m3/s


mol CO 2 terserap
KGa=
AZP
6

KGa=

3,18 x 10 mol /s
mol
=1,8066 x 107
4 2
5
3
8,55 10 m x 0.303 m x 0.449 x 1,51325 x 10 Pa
Pa .m . s

c. Variabel 3 dengan laju alir 9 x 10-6 m3/s


mol CO 2 terserap
KGa=
AZP
KGa=

7.0731 x 106 mol /s


mol
7
=4,0183 x 10
4 2
5
3
8,55 10 m x 0.303 m x 0.449 x 1,51325 x 10 Pa
Pa . m . s

Perhitungan Harga KLA

a. Variabel 1 laju alir NaOH 3 x 10-6 m3/s


C O =15 106 kg / m s
2

CO2 = 1264 kg/m3


Q CO2 = 1,8331.10-4 m3/s
NaOH =3,95 x 103 kg/m s
NaOH = 2100 kg/m3
Q NaOH = 3ml/s = 3 x 10-6 m3/s
DA = 2,1 x 10-5 cm2/s = 2,1 x 10-9 m2/s
T = 30oC = 303.15 K
R = 8.314 Pa mol-1K-1
6 ( 1 ) 6 ( 10.449 ) 3,306
a=
=
=
dp
dp
dp

C O .QC O
k Ga . d p 2 . R .T
=4,0777
DA
C O . a

9,149 x 108

109804,95

1,4003

) (

C O
C O . D A
2

1
3

mol
Pa
kg
d p 2 x 303.15 K x 8.314
1264 3 x 1,536.104 m
3
mol
.
k
Pa. m . s
m
=4,0777
9 2
kg 3,306
2,110 m /s
15 106
x
m. s
dp

1
x d p2=4,0777 x 3915,1119 m. d p1.4003 x 3.8374
5
m

28,0464

1
d p0.5967 =15.6450
5
m
d p 0.5967 =0,5578 m5
dp=0,3759 m5
a=

3,306
1
=8,7948 5
5
0,3759 m
m

k L a .dp

.Q
=0,2258 NaOH NaOH
DA
NaOH .a

0.3

NaOH

NaOH . D A

) (

0.5

kg
6 3
x 3 x 10 m / s
3
k La x x 0,3759 m
m
=0,2258
9 2
1
3 kg
2,1 10 m / s
3,95 x 10
x 8,7948 5
m.s
m
5

2100

179000000 m3 / s x k La =4,049 m6
k La=2,2620 x 108 m3 / s
b. Variabel 2 laju alir 6 x 10-6 m3/s
6
C O =15 10 kg / m s
2

CO2 = 1264 kg/m3


4 3
Q CO2 = 1,739.10 m / s
3

NaOH =3,95 x 10 kg/m s


NaOH = 2100 kg/m3

0.3

)(

3,95 x 10

2100

0.5

kg
m.s

kg
9 m
x 2,1 10
3
s
m

Q NaOH = 6 ml/s = 6 x 10-6 m3/s


DA = 2,1 x 10-5 cm2/s = 2,1 x 10-9 m2/s
6 ( 1 ) 6 ( 10.449 ) 3,306
a=
=
=
dp
dp
dp
C O .QC O
k Ga . d p 2 . R .T
=4,0777
DA
C O . a

48,92

1,4003

C O

C O . D A

) (

1
3

mol
Pa
kg
d p 2 x 303.15 K x 8.314
1264 3 x 1,739.104 m3
3
mol . k
Pa. m . s
m
=4,0777
9 2
kg 3,306
2,1 10 m /s
15 106
x
m.s
dp

1,8066 x 107

216825,47

1
2
1.4003
x d p =4,0777 x 4432,5388 m. d p
x 3.8374
5
m

1
. d p0.5967 =15,6478
5
m

d p 0.5967 =0,31986 m5
dp=0,1480 m
a=

3,306
1
=22,3316 5
5
0,1480 m
m

k L a .dp

.Q
=0,2258 NaOH NaOH
DA
NaOH .a

0.3

NaOH

NaOH . D A

) (

0.5

kg
x 6 x 106 m3 / s
3
k La x 0,148 m
m
=0,2258
9 2
kg
1
2,1 10 m /s
3,95 x 103
x 22,3316 5
m. s
m
5

2100

199047619 m3 / s k La=3,7692 m6
k La=1,8936 x 108 m3 / s

c. Variabel 3 laju alir 9 x 10-6 m3/s

0.3

)(

3,95 x 103

2100

0.5

kg
m.s

kg
m
x 2,1109
3
s
m

C O =15 106 kg / m s
2

CO2 = 1264 kg/m3


4 3
Q CO2 = 1,833.10 m / s
NaOH =3,95 x 103 kg/m s
NaOH = 2100 kg/m3
Q NaOH = 6 ml/s = 9 x 10-6 m3/s
DA = 2,1 x 10-5 cm2/s = 2,1 x 10-9 m2/s
6 ( 1 ) 6 ( 10.446 ) 3,306
a=
=
=
dp
dp
dp
C O .QC O
k Ga . d p 2 . R .T
=4,0777
DA
C O . a

4,0183 x 107

4822,7405

103,22
dp

1,4003

) (

C O
C O . D A
2

1
3

mol
Pa
kg
d p2 x 303.15 K x 8.314
1264 3 x 1,833. 104 m
3
mol . k
Pa . m . s
m
=4,0777
9 2
kg 3,306
2,1 10 m / s
15 106
x
m. s
dp

1
x d p 2=4,0777 x 4672,1355 m. d p 1.4003 x 3.8374
5
m

1
d p 0.5967 =15.6478
5
m

0.5967

=0,1515 m

dp=0,0423 m5
a=

3,306
1
=78,1560 5
5
0,0423 m
m

k L a .dp

.Q
=0,2258 NaOH NaOH
DA
NaOH .a

0.3

NaOH

NaOH . D A

) (

0.5

kg
x 9 x 106 m3 /s
5
3
k La x 0,1515 m
m
=0,2258
9 2
kg
1
2,1 10 m /s
3,95 x 103
x 78,1560 5
m. s
m

2100

0.3

)(

kg
3,95 x 10
m.s

kg
m2
2100 3 x 2,1 109
s
m
3

0.5

72142857,14 m3 /s k La =0.7506 m6
8

k La 1,0404 x 10 m / s
6 Perhitungan Harga K2
Dengan :
mol
mol
H=2.88 x 105 3
=2.842 x 104 3
cm . atm
m . Pa
a. Variabel 1 laju alir 3 x 10-6 m3/s
Ra=QNaOH x n CO2 terserap
Ra=3 x 10
=

3
m3
6 mol
12 m mol
x 1,6104 x 10
=4,8312 x 10
s
s
s2

( a avgb avg ) x N HCL


valensi x V sampel
OH

( 10,73 x 1060,56 x 106 ) x 0.5 mol3


m

=
1 x 10 x 106
OH

mol
m3

OH

a x H x Da 0.5 x 0.5 x PCO 2


Ra

K 2=

Ra
KGa

=1,045

2,1 x 109

m2
s

0.5

0.5 x [ 1,045 ] x 5.5 x 105 Pa


m3 mol
4,8312 x 1012
3
s2
9 m
=2,7885
x
10
2
mol . s
1
mol
8,7949 5 x 2.842 x 104 3
x
m
m . Pa

K 2=
b. Variabel 2 laju alir 6 x 10-6 m3/s
Ra=QNaOH x n CO2 terserap
Ra=6 x 10
=

m
6 mol
12 m mol
x 3,18 x 10
=1,908 x 10
s
s
s2

( a avgb avg ) x N HCL


valensi x V sampel
OH

( 1,06 x 1051.1181 x 106 ) x 0.5 mol3


m

=
6

1 x 10 x 10

mol
m3

OH

OH

a x H x Da 0.5 x 0.5 x PCO 2


Ra

K 2=

Ra
KGa

=0.4741

2,1 x 109

m2
s

0.5

0.5 x [ 0.4741 ] x 5.5 x 105 Pa


m3 mol
1,908 x 1012
3
s2
10 m
=4.4616
x
10
2
mol . s
1
mol
22,3316 5 x 2.842 x 104 3
x
m
m . Pa

K 2=
c. Variabel 3 laju alir 9 x 10-6 m3/s
Ra=QNaOH x n CO2 terserap
Ra=9 x 10
=

m
6 mol
11 m mol
x 7,7031 x 10
=6,9328 x 10
s
s
s2

( a avgb a vg ) x N HCL
valensi x V sampel
OH

( 11.19 x 106 1,418 x 106 ) x 0.5 mol3


m

mol
1 x 10 x 10
m3
OH

=0.4886

OH

a x H x Da 0.5 x 0.5 x PCO 2

Ra
KGa

Ra

K 2=

m3 mol
6,932
2
s

2 0.5
0.5
1
4 mol
9 m
5
78,1560 5 x 2.842 x 10
x 2,1 x 10
x [ 0.4886 ] x 5.5 x 10 Pa 4,018
s
m
m3 . Pa
6,9328 x 1011

K 2=

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy