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II PUC Chemistry Lab Syllabus

The document is a model question paper for a Chemistry practical examination at Excellent PU Science College, detailing systematic semi-micro qualitative analysis of simple inorganic salts. It includes experiments for detecting acid and basic radicals in various salts, with specific observations and inferences for each test. The report section summarizes the identified acid and basic radicals for each salt analyzed.

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Samarth Salunke
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0% found this document useful (0 votes)
7 views18 pages

II PUC Chemistry Lab Syllabus

The document is a model question paper for a Chemistry practical examination at Excellent PU Science College, detailing systematic semi-micro qualitative analysis of simple inorganic salts. It includes experiments for detecting acid and basic radicals in various salts, with specific observations and inferences for each test. The report section summarizes the identified acid and basic radicals for each salt analyzed.

Uploaded by

Samarth Salunke
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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VECAS ASSOCIATION’S (R)

EXCELLENT PU SCIENCE COLLEGE, VIJAYAPUR.


Class : PUC II Year Department of Chemistry Max. Marks : 30
Subject : Chemistry(34) Time : 2hrs.

MODEL QUESTION PAPER WITH ANSWERS


CHEMISTRY PRACTICAL EXAMINATION

I) Analyse the given simple inorganic salt systematically and report one acidic radical and
one basic radical. (Any one salt Analysis from following)

SALT ANALYSIS - 1

Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.

Part I: Preliminary tests:


1. Physical state : Crystalline
2. Colour : White
3. Solubility : Soluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for Carbonate ion :


Salt + dil. HCl No Brisk effervescence I Group absent

1|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


II - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for Cl-,Br-,NO3- :


Salt + conc. H2SO4 Gas evolved II Group may be present
(3-4 drops in a dry test
Colourless, White fumes with
tube)
pungent smell, gives dense white Cl− may be present
fumes with a glass rod dipped in
NH4OH

C. T for chloride ion (Cl−):


(Chromyl chloride test)
Salt + K2Cr2O7 crystals +
conc. H2SO4, heat and pass Water turns yellow solution
the liberated gas through Thick yellow ppt Cl− Confirmed
water taken in another test
Chloride ion confirmed
tube. Water turns yellow,
Above yellow solution +
add Lead acetate

Part-III: Detection of Basic Radicals (Cations):

Zero group
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐍𝐇𝟒+ Pungent smell of ammonia, Zero group may be Present
Salt + NaOH solution, heat gives dense white fumes with NH4+ .
a glass rod dipped in con. HCl. (Ammonium ion)
C.T for 𝐍𝐇𝟒+ Ammonium ion confirmed
O.S + Nessler’s reagent + Brown ppt NH4+ Confirmed
NaOH Solution in excess.

Part-IV: Preparation of O.S. (Original Solution):


(i) Salt + Water ⟶ soluble in water i.e, Crystalline salt

Part V: REPORT:
Acid radical Group: II
Cl–
(Anion)
Basic radical Group: 0
𝐍𝐇𝟒+
(Cation)

Given Salt is : Ammonium chloride (NH4Cl)

2|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


SALT ANALYSIS - 2
Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.
Part I: Preliminary tests:
1. Physical state : Crystalline
2. Colour : White
3. Solubility : Soluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE

Salt + dil. HCl No Brisk effervescence I Group absent

II - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for Cl-,Br-,NO3- : Gas evolved II Group present


Salt + conc. H2SO4
Orange Red fumes and solution Br– may be present
(3-4 drops in a dry test tube)
turns light yellow (Bromide ion)
C. T for Bromide ion (Br-):
Orange red fumes solution turn Br– Confirmed
Salt + MnO2 powder + conc.
orange red colour
H2SO4, heat Bromide ion confirmed

Part-III: Detection of Basic Radical (Cation):

Zero group
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐍𝐇𝟒+ Pungent smell of ammonia, Zero group may be Present
Salt + NaOH solution, heat gives dense white fumes with NH4+ .
a glass rod dipped in con. HCl. (Ammonium ion)
C.T for 𝐍𝐇𝟒+
Brown ppt Ammonium ion confirmed
O.S + Nessler’s reagent +
NaOH Solution in excess. NH4+ confirmed

Part-IV: Preparation of O.S. (Original Solution):


(i) Salt + Water ⟶ soluble in water i.e, Crystalline salt
Part V: REPORT:
Acid radical (Anion)
Br– Group: II
Basic radical (Cation)
𝐍𝐇𝟒+ Group: 0

Given Salt is : Ammonium Bromide (NH4Br)

3|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


SALT ANALYSIS - 3

Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.

Part I: Preliminary tests:


1. Physical state : Crystalline
2. Colour : White
3. Solubility : Insoluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Brisk effervescence with the I Group may be present
Salt + dil. HCl
colourless & odourless gas CO3−2 present

C. T for (𝐂𝐎−𝟐𝟑 ):
Effervescence of CO2 turns lime I Group confirmed
Salt + dil. HCl
water milky (CO−2
3 ) Confirmed

Part-III: Detection of Basic Radical (Cation):

Zero group
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐍𝐇𝟒+ : No Pungent smell of ammonia Zero group absent


salt + NaOH solution, heat gas

Part-IV: Preparation of O.S. (Original Solution):


(i) Salt + dil. HCl
I-GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + dil. HCl No ppt I Group absent

II - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + dil. HCl pass H2S gas No ppt II Group absent

4|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


III - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH in No gelatanious white ppt III Group absent


excess

IV - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH No ppt IV Group absent


pass H2S gas

V - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH +


Ammonium covelent an White ppt V Group may be present
excess

O.S + dil. H2SO4 No ppt Ca+2 present calcium ion

C.T for Ca+2


Ca+2 confirmed calcium ion
O.S + Ammonium White ppt
confirmed
Oxalate (NH4)2C2O4
Flame test:
Salt paste is prepared with Brick red flame Ca+2 confirmed
conc. HCl it is held to the
bunsun flame with Pt Wire.

Part V:
REPORT:
Acid radical
𝐂𝐎−𝟐
𝟑 Group: II
(Anion)
Basic radical
Ca+2 Group: V
(Cation)
Given Salt is : Calcium carbonate (CaCO3

5|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


SALT ANALYSIS - 4

Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.

Part I: Preliminary tests:


1. Physical state : Crystalline
2. Colour : White
3. Solubility : Insoluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Salt + dil. HCl No Brisk effervescence I Group absent

II-GROUP

EXPERIMENT OBSERVATION INFERENCE

Test for Cl–, Br–, 𝐍𝐎− 𝟑: No gas evolved II Group absent


Salt + conc. H2SO4
(3, 4 drops on a day test tube)

III - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐒𝐎−𝟐𝟒 Thick white ppt III Group may be present
Salt solution + BaCl2 solution
SO−2
4 present

C.T for 𝐒𝐎−𝟐 𝟒


Thick white ppt III Group confirmed
Salt solution + lead acitate
solution SO−2
4 confirmed

6|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


Part-III : Detection of Basic radical [cations]
Zero - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐍𝐇𝟒+ : No pungent smell of Ammonia gas Zero Group absent
Salt + NaOH solution heat

Part-IV : Preparation of O.S


1) Salt + Water
I - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + dil HCl


No ppt I Group absent

II - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + dil.HCl pass H2S gas No ppt II Group absent

III - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH in Gelatinous white ppt III Group may be present
excess
Al+3 may be present

C.T for Al+3 White ppt soluble in excess to give III Group confirmed
O.S + NaOH drop by drop clear solution Al+3 confirmed

Part V: REPORT:
Acid radical
𝐒𝐎−𝟐
𝟒 Group: III
(Anion)
Basic radical
Al+3 Group: III
(Cation)

Given Salt is : Aluminium Sulphate [Al2 (SO4)3]

7|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


SALT ANALYSIS - 5

Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.

Part I: Preliminary tests:


1. Physical state : Amorphus
2. Colour : White
3. Solubility : Insoluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
Brisk effervescence with the I Group may be present
Salt + dil. HCl
of colourless & odorless gas
CO3−2 Present

C.T for 𝐂𝐎−𝟐 Effervescence of CO2 turns I Group confirmed


𝟑
lime water into milky CO3−2 confirmed
Salt + dil HCl

Part-III : Detection of Basic radical [cations]


Zero - GROUP
EXPERIMENT OBSERVATION INFERENCE

Salt + NaOH solution heat No pungent smell of Ammonia gas Zero Group absent

Part-IV : Preparation of O.S


1) Salt + dil HCl
I-GROUP

EXPERIMENT OBSERVATION INFERENCE

1) O.S + dil HCl No ppt II Group absent

II-GROUP

EXPERIMENT OBSERVATION INFERENCE

2) O.S + dil HCl pass H2S gas No gas evolved II Group absent

8|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


III - GROUP
EXPERIMENT OBSERVATION INFERENCE

3) O. S + NH4Cl + NH4OH No Gelatinous white ppt III Group absent


in excess

IV - GROUP
EXPERIMENT OBSERVATION INFERENCE

4) O.S + NH4Cl + NH4OH No ppt IV Group absent


pass H2S gas

V - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH


Ammonium Carbonate White ppt V Group absent
Excess

VI - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for Mg+2 : VI Group may be present


O.S + NH4Cl + NH4OH + Crystalline White ppt Mg+2 present
Na2HPO4
Scratch the side of the test
tube with a glass rod.

C.T for Mg+2 : VI Group confirmed


White ppt insoluble in excess Wh

O.S + NaOH drop by drop Mg+2 confirmed

REPORT:
Acid radical
CO3−2 Group: I
(Anion)
Basic radical
Mg+2 Group: VI
(Cation)

Given Salt is : Magnesium Carbonate (MgCO3 )

9|Page Dept. of Chemistry | Excellent PU Science College, Vijayapur


SALT ANALYSIS - 6

Aim: “Systematic semi-micro qualitative analysis of Simple Inorganic Salts”.

Part I: Preliminary tests:


1. Physical state : Crystaline
2. Colour : White
3. Solubility : Salt + Water
Soluble in water.

Part II : Detection of Acid Radicals (Anions):

I-GROUP
EXPERIMENT OBSERVATION INFERENCE
Test for Carbonate ion :
No Brisk effervescence I Group absent
Salt + dil.HCl

II-GROUP

EXPERIMENT OBSERVATION INFERENCE

Test for Cl–, Br–, 𝐍𝐎− 𝟑 : No gas evolved II Group absent


Salt + conc. H2SO4
(3-4 drops in a dry test tube.)

III - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for 𝐒𝐎−𝟐𝟒 : Thick white ppt III Group may be present
Salt Solution + BaCl2
SO−2
4 present
Solution
C.T for 𝐒𝐎−𝟐𝟒 : III Group confirmed
Salt Solution + lead acetate Thick white ppt SO−2
4 is confirmed

Part III : Detection of Basic Radicals (Cations):

Zero - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for NH4+


No pungent smell of Ammonia gas Zero Group absent
Salt + NaOH solution heat

10 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


Part-IV : Preparation of O.S
Salt + water
EXPERIMENT OBSERVATION INFERENCE

O.S + dil.HCl No ppt I Group absent

O.S + dil.HCl, pass H2S gas No ppt II Group absent

O.S + NH4Cl + NH4OH


No Gelatinous white ppt III Group absent
in excess

IV - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH No white ppt IV Group absent


pass H2S gas

V - GROUP
EXPERIMENT OBSERVATION INFERENCE

O.S + NH4Cl + NH4OH


+ (NH4)2CO3 (Ammonium No White ppt V Group absent
carbonate) in Excess

VI - GROUP
EXPERIMENT OBSERVATION INFERENCE

Test for Mg+2 : VI Group may be present


O.S + NH4Cl + NH4OH +
Na2HPO4 Crystalline White ppt Mg+2 present
Scratch the side of the test
tube with a glass rod.

C.T for Mg+2: VI Group confirmed


White ppt insoluble in excess Wh

O.S + NaOH drop by dro


Mg+2 confirmed

PART - V REPORT:
Acid radical
SO−2
4 III Group
(Anion)
Basic radical
Mg+2 VI Group
(Cation)

Given Salt : Magnesium Sulphate (MgSO4 )

11 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


II) Determine the molarity of Potassium Permanganet (KMnO4) using standard 0.1M Ferrous
Ammonium Sulfate (FAS) solution by volumetric analysis.

Observations: (3 M)
1) Burette : KMnO4 solution
2) Conical flask : 10 ml of 0.1 M FAS + 1 test tube dil.H2SO4.
3) Indicate : KMnO4 is self indicator
4) End Point : Colourless to pale pink.

Tabulations : (4 M)

Trail No.
Burette reading in (ml)
I II III
Final
Initial
Volume of KMnO4 added in ml

Mean Burette reading (MBR) = V1 = I + II + III = _____ml


3
Calculation : (3 M)
We know that ,
a1 (M1 x V1) KMnO4 = a2 (M2 x V2) FAS
Where ,
a1 = No of electrons gained per formulae unit of KMnO4
M1 = Molarity of KMnO4 = ?
V1 = Volume of KMnO4 = ____ml
a2 = No of is last per formula unit of FAS = 1
M2 = Molarity of FAS = 0.1M
V2 = Volume of FAS = 10 ml

𝑎2 𝑋 𝑀2 𝑋 𝑉2 1 𝑋 0.1 𝑋 10
∴ M1 = = =
𝑎1 𝑋 𝑉1 5 𝑋 𝑉1

Result : Molarity of KMnO4 =________M.

12 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


SCHEME OF VALUATION
Centre Code (EE0376)
Time : 2 Hrs. Sub : Chemistry (Sub Code : 34) Max. Marks : 30
I] Experiments : Marks
1) Salt Analysis (10 Marks) :
i) Preliminary Tests (Any Two Correct Tests) 1 Marks
ii) Detection of Acid Radical 4 Marks
● Group Detection : (2 Marks)
(Correct Group Identification – 1 Mark)
(Correct Radical Identification – 1 Mark)
● Confirmatory Test : (2 Marks) 10
iii) Detection of Basic Radical 4 Marks Marks
● Group Detection : (2 Marks)
(Correct Group Identification – 1 Mark)
(Correct Radical Identification – 1 Mark)
● Confirmatory Test : (2 Marks)
iv) For writing systematic procedure with
absence of previous groups with correct report 1 Mark
2) Titration (10 Marks) :
i) For Performing the Experiment 3 Marks
ii) For Recording the Readings in the Tabular Coloumn 1 Mark
iii) For Accuracy of the Titre Value up to 3 Marks
0.3 ml Error (3 Marks)
10
0.4 ml Error (2 Marks)
Marks
0.5 ml Error (1 Mark)
0.6 ml Error & above (0 Mark)
iv) Calculations of Molarity
● Formula 1 Mark
● Substitution and Answer with Unit (1+1) 2 Marks
II Viva on Functional Group in Organic Compound :
Four Questions will be asked from Any Two Functional Groups in 4
Marks
Organic Compound (1 x 4)

III Journal Book : 6


Submission of the duly completed and certified journal book Marks

30
Grand Total Marks

13 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


Viva Questions With Answers
(Based on EXPERIMENT NO -18 & 19)

ORGANIC FUNCTIONAL GROUPS TEST

1. ALCOHOL:
A. Ceric Ammonium Nitrate test
b) Lucas test

2. PHENOL:
A. Neutral Ferric Chloride test
b) Phthalein dye test

3. ALDEHYDES AND KETONES:


A. 2, 4-DNP test
b) Tollen’s reagent test
c) Sodium nitroprusside test

4. CARBOXYLIC ACID:
A. Litmus test
b) Sodium bicarbonate test
c) Esterification test

5. PRIMARY AMINE:
A. Carbylamine test
b) Azo dye test (coupling reaction)

14 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


Test for Functional Groups In Organic Chemistry :

I) ALCOHOLS :
1. What is the General formula for alcohols?
A. R−OH
2. Which Functional Group is present in alcohols?
A. −OH
3. What happens when alcohols are treated with Cerric ammonium nitrate?
A. Red Coloured solution is formed.
4. What is Lucas reagent?
A. Mixture of Con. HCl and ZnCl2
5. What happens Lucas-Reagent is treated with 1. Primary alcohols 2. Secondary alcohols
3. Tertiary alcohols?
A. 1. No ppt. 2. ppt. after 4-5 minuts 3. Immdiate ppt.

II) PHENOLS :
1. What are Phenols?
A. Hydroxy derivative of Benzene is called as Phenol.
2. What happens when Phenol is treated with Neutral FeCl3 ?
A. Violet coloured solution is formed.
3. How you Conduct Phthalein dye test?
A. Little Phthalic anhydride is heated with Phenol and con. H2SO4 then the mixture is poured into NaOH
solution, pink coloured solution is produced.
4. What are the Reagents used in phthalein test?
A. Phenol, phthaleic anhydride and con. H2SO4.
5. Why, the pink coloured solution is produced in phthaleic fusion test?
A. Due to the formation of Phenolphthalein (indicator)
6. What is the action of conc. H2SO4 in Phthalein fusion test?
A. De-hydrating agent.

III) ALDEHTDES AND KETONES :

1. Which Functional group is present in 1. Aldehydes 2. Ketones


A. 1. –CHO 2. −CO−
2. What happens Aldehydes/Ketones are treated with 2, 4-DNPH?
A. Orange Red ppt. or Yellow ppt.
3. What is the use of 2, 4-DNPH?
A. It is used to detect Aldehyde or Ketone groups.
4. What is Tollen’s Reagent?
A. Ammonical solution of AgNO3 is called as Tollen’s Reagent.
5. What is the use of Tollen’s Reagent ?
A. It is used to detect an aldehydes group
6. What happens Aldehydes are warmed with Tollen’s Reagent?
A. Black ppt of bright silver mirror is formed.

15 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


IV) CARBOXYLIC ACIDS :

1. What is the General formula for Carboxylic acids?


A. R−COOH
2. What happens when moist blue litmus paper is dipped in the Carboxylic acids?
A. Blue litmus turns Red.
3. Name the Reagent used to detect the Carboxylic acids.
A. NaHCO3 solution
4. Name the gas liberated when the Carboxylic acids are treated with NaHCO3 solution?
A. CO2 gas
5. What is Esterification reaction?
A. It is the Reaction between Alcohols and Carboxylic acids in presence of Conc. H2SO4
6. What is the role of con. H2SO4 in the Esterification reaction?
A. Dehydrating agent.
7. What is the odour of the compound obtained during the Esterification reaction?
A. Fruity odour
8. What is the General formula for Esters?
A. R−COO−R

V) AMINES :
1. What is the general formula for Primary Amines?
A. R−NH2
2. What is Carbyl amine Reaction?
A. It is the reaction between primary amines and CHCl3 & alc. KOH
3. What is the odour of the gas evolved during the carbyl amine reaction?
A. Foul smell or Obnoxious smell
4. Name the gas evolved when aniline is heated CHCl2 and alc. KOH
A. Phenyl-isocyanides
5. What is Di-azotisation reaction?
A. It is the reaction between Aniline and Nitrous acid in presence of dil. HCl at 0 – 5oC.
Or (it is a test for aromatic primary amines)
6. What is the colour produced during the Azo-dye test?
A. Red colour or Red-dye.
7. Name a test to detect an alcoholic-OH group.
A. Ceric ammonium nitrate test.
8. Mention one reagent used to test alcohol
A. Lucas reagent or ceric ammonium nitrate
9. What happens when ceric ammonium nitrate is added to alcohol?
A. Pink or Red colour is obtained
10. Which organic compound is identified by using ceric ammonium nitrate?
A. Alcohol
11. What colour is seen when ceric ammonium nitrate is added to alcohol?
A. Pink colour or Red colour
12. What is Lucas reagent?
A. A mixture of anhydrous ZnCl2 and conc. HCl is called Lucas reagent.
13. Name the reagent used to distinguish between primary, secondary and Tertiary alcohols.
A. Lucas reagent test

16 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


14. What happens when a primary alcohol is treated with Lucas reagent?
A. White turbidity appears only on heating
15. What happens when a secondary alcohol is treated with Lucas reagent?
A. White turbidity appears after five to ten minutes
16. What happens when a tertiary alcohol is treated with Lucas reagent?
A. White turbidity appears immediately.
17. Which alcohol immediately forms turbidity with Lucas reagent?
A. Tertiary alcohol
18. Which alcohol forms turbidity with Lucas reagent after five minutes?
A. Secondary alcohol
19. Which alcohol do not form turbidity when treated with Lucas reagent at room temperature?
A. Primary alcohol
20. Which organic compound gives violet colour with neutral Ferric chloride solution?
A. Phenol
21. How do you detect phenol?
A. Neutral ferric chloride test or phthalein fusion test is used to detect phenol.
22. Which organic compound answers phthalein fusion test?
A. Phenol
23. Name the product obtained in phthalein fusion test.
A. Phenolphthalein
24. Mention the reagents used in phthalein fusion test.
A. Phenol + phthalic anhydride + conc. H2SO4.
25. Which colour is obtained when phenol undergoes phthalein fusion test?
A. Pale pink colour
26. What for is 2, 4-DNP reagent used?
A. 2, 4-DNP reagent is used to detect carbonyl group (aldehyde or ketene)
27. Which organic compound / Functional group is identified in 2, 4-DNP test?
A. Aldehyde or Ketones (Carbonyl group)
28. What happens when an aldehyde or a ketone is heated with 2, 4-DNP reagent?
A. Crystaline organe precipitate is formed
29. Mention one test for aldehyde
A. 2, 4-DNP test or Tollen’s reagent test
30. What is Tollen’s test
A. Tollen’s reagent test is used to detect aldehyde. A silver mirror is obtained when an aldehyde is heated
with Tollen’s reagent
31. Which organic compound gives a silver mirror when heated with Tollen’s reagent?
A. Aldehyde
32. What is Esterification test?
A. It is a confirmatory test for carboxylic acids and alcohols. When a carboxylic acid is heated with an
alcohol in presence of cone H2SO4, an ester having fruity smell is formed?
33. Which organic compound answers Esterification test?
A. Carboxylic acid or alcohol
34. Mention one simple test to identify a carboxylic acid.
A. Sodium bicarbonate test or litmus paper test.
35. What happens when a carboxylic acid is treated with NaHCO3 solution?
A. Brisk effervescence takes place with the liberation of CO2 gas.
36. Which organic compound answers carbyl-amine test?
A. Primary amines

17 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur


37. How do your perform carbyl amine test?
A. Primary amine on heating with chloroform and alcoholic KOH or NaOH gives. Carbyl amine
(isocyanides) having foul smell.
38. What happens when a primary amine is heated with chloroform and alcoholic KOH solution?
A. Carbyl amine is obtained
39. Explain Azo dye test.
A. Azo dye test is used to detect aromatic primary amine
When an aromatic 1o amine is treated with dilute HCl, sodium nitrite, and β-Naphthal in NaOH solution
at 0.5oC gives orange red dye.
40. What colour is seen in Azo dye test?
A. Orange red dye.
41. Which organic compound answers Azo-dye test?
A. Aromatic primary amine
42. What is Tollen’s reagent?
A. Ammonical silver nitrate solution is called Tollen’s reagent
43. What is Litmus paper test?
A. It is used to detect carboxylic acid. A carboxylic acid turns litmus paper into red.

*NOTE : 1. Learn the complete Salt Analysis & Titration Experiment.


2. Experiment No - 6 & 7 in chart should be read for viva.

INSTRUCTIONS FOR STUDENTS

1. Bring duly certified practical journal book.


2. Wear apron and sleepers/shoe before entering into the Laboratory.
3. Manual, Writing Pad, Mobile and any kind of electronic devices other than simple calculators are not
allowed in the Examination.
4. Enter your Examination seat number carefully on the Answer booklet.
5. Write the required things for the given experiments and take signature of examiners as instructions given
by the Examiners.
6. Handel the apparatus carefully and don’s waste the solutions/chemical.
7. Perform the experiments as per the procedure prescribed for it.
8. If students are unable to attend the practical exam on the prescribed batch or day then they will not be
allowed for the next batch or day.

18 | P a g e Dept. of Chemistry | Excellent PU Science College, Vijayapur

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