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Organic Experiments

The document describes 15 experiments testing organic compounds for various functional groups. Experiment 11 tests for an alcoholic (-OH) group using ester and Ceric ammonium nitrate tests. Experiment 12 tests for a phenolic group using Ferric chloride and Azo dye tests. Experiment 13 tests for an aldehyde (-CHO) group using Schiff's reagent, Tollen's reagent, and Fehling's solution tests. Experiment 14 tests for a carboxylic (-COOH) group using litmus, sodium bicarbonate, and ester tests. Experiment 15 tests for an amino (-NH2) group using carblyamine and Azo dye tests.

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41 views

Organic Experiments

The document describes 15 experiments testing organic compounds for various functional groups. Experiment 11 tests for an alcoholic (-OH) group using ester and Ceric ammonium nitrate tests. Experiment 12 tests for a phenolic group using Ferric chloride and Azo dye tests. Experiment 13 tests for an aldehyde (-CHO) group using Schiff's reagent, Tollen's reagent, and Fehling's solution tests. Experiment 14 tests for a carboxylic (-COOH) group using litmus, sodium bicarbonate, and ester tests. Experiment 15 tests for an amino (-NH2) group using carblyamine and Azo dye tests.

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VAIBHAW VAIBHAW
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EXPERIMENT NO.

11

Name of the Experiment: To test the presence of alcoholic group in the given organic compound.

Experiment Observation Inference


Ester Test: Take a few drops of the given A fruity smell is observed. -OH group
compound in a test tube. Add a few drops of present.
acetic acid and a few drop of conc H 2SO4 .Warm
the mixture in water bath.
Ceric Ammonium Nitrate Test: Take a few drops Red colour appeared -OH group
of the given compound in a test tube. Add a few present.
drops of ceric ammonium nitrate and shake well.

Result: The given organic compound contains alcoholic group (-OH).

EXPERIMENT NO. 12

Name of the Experiment: To test the presence of Phenolic group in the given organic compound.

Experiment Observation Inference


Ferric Chloride Test: Take a few drops of the A violet colour aappeared Phenolic group
given compound in a test tube. Add a few drops present.
of aqueous ferric chloride.
Azo Dye Test: Take a few drops of the given Formation of Brilliant Red or Phenolic group
compound in a test tube. Add about 2 ml of dil orange colour. present.
HCl. Then add freshly prepared aniline. Now add
a pinch of NaNO2 and cool the solution.

Result: The given organic compound is Phenol (C 6H5OH).


EXPERIMENT NO. 13

Name of the Experiment: To test the presence of aldehyde group in the given organic compound.

Experiment Observation Inference


Schiff’s Reagent Test: Take a few drops of the Pink colour appeared. -CHO group
given organic compound in a test tube. Add a few present.
drops of schiff’s reagent and shake well.
Tollen’s Reagent Test: Take a few drops of the Silver mirror on the side of test -CHO group
given organic compound in a test tube. Add a few tube is appeared. present.
drops of tollen’s reagent. Then worm the solution
in water bath.
Fehling Solution Test: Take a few drops of the A redish brown precipitate is -CHO group
given organic compound in a test tube. Add a few obtained. present.
drops of Fehling solution A and B. Then worm the
solution in water bath.

Result: The given organic compound contains aldehyde group (-CHO).

EXPERIMENT NO. 14

Name of the Experiment: To test the presence of carboxylic group in the given organic compound.

Experiment Observation Inference


Litmus Test: Take a few drops of the given Blue litmus solution turned red. -COOH group
compound in a test tube. Add a few drops of blue present.
litmus solution.
Sdium bicarbonate Test: Take a few drops of the A gas is evolved with brisk -COOH group
given compound in a test tube. Add a pinch of effervescence i.e. CO2 present.
NaHCO3
Ester Test: Take a few drops of the given A fruity smell of ester is -COOH group
compound in a test tube. Add a few drops of obtained. present.
ethyl alcohol and a few drop of conc H 2SO4 .Warm
the mixture in water bath.

Result: The given organic compound contains carboxylic group (-COOH).


EXPERIMENT NO. 15

Name of the Experiment: To test the presence of amino group in the given organic compound.

Experiment Observation Inference


Carbylamine Test: Take a few drops of the given Offensive smell obtained. -NH2 group
compound in a test tube. Add few drop of present.
Chloroform. Then add alcoholic KOH solution and
warm on water bath.
Azo Dye Test: Take a few drops of the given Blood red dye is obtained -NH2 group
compound in a test tube. Add about 2 ml of dil present.
HCl. Then add freshly prepared aniline. Now add
a pinch of NaNO2 and cool the solution. Now add
alkaline solution of 2 naphthol.

Result: The given organic compound contains amino group (-NH 2).

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