II PUC Chemistry Lab Syllabus
II PUC Chemistry Lab Syllabus
I) Analyse the given simple inorganic salt systematically and report one acidic radical and
one basic radical. (Any one salt Analysis from following)
SALT ANALYSIS - 1
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Zero group
EXPERIMENT OBSERVATION INFERENCE
Test for 𝐍𝐇𝟒+ Pungent smell of ammonia, Zero group may be Present
Salt + NaOH solution, heat gives dense white fumes with NH4+ .
a glass rod dipped in con. HCl. (Ammonium ion)
C.T for 𝐍𝐇𝟒+ Ammonium ion confirmed
O.S + Nessler’s reagent + Brown ppt NH4+ Confirmed
NaOH Solution in excess.
Part V: REPORT:
Acid radical Group: II
Cl–
(Anion)
Basic radical Group: 0
𝐍𝐇𝟒+
(Cation)
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
II - GROUP
EXPERIMENT OBSERVATION INFERENCE
Zero group
EXPERIMENT OBSERVATION INFERENCE
Test for 𝐍𝐇𝟒+ Pungent smell of ammonia, Zero group may be Present
Salt + NaOH solution, heat gives dense white fumes with NH4+ .
a glass rod dipped in con. HCl. (Ammonium ion)
C.T for 𝐍𝐇𝟒+
Brown ppt Ammonium ion confirmed
O.S + Nessler’s reagent +
NaOH Solution in excess. NH4+ confirmed
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Brisk effervescence with the I Group may be present
Salt + dil. HCl
colourless & odourless gas CO3−2 present
C. T for (𝐂𝐎−𝟐𝟑 ):
Effervescence of CO2 turns lime I Group confirmed
Salt + dil. HCl
water milky (CO−2
3 ) Confirmed
Zero group
EXPERIMENT OBSERVATION INFERENCE
II - GROUP
EXPERIMENT OBSERVATION INFERENCE
IV - GROUP
EXPERIMENT OBSERVATION INFERENCE
V - GROUP
EXPERIMENT OBSERVATION INFERENCE
Part V:
REPORT:
Acid radical
𝐂𝐎−𝟐
𝟑 Group: II
(Anion)
Basic radical
Ca+2 Group: V
(Cation)
Given Salt is : Calcium carbonate (CaCO3
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Salt + dil. HCl No Brisk effervescence I Group absent
II-GROUP
III - GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for 𝐒𝐎−𝟐𝟒 Thick white ppt III Group may be present
Salt solution + BaCl2 solution
SO−2
4 present
Test for 𝐍𝐇𝟒+ : No pungent smell of Ammonia gas Zero Group absent
Salt + NaOH solution heat
II - GROUP
EXPERIMENT OBSERVATION INFERENCE
III - GROUP
EXPERIMENT OBSERVATION INFERENCE
O.S + NH4Cl + NH4OH in Gelatinous white ppt III Group may be present
excess
Al+3 may be present
C.T for Al+3 White ppt soluble in excess to give III Group confirmed
O.S + NaOH drop by drop clear solution Al+3 confirmed
Part V: REPORT:
Acid radical
𝐒𝐎−𝟐
𝟒 Group: III
(Anion)
Basic radical
Al+3 Group: III
(Cation)
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Brisk effervescence with the I Group may be present
Salt + dil. HCl
of colourless & odorless gas
CO3−2 Present
Salt + NaOH solution heat No pungent smell of Ammonia gas Zero Group absent
II-GROUP
2) O.S + dil HCl pass H2S gas No gas evolved II Group absent
IV - GROUP
EXPERIMENT OBSERVATION INFERENCE
V - GROUP
EXPERIMENT OBSERVATION INFERENCE
VI - GROUP
EXPERIMENT OBSERVATION INFERENCE
REPORT:
Acid radical
CO3−2 Group: I
(Anion)
Basic radical
Mg+2 Group: VI
(Cation)
I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
No Brisk effervescence I Group absent
Salt + dil.HCl
II-GROUP
III - GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for 𝐒𝐎−𝟐𝟒 : Thick white ppt III Group may be present
Salt Solution + BaCl2
SO−2
4 present
Solution
C.T for 𝐒𝐎−𝟐𝟒 : III Group confirmed
Salt Solution + lead acetate Thick white ppt SO−2
4 is confirmed
Zero - GROUP
EXPERIMENT OBSERVATION INFERENCE
IV - GROUP
EXPERIMENT OBSERVATION INFERENCE
V - GROUP
EXPERIMENT OBSERVATION INFERENCE
VI - GROUP
EXPERIMENT OBSERVATION INFERENCE
PART - V REPORT:
Acid radical
SO−2
4 III Group
(Anion)
Basic radical
Mg+2 VI Group
(Cation)
Observations: (3 M)
1) Burette : KMnO4 solution
2) Conical flask : 10 ml of 0.1 M FAS + 1 test tube dil.H2SO4.
3) Indicate : KMnO4 is self indicator
4) End Point : Colourless to pale pink.
Tabulations : (4 M)
Trail No.
Burette reading in (ml)
I II III
Final
Initial
Volume of KMnO4 added in ml
𝑎2 𝑋 𝑀2 𝑋 𝑉2 1 𝑋 0.1 𝑋 10
∴ M1 = = =
𝑎1 𝑋 𝑉1 5 𝑋 𝑉1
30
Grand Total Marks
1. ALCOHOL:
A. Ceric Ammonium Nitrate test
b) Lucas test
2. PHENOL:
A. Neutral Ferric Chloride test
b) Phthalein dye test
4. CARBOXYLIC ACID:
A. Litmus test
b) Sodium bicarbonate test
c) Esterification test
5. PRIMARY AMINE:
A. Carbylamine test
b) Azo dye test (coupling reaction)
I) ALCOHOLS :
1. What is the General formula for alcohols?
A. R−OH
2. Which Functional Group is present in alcohols?
A. −OH
3. What happens when alcohols are treated with Cerric ammonium nitrate?
A. Red Coloured solution is formed.
4. What is Lucas reagent?
A. Mixture of Con. HCl and ZnCl2
5. What happens Lucas-Reagent is treated with 1. Primary alcohols 2. Secondary alcohols
3. Tertiary alcohols?
A. 1. No ppt. 2. ppt. after 4-5 minuts 3. Immdiate ppt.
II) PHENOLS :
1. What are Phenols?
A. Hydroxy derivative of Benzene is called as Phenol.
2. What happens when Phenol is treated with Neutral FeCl3 ?
A. Violet coloured solution is formed.
3. How you Conduct Phthalein dye test?
A. Little Phthalic anhydride is heated with Phenol and con. H2SO4 then the mixture is poured into NaOH
solution, pink coloured solution is produced.
4. What are the Reagents used in phthalein test?
A. Phenol, phthaleic anhydride and con. H2SO4.
5. Why, the pink coloured solution is produced in phthaleic fusion test?
A. Due to the formation of Phenolphthalein (indicator)
6. What is the action of conc. H2SO4 in Phthalein fusion test?
A. De-hydrating agent.
V) AMINES :
1. What is the general formula for Primary Amines?
A. R−NH2
2. What is Carbyl amine Reaction?
A. It is the reaction between primary amines and CHCl3 & alc. KOH
3. What is the odour of the gas evolved during the carbyl amine reaction?
A. Foul smell or Obnoxious smell
4. Name the gas evolved when aniline is heated CHCl2 and alc. KOH
A. Phenyl-isocyanides
5. What is Di-azotisation reaction?
A. It is the reaction between Aniline and Nitrous acid in presence of dil. HCl at 0 – 5oC.
Or (it is a test for aromatic primary amines)
6. What is the colour produced during the Azo-dye test?
A. Red colour or Red-dye.
7. Name a test to detect an alcoholic-OH group.
A. Ceric ammonium nitrate test.
8. Mention one reagent used to test alcohol
A. Lucas reagent or ceric ammonium nitrate
9. What happens when ceric ammonium nitrate is added to alcohol?
A. Pink or Red colour is obtained
10. Which organic compound is identified by using ceric ammonium nitrate?
A. Alcohol
11. What colour is seen when ceric ammonium nitrate is added to alcohol?
A. Pink colour or Red colour
12. What is Lucas reagent?
A. A mixture of anhydrous ZnCl2 and conc. HCl is called Lucas reagent.
13. Name the reagent used to distinguish between primary, secondary and Tertiary alcohols.
A. Lucas reagent test